NiCoCr-based medium entropy alloy with excellent strength plasticity matching and preparation method

An entropy alloying and strength technology, applied in the field of entropy alloying and preparation in NiCoCr base, can solve problems such as limited yield strength, and achieve the effects of strong plastic deformation ability, excellent strength-plastic matching, and simple preparation method.

Active Publication Date: 2020-11-06
XI AN JIAOTONG UNIV
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  • Abstract
  • Description
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  • Application Information

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Problems solved by technology

However, coarse-grained NiCoCr medium-entropy alloys are similar to fcc pure metals. Although they have high ductility, their yield strength is limited, and it is difficult to meet the need...

Method used

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  • NiCoCr-based medium entropy alloy with excellent strength plasticity matching and preparation method
  • NiCoCr-based medium entropy alloy with excellent strength plasticity matching and preparation method
  • NiCoCr-based medium entropy alloy with excellent strength plasticity matching and preparation method

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preparation example Construction

[0029] The preparation method of the above-mentioned NiCoCr-AlTa series medium entropy alloy comprises the following steps:

[0030] Step 1. According to atomic percentage, uniformly mix metal particles of 29-33% Ni, 29-33% Co, 29-33% Cr, 4-8% Al and 1.0-3.0% Ta.

[0031] The weight of raw materials is accurate to 0.01g when weighing, and then the alloy is smelted by vacuum arc melting method.

[0032] During the smelting process, first vacuum to 5Pa, then pass high-purity argon gas and then evacuate, repeat the furnace washing three times to ensure a high-purity vacuum environment, the smelting induction current is 400-500A, the alloy smelting process is accompanied by electromagnetic stirring, and repeated remelting 5 times to ensure the uniformity of the composition, and finally cooled in a water-cooled copper crucible to obtain an ingot;

[0033] Step 2, the alloy ingot is homogenized at 1150-1250°C;

[0034] Step 3, cold rolling at room temperature, the amount of deform...

Embodiment 1

[0037] A kind of preparation method of NiCoCr-AlTa system entropy alloy, comprises the following steps:

[0038] Step 1. In atomic percentage, uniformly mix metal particles of 29% Ni, 31% Co, 33% Cr, 4% Al and 3% Ta.

[0039] During the smelting process, first vacuum to 5Pa, then pass high-purity argon gas and then evacuate, repeat the furnace washing three times to ensure a high-purity vacuum environment, the smelting induction current is 400A, the alloy smelting process is accompanied by electromagnetic stirring, and repeated remelting 5 times , to ensure the uniformity of the composition, and finally cooled in a water-cooled copper crucible to obtain an ingot;

[0040] Step 2, the alloy ingot is homogenized at 1150°C;

[0041] Step 3, cold rolling at room temperature, the amount of deformation is controlled at 50%;

[0042] In step 4, a single-phase fcc alloy is obtained after recrystallization annealing at 1100°C.

[0043] In the single-phase fcc structure, the equiaxed...

Embodiment 2

[0045] A kind of preparation method of NiCoCr-AlTa system entropy alloy, comprises the following steps:

[0046] Step 1. In atomic percentage, uniformly mix metal particles of 31% Ni, 29% Co, 31% Cr, 7% Al and 2.0% Ta.

[0047]During the smelting process, first vacuum to 5Pa, then pass high-purity argon gas and then evacuate, repeat the furnace washing three times to ensure a high-purity vacuum environment, the smelting induction current is 450A, the alloy smelting process is accompanied by electromagnetic stirring, and repeated remelting 6 times , to ensure the uniformity of the composition, and finally cooled in a water-cooled copper crucible to obtain an ingot;

[0048] Step 2, the alloy ingot is homogenized at 1200°C;

[0049] Step 3, cold rolling at room temperature, the amount of deformation is controlled at 65%;

[0050] Step 4: After recrystallization annealing at 1150° C., a single-phase fcc alloy is obtained.

[0051] In the single-phase fcc structure, the equiaxe...

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Abstract

The invention provides a NiCoCr-based medium entropy alloy with excellent strength plasticity matching and a preparation method. According to the NiCoCr-based medium entropy alloy with the excellent strength plasticity matching and the preparation method, microalloying treatment is performed by utilizing Al and Ta elements, and the alloy can obtain excellent strength-plasticity combination after being subjected to a simple deformation heat treatment process; and by means of Al/Ta element alloying, the grain size is reduced, the twin crystal content is increased, and a remarkable solid solutionstrengthening effect is generated, the lattice friction force is greatly increased, but the alloy still maintains a fcc matrix, so that the alloy still has good toughness while the alloy strength isimproved. The NiCoCr-based medium entropy alloy has excellent room-temperature mechanical properties, the NiCoCr medium entropy alloy yield strength is improved by 106% to be about 635 MPa, the tensile strength is improved by 35% to be about 1000 MPa, and meanwhile, the NiCoCr-based medium entropy alloy has a tensile ductility of 52% at the same time. Based on the above characteristics, the NiCoCr-based medium entropy alloy with the excellent strength plasticity matching is made to have a great competitive advantage in single-phase fcc high/medium entropy alloys and have the engineering application foreground extremely.

Description

technical field [0001] The invention relates to the technical field of high-performance alloy materials, in particular to a NiCoCr-based medium-entropy alloy with excellent strength-plasticity matching and a preparation method thereof. Background technique [0002] For traditional metal materials, it is extremely challenging to design alloys with excellent-strength matching, and the emergence of high / medium entropy alloys (HEAs / MEAs) provides infinite possibilities for realizing this goal. HEAs were first reported in 2004, It is a new type of high-performance metal material that has emerged in recent years with broad application potential. HEAs break the traditional design concept of a single principal element of alloys and open up new ideas for alloy design. Moreover, due to its high mixing entropy effect, severe lattice distortion effect, hysteresis diffusion effect and "cocktail" effect, it has unique microstructure characteristics, and thus presents many unique propertie...

Claims

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Application Information

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IPC IPC(8): C22C30/00C22C1/02C22F1/16
CPCC22C1/02C22C30/00C22F1/16
Inventor 张金钰张东东刘刚孙军
Owner XI AN JIAOTONG UNIV
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