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A kind of treatment method and treatment system of sludge, waste residue or oil sand in natural oil mines that pollute deep oil and water all year round

A processing method and technology for natural oil, which are applied in the field of Ming Dynasty, can solve the problems of affecting the technical and economic performance of oil-containing sludge extraction, large energy consumption of extraction solvent, and postponement of popularization and application, and achieve the effects of easy separation, remarkable effect and high separation efficiency.

Active Publication Date: 2021-11-26
SOUTHEAST UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the separated liquid phase is rectified according to the boiling range of the main agent A, auxiliary agent B and auxiliary agent C, and then compounded with a fresh mixed solvent, that is, the recovery of the extraction solvent consumes a lot of energy
[0008] To sum up, the raw materials currently used as oily solid substances, especially oily and watery sludge, waste residue or oil sand extraction solvents in natural oil mines are mainly light coal tar, petroleum ether, naphtha, benzene, etc. , toluene and other solvents that are liquid at normal temperature and pressure, or a combination solvent with a wide boiling range, can achieve satisfactory extraction results under certain temperature and pressure operating conditions, but a key problem of the above-mentioned solvent extraction method is that the extraction after extraction Since the solvent is liquid at normal temperature and pressure, the mixture with the extracted oil needs to be separated and recovered through complex processes such as rectification to obtain the extraction solvent, which affects the economic performance of the oily sludge extraction technology and delays the promotion of this technology application

Method used

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  • A kind of treatment method and treatment system of sludge, waste residue or oil sand in natural oil mines that pollute deep oil and water all year round
  • A kind of treatment method and treatment system of sludge, waste residue or oil sand in natural oil mines that pollute deep oil and water all year round

Examples

Experimental program
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Effect test

Embodiment 1

[0044] Such as figure 1 As shown, a treatment system for sludge, waste residue, or oil sand in natural oil mines that has been heavily polluted all the year round, includes an extraction reactor 2, a gas-liquid separator 3, a dryer 7, and a compression condenser 8 connected in sequence , solvent storage tank 9; Solvent storage tank 9 is provided with pressurization device 10, gas-liquid separator 3 is connected with oil-water separator liquid separation 4; Extraction reactor 2 is provided with stirring device; Extraction reactor 2 outlets are provided with filter device. A pressure gauge and a thermometer are arranged on the extraction reactor 2; a thermometer is arranged on the solvent storage tank 9; a valve and a flow meter are arranged between the extraction reactor 2, the solvent storage tank 9 and the gas-liquid separator 3; the gas-liquid separator A pressure gauge, a temperature gauge, and a valve are set between 3 and the drier 7; a valve is set between the drier 7; ...

Embodiment 2

[0047] In this example, the extraction agent is gaseous dimethyl ether at normal temperature and pressure, with a boiling point of -24.9°C. The solid matter containing oil and water is obtained from a lubricating oil refinery. The water content of the solid matter containing oil and water is 2.81%. The oil content is 33.63%, and the solid content is 63.56%. The solid matter treatment method containing oil and water, 40g of solid matter containing oil and water is placed in the extraction reactor 2, the temperature is room temperature 15 ° C, under the pressurization of the pressure device 10, the liquid solvent in the solvent storage tank 9 from the solvent The storage tank 9 flows into the extraction reactor 2, and the extraction reactor 2 is pressurized to keep the extraction solvent in a liquid state. The mass ratio of the solid matter containing oil and water to the liquid extraction solvent is 1:25, and the stirring speed is 50rpm. The extraction contact time was 60 min. ...

Embodiment 3

[0049] In this example, the extraction agent is dimethyl ether, which is a gas at normal temperature and pressure, with a boiling point of -24.9°C. The solid matter containing oil and water is taken from a lubricating oil refinery. The water content of the solid matter containing oil and water is 2.81 %, the oil content is 33.63%, and the solid content is 63.56%. The method for treating solid matter containing oil and water, 40 g of solid matter containing oil and water is placed in the extraction reactor 2 at a temperature of 10°C at room temperature, and under the pressure of the pressure device 10, the liquid solvent in the solvent storage tank 9 flows to In the extraction reaction kettle 2, pressurize the extraction reaction kettle 2 to keep the extraction solvent in a liquid state. The mass ratio of the solid matter containing oil and water to the liquid extraction solvent is 1:10, the stirring speed is 50rpm, and the extraction contact time is 60min. After the extraction...

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Abstract

The invention discloses a treatment method and a treatment system for perennially polluted deeply oily and watery sludge, waste residue or oil sand in natural oil mines. The method combines oily and watery solid matter with low Boiling point Weak polar or low boiling point non-polar organic solvent liquid is fully contacted, oil and water in the solid are extracted into the liquid phase, and after solid-liquid separation, the liquid phase is easily separated by decompression or heating up to vaporize the low boiling point Organic solvents with low latent heat and oil and water, the solvent gas is compressed and condensed and then recycled, and the extracted oil and water are separated from oil and water, and the extracted oil can be used as fuel or used for refining. The invention is a high-performance, low-energy-consumption treatment method for solid matter containing oil and water. The effect of oil extraction is outstanding, the extraction solvent is completely separated from the recovered oil, the recycling process of the extraction solvent is simple and energy-saving, and oil extraction and dehydration can be performed simultaneously. , to a greater extent to achieve the oil recovery and recycling of oily sludge, energy goals.

Description

technical field [0001] The invention belongs to the field of environmental pollution, and specifically relates to a treatment method and a treatment system for sludge, waste residue or oil sand in natural oil mines that have been polluted deeply all the year round and contain oil and water, and are especially suitable for tank bottom oil sludge produced during crude oil storage and transportation. Oily and watery sludge produced by oil refineries and oil refinery sewage treatment plants, oil-contaminated soil, sandy soil, and oil sands, oily waste white clay from petrochemical companies, oily waste residue from petrochemical companies, oily soil left after oil extraction in oil fields, etc. , and can recover oil after treatment. Background technique [0002] A large amount of oily sludge is produced in the process of oil extraction, production, and storage. EPA research shows that every 500 tons of crude oil processed will produce 1 ton of oily sludge. The annual production ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F11/00C02F11/121C02F1/40C02F1/26C02F1/06
CPCC02F11/002C02F11/121C02F1/06C02F1/40C02F1/26C10G33/06C10G1/045B01D3/06B01D17/0214B01D1/2846C02F9/00C02F11/127C02F1/38C02F2101/32C02F2103/365B01D17/02C10G2300/4006C10G2300/4012C10G2300/44
Inventor 黄瑛张栋查戎应蒙
Owner SOUTHEAST UNIV