Preparation method of anti-skid elastic spandex core-spun yarn suitable for jean fabric
A technology of spandex core-spun yarn and denim fabric, which is applied in the preparation of anti-slip elastic spandex core-spun yarn and the field of preparation of anti-slip elastic spandex core-spun yarn. Effect of Hysteresis Area
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Embodiment 1
[0033] Step 1: Prepolymer Preparation
[0034] 1) Mix the raw materials polytetramethylene ether glycol PTMG 2000 and 4,4'-diphenylmethane diisocyanate, and react at 80°C for 100 minutes to prepare an isocyanate group-terminated prepolymer, in which 4,4'- The mol ratio of diphenylmethane diisocyanate and polytetramethylene ether glycol 2000 is 1.70:1;
[0035] 2) After the prepolymer is cooled to 45° C., N,N-dimethylacetamide solution is added and mixed evenly by sufficient stirring to prepare a solution with a concentration of 35% by mass.
[0036] The second step: the preparation of polyurethane urea
[0037] 2) Dissolving ethylenediamine and diethylamine into the solvent N,N-dimethylacetamide to form a mixed amine solution with a concentration of 7.00% by mass;
[0038] 3) Add the prepared mixed amine solution to the N,N-dimethylacetamide solution of the prepolymer and stir rapidly to react to form a polyurethane solution with a concentration of 35% by mass, wherein the a...
Embodiment 2
[0047] Step 1: Prepolymer Preparation
[0048] 1) Mix the raw material polytetramethylene ether glycol PTMG 1800 with 4,4'-diphenylmethane diisocyanate and 2,4'-diphenylmethane diisocyanate, and react at 90°C for 120 minutes to prepare the isocyanate group Blocked prepolymer in which the mass ratio of 2,4'-diphenylmethane diisocyanate to 4,4'-diphenylmethane diisocyanate is 1:9 and the molar ratio of isocyanate groups to hydroxyl groups is 2.00:1 ;
[0049] 2) After cooling the prepolymer to 45° C., add N,N-dimethylacetamide solution, stir and mix evenly to prepare a solution with a concentration of 40% by mass.
[0050] The second step: the preparation of polyurethane urea
[0051] 2) dissolving ethylenediamine, butylenediamine, and diethylamine into the solvent N,N-dimethylacetamide to form a mixed amine solution with a concentration of 7.00% by mass;
[0052] 3) Add the prepared mixed amine solution to the N,N-dimethylacetamide solution of the prepolymer and stir rapidly...
Embodiment 3
[0061] Step 1: Prepolymer Preparation
[0062] 1) Mix the raw materials polytetramethylene ether glycol PTMG 2000 and 4,4'-diphenylmethane diisocyanate, and react at 90°C for 100 minutes to prepare an isocyanate group-terminated prepolymer, in which 4,4'- The mol ratio of diphenylmethane diisocyanate and polytetramethylene ether glycol 2000 is 1.50:1;
[0063] 2) After cooling the prepolymer to 45° C., add N,N-dimethylacetamide solution, stir and mix evenly to prepare a solution with a concentration of 40% by mass.
[0064] The second step: the preparation of polyurethane urea
[0065] 2) dissolving ethylenediamine, butylenediamine, diethylamine, and 1,4-butanolamine into the solvent N,N-dimethylacetamide to form a mixed amine solution with a concentration of 7.00% by mass;
[0066] 3) Add the prepared mixed amine solution to the N,N-dimethylacetamide solution of the prepolymer and stir rapidly to react to form a polyurethane solution with a mass percentage concentration of ...
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