Application of phosphorus-doped titanium dioxide nanotube array catalyst in photoelectrocatalytic degradation of tylosin

Abstract

The invention discloses an application of a phosphorus-doped titanium dioxide nanotube array catalyst in photoelectrocatalytic degradation of tylosin, and belongs to the field of photoelectrocatalysis. According to the titanium dioxide nanotube array catalyst, a titanium sheet, red phosphorus and ethylene glycol are adopted as raw materials, a titanium dioxide nanotube array is prepared through ananodic oxidation method, then an ampoule bottle is sealed, and the titanium dioxide nanotube array is calcined with amorphous red phosphorus to prepare the phosphorus-doped titanium dioxide nanotubearray. According to the invention, the catalyst has excellent performance of photoelectrocatalytic degradation of tylosin (80% of tylosin can be removed after four hours of illumination) and good cycling stability (78% of tylosin can still be removed after four cycling tests); at present, a plurality of methods are used for removing tylosin, such as physical adsorption, biodegradation, chemical oxidation, photocatalysis technology and the like, but the methods have the defects of high energy consumption, poor tylosin removal effect under low pollutant concentration and the like to different extents, so that the photoelectrocatalysis technology with the help of the phosphorus-doped titanium dioxide nanotube array catalyst has certain significance; and the titanium sheet and the red phosphorus are rich in reserves in nature, non-toxic, low in price and environment-friendly, and are environment-friendly catalysts with very good prospects.

Description

technical field [0001] The invention belongs to the field of photoelectric catalysis, and in particular relates to the application of a phosphorus-doped titanium dioxide nanotube array catalyst in the photoelectric catalytic degradation of tylosin. Background technique [0002] The photoelectrocatalytic method is an efficient green technology, which can control the reaction rate and does not require the addition of chemical additives. Most importantly, it can achieve continuous degradation of pollutants at lower pollutant concentrations. The research on high-efficiency photocatalysts has also become a hot spot in recent years. As a semiconductor photocatalyst, titanium dioxide has been widely used in photocatalysis due to its advantages of non-toxicity, low price and sustainable use. However, the large band gap (3.2 eV) and high photoinduced charge carrier recombination rate make it poor in photocatalytic efficiency. [0003] The titanium dioxide nanotube array grown on th...

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Problems solved by technology

However, the large bandgap (3.2eV) and high photoinduced charge carrier recombination rate make it poor in photocatalytic efficiency.

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