Preparation method of heat-resistant high-strength agricultural machinery adhesive
A high-strength, agricultural machinery adhesive technology, applied in the direction of adhesives, polymer adhesive additives, adhesive types, etc., can solve the impact resistance of adhesive joints, low bending and peel strength, poor aging resistance of agricultural machinery adhesives, Solving problems such as low temperature resistance of bonding, achieving the effect of low curing temperature, good processing technology, and reduced price
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Embodiment 1
[0017](1) Add 105 parts of 4,4'-diaminodiphenyl ether and trimellitic anhydride to the reaction kettle in parts by weight, wherein the molar ratio of 4,4'-diaminodiphenyl ether: trimellitic anhydride is 3: 2. After raising the temperature to 120°C and starting to stir for 6 hours, continue to add 93 parts of a mixture of diethylene glycol, neopentyl glycol and phthalic anhydride with a molar ratio of 2.5:2:1.5 and Atlac590 phenolic vinyl 145 parts of ester resin and control the temperature to 180°C under the condition of 20°C / hour heating rate and continuously test the acid value. When the acid value is lower than 25mgKOH / g, stop the reaction and vacuum for 30min, then add the weight of phenolic vinyl ester resin Continue stirring with 25% active diluent, lower the temperature to below 50°C, add 0.1% polymerization inhibitor p-tert-butylcatechol to obtain modified vinyl ester resin according to the weight of phenolic vinyl ester resin; (2) parts by weight Counting, 91 parts of...
Embodiment 2
[0019] (1) Add 100 parts of 4,4'-diaminodiphenyl ether and trimellitic anhydride to the reactor in parts by weight, wherein the molar ratio of 4,4'-diaminodiphenyl ether: trimellitic anhydride is 2: 2. After heating up to 120°C and starting to stir and react for 6 hours, continue to add 88 parts of a mixture of diethylene glycol, neopentyl glycol and phthalic anhydride with a molar ratio of 1:2:1.5 and phenolic vinyl ester 145 parts of resin and control the temperature to 180°C under the condition of 15°C / hour heating rate and constantly test the acid value. When the acid value is lower than 25mgKOH / g, stop the reaction and vacuum for 20min, then add phenolic vinyl ester resin by weight Continue stirring with 25% active diluent, lower the temperature to below 50°C, add 0.05% polymerization inhibitor p-methoxyphenol to the weight of Ripoxy630 phenolic vinyl ester resin to obtain modified vinyl ester resin; (2) parts by weight In total, 88 parts of trishydroxyethyl isocyanurate,...
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