Ultrahigh-temperature wear-resistant corrosion-resistant ceramic glaze and preparation method and application thereof

An ultra-high temperature, ceramic glaze technology, applied in the field of ceramic glaze, can solve the problems of low hardness of the glaze surface, difficulty in meeting performance requirements, poor wear resistance and corrosion resistance, etc., to reduce the friction coefficient, broaden the firing range, The effect of meeting high performance requirements

Pending Publication Date: 2021-03-16
ZIBO CHANGAN CERAMIC TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

And the glaze hardness is not high, poor wear resistance and corrosion resistance
Therefore, the existing ceramic glaze formulations are difficult to meet the performance requirements of engineering ceramics and bioceramics with higher requirements

Method used

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  • Ultrahigh-temperature wear-resistant corrosion-resistant ceramic glaze and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] According to the proportion of raw materials, 46% of quartz powder, 12% of potassium feldspar, 8% of kaolin, 15% of wollastonite, and 8% of alumina are weighed and added to the ball mill with high alumina lining and high alumina balls, and the above mixture is added Water ball milling with 50% mass for 24 hours, then add 1% lanthanum oxide, 2% molybdenum trioxide, 1% cerium oxide, 5% zirconium dioxide, and 2% yttrium trioxide, according to the ratio of 1:1 by weight of the above raw materials Add corresponding water, and then ball mill for 8 hours. The particle size of the glaze is controlled to be less than 0.05% on a 325 mesh sieve. Remove iron from the mill and sieve. Apply glaze to the 90 alumina ceramic body by spraying method, the glaze thickness is 25μm, and fire at 1480±10°C for 2 hours.

Embodiment 2

[0019] According to the raw material ratio of 52% quartz powder, 8% potassium feldspar, 7% kaolin, 7% wollastonite, and 12% alumina, weigh each material and add it to a ball mill with high alumina lining and zirconia balls, and add the above mixture 52% by weight of water ball mill for 22 hours, then add 2% of lanthanum oxide, 3% of molybdenum trioxide, 2% of cerium oxide, 6% of zirconium dioxide, and 1% of diyttrium trioxide, according to the ratio of 1:1 by weight of the above raw materials Add corresponding water, and then ball mill for 6 hours to control the particle size of the glaze to be less than 0.05% on a 325 mesh sieve. Remove iron from the mill and sieve. Apply glazing on the 95 alumina ceramic body by spraying method, the glazing thickness is about 15μm, and fire at 1560±10℃ for 1 hour.

Embodiment 3

[0021] According to the proportion of raw materials, 40% of quartz powder, 15% of potassium feldspar, 11% of kaolin, 10% of wollastonite, and 6% of alumina are weighed and added to a ball mill with high alumina lining and zirconia balls, and the above mixture is added 45% by weight of water ball mill for 26 hours, then add 1% of lanthanum oxide, 6% of molybdenum trioxide, 1% of cerium oxide, 8% of zirconium dioxide, and 2% of diyttrium trioxide, according to the ratio of 1:1 by weight of the above raw materials Add corresponding water, and then ball mill for 6 hours to control the particle size of the glaze to be less than 0.05% on a 325 mesh sieve. Remove iron from the mill and sieve. Apply glaze to the 90 alumina ceramic body by spraying method, the glaze thickness is about 35μm, and fire at 1500±10°C for 3 hours.

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Abstract

The invention belongs to the technical field of ceramic glazes, and particularly relates to an ultrahigh-temperature wear-resistant corrosion-resistant ceramic glaze and a preparation method and application thereof. The ceramic glaze is prepared from quartz powder, potassium feldspar, kaolin, wollastonite, aluminum oxide, lanthanum oxide, molybdenum trioxide, cerium dioxide, zirconium dioxide andyttrium oxide. The ceramic glaze has a wide glaze firing range, can be fired at a high temperature of 1450-1600 DEG C, has a high use temperature, and can be used at a temperature of 1250 DEG C or below. By introducing lanthanum oxide, molybdenum trioxide, cerium dioxide, zirconium dioxide, yttria and other components, the microstructure of the ceramic glaze layer is effectively improved, the hardness of the ceramic glaze layer is enhanced, the wear resistance and the corrosion resistance of the glaze layer are improved, the firing range of the glaze is widened, the friction coefficient of theglaze layer is reduced, and the frictional resistance of ceramics is reduced. The high-performance requirements of wear resistance and corrosion resistance of ceramic products such as engineering ceramics and biological ceramics are met.

Description

technical field [0001] The invention belongs to the technical field of ceramic glazes, and in particular relates to an ultra-high temperature wear-resistant and corrosion-resistant ceramic glaze and its preparation method and application. Background technique [0002] The ceramic glaze layer refers to a layer of amorphous glassy substance formed on the surface of the body after the ceramic glaze is glazed on the body of the body after high-temperature melting. Easy to clean and protect ceramic products. [0003] At present, ceramic glazes with a firing temperature between 1250°C and 1380°C are generally called high-temperature glazes, which are usually prepared from quartz, feldspar, kaolin, calcium carbonate, aluminum oxide, zinc oxide, etc. Their softening point They are all below 1100°C, and the operating temperature cannot be higher than 1100°C. And the hardness of the glaze is not high, and the wear resistance and corrosion resistance are poor. Therefore, the existin...

Claims

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Application Information

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IPC IPC(8): C03C8/00C04B41/86
CPCC03C8/00C04B41/009C04B41/5022C04B41/86C04B35/10
Inventor 姜丽玮陈晨姜兆岭陈绍平
Owner ZIBO CHANGAN CERAMIC TECH
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