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High-performance flame-retardant self-cleaning daylighting panel material easy to melt and break and free of dripping and production process thereof

A lighting board, high-performance technology, applied in the production of bulk chemicals, coating, etc., can solve the problems of low mechanical properties, easy dripping, and high material cost of lighting boards, and achieve increased stain resistance and aesthetics. The effect of uniform distribution and improvement of limiting oxygen index

Active Publication Date: 2021-04-02
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are still many deficiencies in the existing daylighting panel materials: first, due to the flammability of polymer materials, it is very likely to form passive fires under external fire conditions, such as fireworks, cigarette butts falling, and There is a risk of fire caused by electrical short circuit and other situations; second, after a fire occurs, the lighting panel is not easy to melt, so a large amount of toxic smoke cannot be released in time, which can easily cause a large number of casualties
However, the fusible lighting panel technology is mainly monopolized by foreign companies, usually prepared from modified polyester materials, the material cost is high, and the fusible performance is not ideal (it needs to be around 150°C to start melting)
If ordinary low-melting point polymers are used as the base material of the fusible daylighting sheet, it will lead to problems such as low mechanical properties and easy dripping of the daylighting sheet, which cannot meet the requirements of use
At the same time, because the lighting panels are usually located on the top of the building and other places that are not easy to clean manually, after a certain period of use, they will often be polluted by water stains, dust, etc., which will affect the lighting and aesthetics.

Method used

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  • High-performance flame-retardant self-cleaning daylighting panel material easy to melt and break and free of dripping and production process thereof
  • High-performance flame-retardant self-cleaning daylighting panel material easy to melt and break and free of dripping and production process thereof
  • High-performance flame-retardant self-cleaning daylighting panel material easy to melt and break and free of dripping and production process thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] A self-cleaning flame-retardant lighting board that is easy to melt and not drip, comprising the following components in mass percentage:

[0040] 30% low-density polyolefin, 20% polypropylene, 5% ethylene wax, 20% intumescent flame retardant (ammonium polyphosphate and triazine char-forming agent with a mass ratio of 1:1), 20% glass fiber, Malay Anhydride grafted polyethylene 3%, antioxidant 1618 0.5%, antioxidant 1010 0.5%, silicone powder 1%, wherein, the surface of the lighting board prepared by the above components is coated with a 0.8 μm transparent super-amphiphobic coating ,

[0041] Its production process includes the following steps:

[0042] Step 1. According to the above formula of a high-performance flame-retardant lighting board that is easy to melt and not drip, weigh each component and dry it for later use;

[0043] Step 2, mixing low-density polyolefin, polypropylene, ethylene wax, intumescent flame retardant, maleic anhydride grafted polyethylene, an...

Embodiment 2

[0050] A high-performance flame-retardant lighting board that is easy to melt and not drip, including the following components in mass percentage:

[0051] 20% low-density polyolefin, 20% polypropylene, 10% ethylene vinyl acetate copolymer, 5% ethylene wax, 20% intumescent flame retardant (ammonium polyphosphate and triazine char-forming agent with a mass ratio of 1:1) , glass fiber 20%, maleic anhydride grafted polyethylene 3%, antioxidant 1618 0.5%, antioxidant 1010 0.5%, silicone powder 1%, wherein, the surface of the lighting board prepared by the above components is coated with 0.8μm transparent superamphiphobic coating;

[0052] Its production technology is with embodiment 1.

Embodiment 3

[0054] A high-performance flame-retardant lighting board that is easy to melt and not drip, including the following components in mass percentage:

[0055] 25% low-density polyolefin, 15% polypropylene, 5% ethylene wax, 22% intumescent flame retardant (ammonium polyphosphate and triazine char-forming agent with a mass ratio of 1:1), 28% glass fiber, Malay Anhydride grafted polyethylene 3%, antioxidant 1618 0.5%, antioxidant 1010 0.5%, silicone powder 1%, wherein, the surface of the lighting board prepared by the above components is coated with a 0.8 μm transparent super-amphiphobic coating ;

[0056] Its production technology is with embodiment 1.

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Abstract

The invention discloses a high-performance flame-retardant self-cleaning daylighting panel material easy to melt and break and free of dripping and a production process thereof. The production processcomprises the following steps: taking and drying polyolefin resin, low-melting-point resin, a flame retardant, a compatilizer, an antioxidant and a lubricant, and mixing to obtain a mixture; adding the mixture from a main feeding port of a screw extruder, adding continuous fibers by adopting a melt impregnation method or adding non-continuous fibers through a side feeding port of the extruder, performing extrusion granulation to obtain a glass fiber reinforced polyolefin flame-retardant composite material, and performing extrusion molding through a multi-roll calender to obtain the high-performance flame-retardant daylighting panel which is easy to melt and break and free of dripping. The daylighting panel disclosed by the invention has fusible breaking performance, and can be automatically broken within a temperature range of 100-150 DEG C, so that escape of toxic smoke is facilitated, and the purpose of reducing casualties is achieved. Meanwhile, due to the addition of the reinforcing fibers, the material has higher melt strength and cannot be molten and drop within a melting breaking temperature range.

Description

technical field [0001] The invention belongs to the technical field of fusible daylighting boards, in particular to a fusible non-dripping high-performance flame-retardant daylighting board and a production process thereof. Background technique [0002] Daylighting board refers to a light-transmitting sheet material used to replace opaque materials for building roofs. It is now widely used in industrial production workshops, storage warehouses, commercial buildings, airports, gymnasiums, and bio-based buildings in villages and towns. At present, most daylighting panels are made of polycarbonate, glass fiber reinforced epoxy resin and other materials, which have the characteristics of light weight, light transmission, easy installation, and beautiful appearance. However, there are still many deficiencies in the existing daylighting panel materials: first, due to the flammability of polymer materials, it is very likely to form passive fires under external fire conditions, such...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/00C08L23/12C08L23/06C08L51/06C08L83/04C08L23/08C08L23/28C08K13/04C08K7/14C08K3/32C08K5/3492C08K5/526C08K5/134C08K13/06C08K9/02C08K9/04C08J5/18C08J5/04C08J5/08C08J7/06
CPCC08J5/043C08J5/08C08J5/18C08J7/042C08J2323/00C08J2323/12C08J2423/06C08J2423/08C08J2423/12C08J2423/28C08J2451/06C08J2483/04C08K5/1345C08K5/3492C08K5/526C08K7/14C08K9/02C08K9/04C08K9/08C08K13/04C08K13/06C08K2003/323C08J7/0427Y02P20/54
Inventor 赵泽永王玉忠邓聪王子晟
Owner SICHUAN UNIV
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