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Irradiation crosslinking chlorinated polyether rubber heat shrinkable tube and preparation method thereof

A technology of chlorinated polyether and heat-shrinkable tubes, which is applied in the field of heat-shrinkable tubes, can solve the problems of high comprehensive input cost and poor anti-aging performance, and achieve the effects of reducing comprehensive input costs, good anti-aging performance, and satisfying the use

Pending Publication Date: 2021-04-16
CHANGYUAN ELECTRONICS DONGGUAN +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the embodiments of the present invention is to provide a heat-shrinkable tube of radiation-crosslinked chlorinated polyether rubber, which aims to solve the technical problems of poor aging resistance and high comprehensive investment cost in existing heat-shrinkable tubes

Method used

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  • Irradiation crosslinking chlorinated polyether rubber heat shrinkable tube and preparation method thereof
  • Irradiation crosslinking chlorinated polyether rubber heat shrinkable tube and preparation method thereof
  • Irradiation crosslinking chlorinated polyether rubber heat shrinkable tube and preparation method thereof

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preparation example Construction

[0022] The embodiment of the present invention also provides a kind of preparation method of radiation cross-linked chlorinated polyether rubber heat-shrinkable tube, specifically comprising:

[0023] Weigh the raw materials according to the following parts by weight: 85-95 parts of chlorinated polyether rubber, 5-15 parts of chlorinated resin, 30-50 parts of flame retardant, 10-25 parts of flame retardant synergist, and 2-25 parts of antioxidant. 5 parts, 2-5 parts of light stabilizer, 2-5 parts of lubricant, 2-3 parts of cross-linking agent and 1-2.5 parts of toner;

[0024] Add the above components into a high-speed mixer, and mix at a high speed for 5-10 minutes;

[0025] Using the internal mixer or twin-screw extruder to generate the master batch under the condition of 90~170℃;

[0026] Extruding the above-mentioned masterbatch through a single-screw extruder at a temperature of 80-150°C;

[0027] Irradiate the above-mentioned extruded pipe with an electron accelerator,...

Embodiment 1

[0033] The raw materials are weighed according to the following parts by weight: 90 parts of chlorinated polyether rubber (90 kg of copolymerized chloroether rubber), 10 parts of chlorinated resin (10 kg of chlorinated polyvinyl chloride resin), 40 parts of flame retardant ( Specifically, 20kg of decabromodiphenylethane, 20kg of diethylaluminum hypophosphite), 20 parts of flame retardant synergists (specifically, 10kg of zinc borate and 10kg of antimony trioxide), and 4 parts of antioxidant (specifically, antioxidant). agent 10102kg, antioxidant Ky4052kg), 5 parts of light stabilizer (specifically take three (1,2,2,6,6-pentamethylpiperidinyl) phosphite (brand name: GW540) 5kg), lubricant 5 Parts (specifically get methyl silicone oil 2kg, ethylene bis-stearamide 3kg), 3 parts of cross-linking agents (specifically get trimethylolpropane trimethacrylate 3kg) and 2 parts of color powder (specifically get N110 carbon black 2kg) );

[0034] First add the copolymerized chloroether r...

Embodiment 2

[0040] The raw materials are weighed according to the following parts by weight: 90 parts of chlorinated polyether rubber (90 kg of copolymerized chloroether rubber), 10 parts of chlorinated resin (10 kg of chlorinated polyvinyl chloride resin), 35 parts of flame retardant ( Specifically, 20kg of decabromodiphenylethane, 15kg of diethylaluminum hypophosphite), 15 parts of flame retardant synergist (specifically, 10kg of zinc borate, 5kg of antimony trioxide), 4 parts of antioxidant (specifically, antioxidant agent 10762kg, antioxidant Ky4052kg), 4 parts of light stabilizer (specifically take three (1,2,2,6,6-pentamethylpiperidinyl) phosphite (brand name: GW540) 4kg), lubricant 5 Parts (specifically get methyl silicone oil 2kg, ethylene bis-stearamide 3kg), 2 parts of crosslinking agents (specifically get trimethylolpropane trimethacrylate 2kg) and 2.5 parts of toners (specifically get N110 carbon black 2.5 kg);

[0041] First add the above components into a high-speed mixer, ...

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Abstract

The invention is applicable to the technical field of heat shrinkable tubes, and provides an irradiation crosslinking chlorinated polyether rubber heat shrinkable tube and a preparation method thereof. The heat shrinkable tube is prepared from the following components in parts by weight: 85-95 parts of chlorinated polyether rubber, 5-15 parts of chlorinated resin, 30-50 parts of a flame retardant, 10-25 parts of a flame retardant synergist, 2-5 parts of an antioxidant, 2-5 parts of a light stabilizer, 2-5 parts of a lubricant, 2-3 parts of a cross-linking agent and 1-2.5 parts of toner. The chlorinated polyether rubber base material adopted by the invention is highly saturated in structure, not easy to decompose when heated and good in ageing resistance, and the chloromethyl side chain can provide crosslinking, so that the strength, solvent resistance and other properties of the heat shrinkable tube can be improved; meanwhile, the added chlorinated resin and chlorinated polyether rubber are blended, so that performance complementation is facilitated, the heat shrinkable tube with excellent high-temperature resistance, low-temperature resistance, aging resistance, oil resistance, corrosion resistance and solvent resistance is obtained, and the heat shrinkable tube can be used in a harsh environment; in addition, the comprehensive investment cost is also reduced.

Description

technical field [0001] The invention belongs to the technical field of heat-shrinkable tubes, and in particular relates to a radiation-crosslinked chlorinated polyether rubber heat-shrinkable tube and a preparation method thereof. Background technique [0002] Heat shrinkable tube has the advantages of softness, flame retardant, fast shrinkage, stable performance, etc. It is widely used in wire connection, wire end treatment wire harness, solder joint protection, electronic device protection and insulation treatment, fitness equipment parts and steel structure surface protection Wait. [0003] Traditional heat-shrinkable tubes mostly use polyolefin materials as the base material, but the heat-shrinkable tubes made of polyolefin-based materials have defects such as oil resistance, high temperature resistance, and low temperature resistance, which limit their use in harsh environments. In order to make up for the above-mentioned defects of heat-shrinkable tubes, in recent yea...

Claims

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Application Information

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IPC IPC(8): C08L71/03C08L27/24C08K13/02C08K5/03C08K5/5313C08K3/38C08K3/22C08K5/524C08K5/103
Inventor 谢世平田冠楠李菁刘晓播
Owner CHANGYUAN ELECTRONICS DONGGUAN