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Method for treating inner surface of hydrocarbon cracking furnace tube

A technology for hydrocarbon cracking furnace tubes and cracking furnace tubes, which is applied in the field of treating the inner surface of hydrocarbon cracking furnace tubes, and can solve problems such as deposition reduction, and achieve the effects of increased surface roughness, densification and peeling, and improved compactness

Active Publication Date: 2022-05-24
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The purpose of the present invention is to provide a method for processing the inner surface of the hydrocarbon cracking furnace tube in order to overcome the coking problem existing in the prior art inside the hydrocarbon cracking furnace tube. The oxide protective layer is thinner and not easy to peel off, so that the deposition of coke on the inner surface of the split tube furnace is significantly reduced, and the service life of the oxide protective layer obtained by using this method is longer, which can meet the requirements of long-term use and repeated heating of cracking furnace tubes. Waiting for needs

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  • Method for treating inner surface of hydrocarbon cracking furnace tube
  • Method for treating inner surface of hydrocarbon cracking furnace tube
  • Method for treating inner surface of hydrocarbon cracking furnace tube

Examples

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Effect test

Embodiment 1

[0097] A new furnace tube with the same size and material as Comparative Example 1 was used, and the furnace tube was coated according to the method of the present invention. First, extrude and grind the furnace tube according to the method of Comparative Example 4, and then let the furnace tube in pure H 2 In an atmosphere of normal pressure, the cracking furnace tube was heated to 1150 °C at a heating rate of 40 °C / h, and then the furnace tube was cooled to 450 °C at a cooling rate of 40 °C / h; The furnace tube was heated to 1000°C, and finally the furnace tube was treated according to the two-stage low oxygen partial pressure method. In the first stage, let the furnace tube be at a pressure of 0.3MPa, H 2 H with a molar ratio of 4000 to water vapor 2 -H 2 In the low oxygen partial pressure atmosphere, the temperature was kept at 1000 °C for 10 hours; in the second stage, the furnace tube was kept at a pressure of 0.4MPa, H 2 H with a molar ratio of 100 to water vapor 2 ...

Embodiment 2

[0100] A new furnace tube with the same size and material as Comparative Example 1 was used, and the furnace tube was coated according to the method of the present invention. The furnace tube was first extruded and ground according to the following conditions: (1) abrasive formula, 83% silicon carbide (400 mesh) + 17% vaseline; (2) extrusion grinding pressure, 2MPa; (3) extrusion grinding time, 500 seconds. Then let the furnace tube in pure H 2 In an atmosphere of normal pressure, the cracking furnace tube was heated to 1120 °C at a heating rate of 60 °C / h, and then the furnace tube was cooled to 400 °C at a cooling rate of 60 °C / h; The furnace tube was heated to 1050°C, and finally the furnace tube was treated according to the two-stage low oxygen partial pressure method. In the first stage, let the furnace tube be at a pressure of 0.3MPa, H 2 H with a molar ratio of 4000 to water vapor 2 -H 2 In the second stage, the furnace tube was kept at a pressure of 0.5MPa, H 2 H...

Embodiment 3

[0103] A new furnace tube with the same size and material as Comparative Example 1 was used, and the furnace tube was coated according to the method of the present invention. The furnace tube was first extruded and ground according to the following conditions: (1) abrasive formula, 83% silicon carbide (400 mesh) + 17% vaseline; (2) extrusion grinding pressure, 2MPa; (3) extrusion grinding time, 500 seconds. Then let the furnace tube in pure H 2 In an atmosphere of normal pressure, the cracking furnace tube was heated to 1160 °C at a heating rate of 80 °C / h, and then the furnace tube was cooled to 480 °C at a cooling rate of 100 °C / h; The furnace tube was heated to 900°C, and the furnace tube was treated according to the two-stage low oxygen partial pressure method. In the first stage, let the furnace tube be at a pressure of 0.4MPa, H 2 H with a molar ratio of 5000 to water vapor 2 -H 2 In the second stage, the furnace tube was kept at a pressure of 0.35MPa, H 2 H with a...

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Abstract

The invention relates to the field of petrochemical industry, and discloses a method for treating the inner surface of a hydrocarbon cracking furnace tube, wherein the method comprises the following steps: (1) Extruding and grinding the inner surface of a hydrocarbon cracking furnace tube to obtain a pretreatment cracking Furnace tube; (2) under normal pressure, in H 2 In the atmosphere, the pretreatment cracking furnace tube is heat treated to obtain the heat treatment cracking furnace tube; (3) under pressurized conditions, in the presence of the treatment gas, the inner surface of the heat treatment cracking furnace tube is subjected to the first oxidation treatment and the second oxidation treatment. The method can form a dense, thinner and less prone to peeling oxide protective layer on the inner surface of the hydrocarbon cracking furnace tube, so that the deposition of coke on the inner surface of the split tube furnace is significantly reduced, and the obtained oxide protective layer is treated by this method The service life is longer, which can meet the needs of long-term use and repeated heating of cracking furnace tubes.

Description

technical field [0001] The invention relates to the petrochemical field, in particular to a method for treating the inner surface of a hydrocarbon cracking furnace tube. Background technique [0002] Ethylene is one of the main products of the petrochemical industry. The trienes (ethylene, propylene, butene) and triphenyls (benzene, toluene, xylene) produced by the ethylene plant are the basic raw materials of the petrochemical industry. At present, the method of producing ethylene is mainly based on the tubular furnace cracking technology. [0003] However, when the hydrocarbon feedstock is thermally cracked at high temperature to produce ethylene, coke will be formed on the inner surface of the furnace tube in the radiant section of the tubular cracking furnace. The coke formed at high temperature is a poor conductor of heat, which will increase the heat transfer resistance of the furnace tube and reduce the inner diameter of the furnace tube, resulting in an increase in ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G9/20C10G9/16C23C8/16C22C30/00C22C27/06C22C19/05B24B31/116C07C4/04C07C11/04
CPCC10G9/20C10G9/16C23C8/16C22C19/058C22C27/06C22C30/00C22C19/052B24B31/116C07C4/04C07C11/04
Inventor 王申祥柳颖王红霞郏景省王国清张利军
Owner CHINA PETROLEUM & CHEM CORP