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Preparation method of high-temperature molten salt pipeline

A high-temperature molten salt and pipeline technology, applied in pipeline protection, pipeline protection through heat insulation, pipeline anticorrosion/rust protection, etc., can solve the problems of high requirements for pipelines, and achieve low void ratio, high pressure resistance, and light weight Effect

Pending Publication Date: 2021-05-11
SHANGHAI INST OF APPLIED PHYSICS - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In order to solve the problem that high-temperature molten salt has high requirements on pipelines in the prior art, the present invention provides a method for preparing high-temperature molten salt pipelines

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] According to the shape of the control rod casing, process a graphite core material with a length of 3000mm, an inner diameter of 60mm, an outer diameter of 70mm, a U-shaped bottom and an open upper part.

[0022] Set the density to 1.80g / cm 3 The high-purity graphite core material is used as the substrate, and then trichloromethylsilane (MTS) is used as the precursor raw material, hydrogen is used as the carrier gas, and argon is used as the diluent gas to deposit a layer of 2mm carbonization by chemical vapor phase in the range of 950-1300 ° C. Silicon impermeable layer.

[0023] Using T700 grade carbon fiber as a reinforcement, the carbon fiber impregnated with phenolic resin is used to uniformly wind the core material of the silicon carbide coating through the numerical control fiber winding machine. The winding temperature range is 25-40°C, the tension is 3-5kg, and the angle is 0° 25°, winding thickness 5-6mm, the resin used is thermosetting phenolic resin.

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Embodiment 2

[0028] The passing density is 2.0g / cm 3 A graphite tube with an outer diameter of 100mm and an inner diameter of 80mm is made of high-purity graphite material.

[0029] Put the graphite tube into the deposition furnace, and use methane as the carbon source to generate the pyrolytic carbon anti-seepage layer. In the temperature range of 1000-1500°C, methane flow rate of 300-800ml / min, and pressure of 6-12KPa, a pyrolytic carbon coating of 2-3mm is formed after 4-6h.

[0030] T1000 grade carbon fiber is selected as the reinforcement, and the carbon fiber is wound on the surface of the prepared pyrolytic carbon coated graphite through a numerical control fiber winding machine. The winding temperature range is 25-40°C, the tension is 5-10kg, the angle is 85°-90°, and the winding thickness 5-6mm.

[0031] Put the wrapped product into the autoclave to impregnate the phenolic resin at a pressure of 2-5MPa for 6-10 hours, and cure the impregnated sample at a pressure of 1-2MPa and a...

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PUM

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Abstract

The invention relates to a preparation method of a high-temperature molten salt pipeline. The preparation method comprises the following steps of S1, processing graphite to form a lining, S2, forming a uniform and compact impermeable layer on the outer surface of the lining through a chemical vapor deposition method, S3, uniformly winding the carbon fiber impregnated with the phenolic resin on the impermeable layer as a carbon fiber reinforcing material to obtain a first product, S4, curing the first product to obtain a second product, and S5, enabling the second product to be subjected to carbonization and graphitization treatment, and acquiring the high-temperature molten salt pipeline. According to the preparation method of the high-temperature molten salt pipeline, the graphite pipeline is reinforced by adopting the carbon fibers, and the pipeline has a good anti-seepage effect by adopting the anti-seepage interlayer.

Description

technical field [0001] The invention relates to the field of high-temperature molten salt energy storage, and more particularly relates to a preparation method of a high-temperature molten salt pipeline. Background technique [0002] Molten salt is a good heat carrier, and it has been widely used in energy and chemical fields in recent years, such as molten salt reactors, molten salt energy storage, and molten salt heat treatment. Due to the high melting point and strong corrosiveness of molten salt, there are many difficulties to be overcome in the use of general alloys as pipes, especially in the application of molten salt in the field of ultra-high temperature. [0003] Carbon materials are widely used in the chemical industry due to their excellent heat resistance, low thermal expansion coefficient, and excellent thermal shock resistance. It is an inevitable trend to apply the excellent performance of carbon materials in the field of ultra-high temperature molten salt. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/52C04B41/87C04B35/83F16L9/14F16L58/00F16L59/02
CPCC04B35/522C04B41/87C04B41/009C04B41/5059C04B35/83F16L9/14F16L58/00F16L59/02C04B2235/48C04B2235/96C04B41/4531
Inventor 贺周同黄波
Owner SHANGHAI INST OF APPLIED PHYSICS - CHINESE ACAD OF SCI