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Preparation method of superfine dolomite and application of superfine dolomite

A dolomite and fine powder technology, applied in chemical instruments and methods, inorganic chemistry, calcium/strontium/barium compounds, etc., can solve the problems of easy agglomeration of ultrafine powder, small application range, and difficulty in uniform dispersion

Inactive Publication Date: 2021-07-13
铜陵博锋实业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In order to overcome the above-mentioned technical problems, the object of the present invention is to provide a preparation method of ultrafine dolomite and the application of ultrafine dolomite: by pulverizing dolomite and sieving to obtain dolomite coarse powder, the dolomite coarse powder , adding grinding aid to water, stirring evenly to obtain dolomite slurry, adding the dolomite slurry to the peeling machine for ultra-fine peeling to obtain ultra-fine slurry, dehydrating, drying, and pulverizing the ultra-fine slurry to obtain dolomite Fine powder, add dolomite fine powder and calcium hydroxide solution into a four-necked flask equipped with a stirrer, then place the four-necked flask in a constant temperature water bath, add crystal form control agent while stirring, and then pass into the three-necked flask The mixed gas of air and carbon dioxide continues to stir and react. When the pH is equal to 7, the reaction is stopped, and the reaction solution is spray-dried to form a powder to obtain the ultrafine dolomite, which solves the problem of the large particle size of the existing dolomite powder. The range is small, and the ultrafine powder is easy to agglomerate and difficult to disperse evenly

Method used

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  • Preparation method of superfine dolomite and application of superfine dolomite

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Embodiment 1

[0039] Present embodiment is a kind of grinding aid, and the preparation process of described grinding aid comprises the following steps:

[0040] S1: Add phenol to a three-necked flask equipped with a condenser and a stirrer, then add octanoic acid and triethanolamine, and place the three-necked flask in a constant temperature oil bath at a temperature of 130°C and a stirring speed of 100r / min Stirring and reacting for 7 hours until the water is completely discharged, the crude product of intermediate 1 is obtained; the molar ratio of octanoic acid and triethanolamine is 1.6:1.0, and the dosage ratio of octanoic acid and phenol is 1g:5mL;

[0041]S2: Dissolve the crude product of intermediate 1 in isooctane to obtain the crude product solution of intermediate 1, wash the crude product solution of intermediate 1 with aqueous sodium hydroxide solution and distilled water three times respectively, and remove unreacted octanoic acid, triethanolamine and phenol , and then the crud...

Embodiment 2

[0045] Present embodiment is a kind of grinding aid, and the preparation process of described grinding aid comprises the following steps:

[0046] S1: Add phenol to a three-necked flask equipped with a condenser and a stirrer, then add octanoic acid and triethanolamine, and place the three-necked flask in a constant temperature oil bath at a temperature of 135°C and a stirring speed of 150r / min Stirring and reacting for 8 hours, until the water is completely discharged, the crude product of intermediate 1 is obtained; the molar ratio of octanoic acid and triethanolamine is 1.6:1.0, and the dosage ratio of octanoic acid and phenol is 1g:8mL;

[0047] S2: Dissolve the crude product of intermediate 1 in isooctane to obtain the crude product solution of intermediate 1, wash the crude product solution of intermediate 1 with sodium hydroxide aqueous solution and distilled water 4 times respectively, and remove unreacted octanoic acid, triethanolamine and phenol , and then the crude ...

Embodiment 3

[0051] Present embodiment is a kind of grinding aid, and the preparation process of described grinding aid comprises the following steps:

[0052] S1: Add phenol to a three-necked flask equipped with a condenser and a stirrer, then add octanoic acid and triethanolamine, and place the three-necked flask in a constant temperature oil bath at a temperature of 140°C and a stirring speed of 200r / min Stirring and reacting for 9 hours until the water is completely discharged, the crude product of intermediate 1 is obtained; the molar ratio of octanoic acid and triethanolamine is 1.6:1.0, and the dosage ratio of octanoic acid and phenol is 1g:10mL;

[0053] S2: Dissolve the crude intermediate 1 in isooctane to obtain the crude intermediate 1 solution, wash the crude intermediate 1 solution with sodium hydroxide aqueous solution and distilled water 5 times respectively, and remove unreacted octanoic acid, triethanolamine and phenol , and then the crude product solution of Intermediate ...

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Abstract

The invention discloses a preparation method of superfine dolomite and application of the superfine dolomite, and relates to the technical field of dolomite processing. The preparation method comprises the steps: crushing dolomite, and screening to obtain dolomite coarse powder; adding the dolomite coarse powder and a grinding aid into water, and uniformly stirring to obtain dolomite slurry; adding the dolomite slurry into a stripping machine, and carrying out superfine stripping to obtain superfine slurry; dehydrating, drying and crushing the superfine slurry to obtain dolomite fine powder; adding the dolomite fine powder and a calcium hydroxide solution into a four-neck flask provided with a stirrer, then putting the four-neck flask into a constant-temperature water bath, and adding a crystal form control agent while stirring; and then introducing mixed gas of air and carbon dioxide into a three-neck flask for continuous stirring reaction, carrying out spray drying on the reaction liquid, forming powder, and thus obtaining the superfine dolomite. The problems that existing dolomite powder is large in particle size and small in application range, and superfine powder is prone to agglomeration and not prone to uniform dispersion are solved.

Description

technical field [0001] The invention relates to the technical field of dolomite processing, in particular to a method for preparing ultrafine dolomite and the application of ultrafine dolomite. Background technique [0002] Dolomite is a common white non-metallic mineral belonging to CaCO 3 and MgCO 3 The composite carbonate minerals in my country are extremely rich in reserves and are an important calcium and magnesium resource. Dolomite has been widely used as a filler in papermaking, coatings, plastics, rubber, adhesives and other industries. [0003] At present, ultra-fine dolomite has not been applied yet. The existing dolomite is generally tens to hundreds of mesh, and the finest is no more than 1000 mesh, so the application of dolomite is also limited. [0004] At present, the physical pulverization method has become the most widely used method for producing ultrafine powder materials due to its advantages of low cost, simple production process and large output. T...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01F11/18C01F5/24
CPCC01F11/185C01F5/24C01P2004/82
Inventor 何飞
Owner 铜陵博锋实业有限公司
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