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Environment-friendly anti-freezing concrete and preparation method thereof

A concrete and environmentally friendly technology, applied in the field of building materials, can solve the problems affecting the safety and durability of concrete structures, and accelerate the deterioration of concrete structure performance, strength and impermeability, so as to improve impermeability and frost resistance, improve Antifreeze performance, effect of improving compactness

Inactive Publication Date: 2021-07-23
青岛圣丰智能自动化设备有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Concrete freeze-thaw damage is a common disease in concrete structure engineering in cold areas, especially in coastal areas, where the wind is strong and the temperature is low, and the concrete structures that are often in contact with water suffer from different degrees of freeze-thaw damage locally or in large areas, which will accelerate Deterioration of concrete structure performance seriously affects the structural safety and durability of concrete
[0004] At present, there are two main measures to improve the frost resistance of concrete. One is to add air-entraining agents to generate a large number of pores inside the concrete to relieve the ice expansion stress caused by the solid-liquid phase transition of water. However, due to the existence of a large number of pores, the concrete The compactness of the water decreases, and the strength and impermeability become worse. The other is to lower the freezing point of water by adding some salts to the admixture. There is no freezing at minus a few degrees, and it is not suitable for the underwater environment in the lower temperature areas such as the west and the north

Method used

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  • Environment-friendly anti-freezing concrete and preparation method thereof
  • Environment-friendly anti-freezing concrete and preparation method thereof
  • Environment-friendly anti-freezing concrete and preparation method thereof

Examples

Experimental program
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Effect test

preparation example 1

[0039] Preparation example 1: Crush 10kg of egg shells, add 240L of water with a concentration of 36%, then add 24L of acetic acid with a concentration of 36%, keep it at 45°C for 1.5h, then let it stand at room temperature for 24h, filter, wash with water, and dry at 60°C for 1.5h , chopped, added 10L of sulfuric acid with a concentration of 20%, heated to 80° C. for reflux extraction for 5 hours, added 3 kg of calcium carbonate, filtered, spray-dried, and crushed to 1 μm to obtain eggshell membranes.

preparation example

[0041] In Preparation Example 1-4, the modified carboxymethyl starch was selected from Renqiu Haochun Chemical Co., Ltd., model 021, the graphene oxide was selected from Hangzhou Zhiti Purification Technology Co., Ltd., and the urea was selected from Beijing Kangpu Huiwei Technology Co., Ltd. Co., Ltd., the model is 012, and the cellulose is carboxymethyl cellulose selected from Renqiu Jinyu Chemical Co., Ltd., the model is jy-006.

[0042] Preparation example 1: (1) Mix 10kg of graphene oxide and 5kg of modified starch, and disperse it ultrasonically for 1.5h at a power of 600W to obtain a graphene oxide / modified starch intercalation composite material. The modified starch is modified carboxylated starch methyl starch;

[0043] (2) Dissolve 2.5kg urea and 2.5kg sodium hydroxide in water respectively to form a 12% urea solution and a 7% sodium hydroxide solution, mix the urea solution and the sodium hydroxide solution, and add graphene oxide / Modified starch intercalation com...

preparation example 2

[0046] Preparation example 2: (1) Mix 13kg graphene oxide and 8kg modified starch, and disperse it ultrasonically for 1.8h at a power of 550W to obtain a graphene oxide / modified starch intercalation composite material. The modified starch is modified carboxylated starch methyl starch;

[0047] (2) Dissolve 3.7kg urea and 3.2kg sodium hydroxide in water respectively to form a urea solution with a concentration of 12% and a sodium hydroxide solution with a concentration of 7%, mix the urea solution and the sodium hydroxide solution, and add graphene oxide / Modified starch intercalation composite material, ultrasonic 1.5h under the power of 450W, cooled to -13 ℃, add 6.5kg cellulose and 0.8kg 2-epoxy-3 chloropropane, stir well at room temperature, add 5.4kg egg Shell film and 3.7kg of iron tailings powder are added in a water bath at 28°C for 44 hours, dried at 65°C for 1.5 hours, and crushed to make antifreeze. The eggshell film is selected from Preparation Example 1 of eggshell...

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Abstract

The invention relates to the technical field of building materials, and particularly discloses environment-friendly anti-freezing concrete and a preparation method thereof. The environment-friendly anti-freezing concrete is prepared from the following components in parts by weight: 420 to 570 parts of cement, 572 to 656 parts of sand, 825 to 940 parts of stone, 170 to 210 parts of water, 51 to 70 parts of admixture, 58.8 to 80.6 parts of admixture, 40 to 60 parts of waste rubber particles and 45 to 60 parts of anti-freezing agent, the anti-freezing agent comprises the following components: modified starch, graphene oxide, iron tailing powder, eggshell membrane, sodium hydroxide, urea and cellulose; the preparation method comprises the following steps: adding the admixture and the antifreeze agent into water, and uniformly mixing to obtain a premix; mixing the cement, the sand, the stones, the admixture and the waste rubber particles, adding the premix, and uniformly mixing to obtain the environment-friendly anti-freezing concrete. The environment-friendly anti-freezing concrete has the advantages that waste rubber is recycled, the anti-freezing performance and the anti-seepage performance are high, and automobile exhaust can be purified.

Description

technical field [0001] The application relates to the technical field of building materials, more specifically, it relates to an environment-friendly frost-resistant concrete and a preparation method thereof. Background technique [0002] With the rapid development of my country's economy, environmental problems are becoming more and more serious, and the output of various wastes has increased sharply. Therefore, recycling wastes is an important way to protect natural resources and promote sustainable development. The output of waste tires in my country reached 330 million in 2015, and the recovery rate was only less than 50%. Recycling waste tires as raw materials for concrete production has a large amount of recycling and can improve the road performance of concrete. [0003] Concrete freeze-thaw damage is a common disease in concrete structure engineering in cold areas, especially in coastal areas, where the wind is strong and the temperature is low, and the concrete stru...

Claims

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Application Information

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IPC IPC(8): C04B28/04C04B20/02C04B20/10C04B24/38C04B111/20C04B111/27C04B18/22
CPCC04B28/04C04B20/023C04B20/1066C04B40/0046C04B2111/29C04B2111/27C04B2103/601Y02W30/91
Inventor 赵海任成成郑金龙
Owner 青岛圣丰智能自动化设备有限公司
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