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Bottom-top composite injection smelting reduction furnace for treating high-iron red mud

A technology of high-speed iron red mud and reduction furnace, which is applied in the direction of reducing gas emission, can solve the problems of low heat utilization rate and long equipment reduction time, and achieve the effects of improving reduction rate, strengthening melting reduction efficiency and reducing energy consumption.

Active Publication Date: 2021-07-30
NORTHEASTERN UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Although the above patents can reduce the red mud, the equipment is complex and the reduction time is long, and the heat utilization rate is low

Method used

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  • Bottom-top composite injection smelting reduction furnace for treating high-iron red mud

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Effect test

Embodiment 1

[0036] The reducing agent is coke, and the molar ratio of the carbon in the reducing agent to the iron oxide in the high-iron red mud is 1.5:1; the ratio of the calcium oxide in the added lime to the sum of the mass of silica and alumina in the high-iron red mud is 1.5:1 ; The added amount of fluorite is 8% of the added amount of calcium oxide. The reduction process temperature is 1650°C, and the reduction time is 20 minutes. After reduction, the iron reduction rate is 96.5%, and about 70% of the sodium oxide in the red mud is enriched in the flue gas for recovery.

Embodiment 2

[0038]The reducing agent is spent cathode carbon block, and the molar ratio of the carbon in the reducing agent to the iron oxide in the high-iron red mud is 6.5:1; 0.8:1; the added amount of fluorite is 15% of the added amount of calcium oxide. The reduction process temperature is 1350°C, and the reduction time is 120min. After reduction, the reduction rate of iron is 95.0%, and about 30% of the sodium oxide in the red mud is enriched in the flue gas for recovery.

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Abstract

The invention relates to the field of comprehensive utilization of red mud, in particular to a bottom-top composite injection smelting reduction furnace for treating high-iron red mud. The furnace comprises a horizontal furnace body, a vortex feed inlet, a bottom-top injection system, an overflow slag outlet, a siphon tap hole and a flue gas outlet, wherein the vortex charging port corresponds to the molten pool vortex area; the bottom-top composite injection system comprises a bottom spray gun and a top spray gun, wherein the bottom spray gun injects a gas reducing agent such as natural gas or coal gas to strengthen a multi-phase reaction process; the top spray gun sprays oxygen-enriched air and fuel combustion heat compensation, and simultaneously combusts CO released in the reduction process to keep the heat balance of the system; a siphon tap hole and the overflow slag hole are formed in the other end of the furnace body, so that continuous tapping and continuous deslagging are realized; and the flue gas outlet is formed in the upper part of the same end of the iron outlet and the slag outlet, and is connected with a flue gas boiler for recovering flue gas. According to the smelting reduction furnace, the smelting reduction efficiency can be improved, system energy is fully utilized, and continuous production of extracting iron from red mud is achieved.

Description

technical field [0001] The invention relates to the field of comprehensive utilization of red mud, in particular to a bottom-top compound injection smelting reduction furnace for processing high-iron red mud. [0002] technical background [0003] China is a big country of alumina, with an annual output of more than 70 million tons of alumina and a discharge of more than 100 million tons of red mud. With the depletion of China's aluminum resources, my country needs to import a large amount of high-iron gibbsite ore to produce alumina every year, and its use ratio is higher than 50%. The discharge of high-iron red mud is more than 60 million tons, of which iron oxide content is more than 30%. ~50%. [0004] For the comprehensive utilization device of high-speed iron Bayer red mud, relevant domestic researchers have carried out a lot of research work, such as Li Shiqi et al. published "a kind of ultra-fine grinding high-speed iron red mud fine reduction device, application numb...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21B13/00
CPCC21B13/0006C21B13/004C21B13/0073Y02P10/143
Inventor 张廷安吕国志豆志河郭军华刘燕张子木赫冀成
Owner NORTHEASTERN UNIV
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