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Multifunctional composite water purification filter element and preparation method and application thereof

A water purification filter element and multi-functional technology, applied in chemical instruments and methods, water pollutants, water/sewage treatment, etc., to achieve the effect of promoting catalytic decomposition, prolonging service life, and improving speed

Active Publication Date: 2021-08-03
BEIJING ORIGIN WATER FILM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to overcome the defects of the prior art, and to solve the problem of excess chlorine, heavy metals, bacteria and other pollutants in drinking water, to propose a method that can quickly eliminate residual chlorine in water, has good adsorption capacity for heavy metal ions, and can effectively inhibit A composite water purification filter element grown by bacteria, and it is expected that the filter element itself will not have the defect of elution of harmful metal ions (including but not limited to copper ions, zinc ions, silver ions, etc.), and it is cheap and easy to produce

Method used

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  • Multifunctional composite water purification filter element and preparation method and application thereof
  • Multifunctional composite water purification filter element and preparation method and application thereof
  • Multifunctional composite water purification filter element and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] Embodiment 1: Preparation of multifunctional composite filter element

[0043] Take 3g of activated carbon fibers with an average length / diameter of 1cm / 8μm and an average specific surface area / porosity of 1000m 2 / g / 0.35, limit the activated carbon to the hydrothermal reactor.

[0044] Weigh 0.053g of copper acetate and dissolve it in 200ml of deionized water, add ammonia water dropwise while stirring at room temperature until the solution pH=7, and then continue stirring for 30min. The solution was quickly poured into a hydrothermal reaction kettle and mixed evenly with activated carbon fibers, and reacted at 190° C. for 2 hours. After the reaction is completed, cool to room temperature, wash the product with water, and dry thoroughly at 60° C. to obtain CuO-loaded activated carbon fibers.

[0045] The activated carbon fiber raw materials and the resulting CuO-loaded activated carbon fibers were observed with an electron microscope, as figure 1 shown. It can be ob...

Embodiment 2

[0048] Example 2: Test residual chlorine and heavy metal removal rate in the laboratory

[0049] Configure the test solution containing HClO and metal ions, make the test solution pass through the filter element of embodiment 1, adjust the flow rate to be 4L / min, and run continuously. After the total effluent is 13t, test the residual chlorine and heavy metal concentration in the filter element product water, and carry out with the test solution For comparison, the results are shown in Table 1.

[0050] Among them, the residual chlorine is tested by the national standard DPD method and an ultraviolet spectrophotometer. In the present invention, residual chlorine refers to free residual chlorine in water, including HClO, ClO - The total concentration of Cl in the Heavy metal ions were tested by ion chromatography.

[0051] Table 1 Water quality test (mg / L) after the composite filter element has a total water output of 13t

[0052] Chlorine Hg 2+

[0053] It ...

Embodiment 3

[0054] Example 3: On-the-spot testing of residual chlorine and heavy metal removal rates

[0055] Carry out identically with the test of embodiment 2, influent is untreated tap water in a certain place, regularly measure the quality of produced water, and compare with influent water quality, the results are shown in Table 2 and figure 2 .

[0056] Table 2 Water quality test (mg / L) of the composite filter element after 10 tons of total effluent

[0057] Chlorine Hg 2+

[0058] It can be seen that after the composite filter element of Example 1 treats 10 tons of water, the concentrations of various pollution indicators in the produced water are all less than 0.001 mg / L. In addition, through repeated sampling and monitoring, it was found that during the operation process of 0-10t produced water, the quality of the effluent was stable, and there was no phenomenon of exceeding the standard, which met the drinking water standard.

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Abstract

The invention provides a multifunctional composite water purification filter element and a preparation method thereof, the filter element is obtained by matching CuO-loaded active carbon fiber, copper fiber and potassium titanate mixture powder with a binder and curing and molding, the mass ratio of the copper fiber to the CuO-loaded active carbon fiber is 1: 5-1: 15, and the mass ratio of the potassium titanate to the CuO-loaded active carbon fiber is 1: 10-1: 20. CuO is loaded on the active carbon fibers to remove residual chlorine adsorbed in carbon fiber channels, a large number of adsorption sites in the carbon fiber channels are activated, and the removal rate of the residual chlorine is further improved in cooperation with the copper fibers. The filter element can continuously and stably remove residual chlorine, Hg < 2 + >, Pb < 2 + >, Cd < 2 + > and As < 2 + > in water, and the produced water meets the drinking water standard.

Description

【Technical field】 [0001] The invention relates to water treatment technology, in particular to a multifunctional composite water purification filter element with heavy metal adsorption properties, and also relates to a preparation method of the filter element and its application in water treatment. 【Background technique】 [0002] Drinking water safety is a common concern in the world today. my country's tap water plants often use chlorine disinfection technology, and residual chlorine will cause serious harm to human health and membrane separation equipment; on the other hand, due to pollution of water sources or management Net "secondary pollution", so that there are heavy metals and microbial pollution in the tap water at the same time. Effectively removing these pollutants to ensure drinking water safety is the focus of current research in the field of water purification. [0003] For the above pollutants, the water purification materials used in the prior art are mainly ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/68C02F1/72C02F101/12C02F101/20
CPCC02F1/725C02F1/68C02F2101/20C02F2101/12
Inventor 陈亦力孟佳意莫恒亮李锁定刘曼曼张金星薛云艳彭文娟许鑫
Owner BEIJING ORIGIN WATER FILM TECH