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Prepn process of composite oxide based on cerium oxide and zirconium oxide

A composite oxide and preparation technology, which is applied in the field of preparation technology of composite oxides based on cerium oxide and zirconia, can solve the problems of long production process and high cost, improve product quality, improve thermal stability, and reduce manufacturing costs. cost effect

Inactive Publication Date: 2003-12-31
淄博正轩稀土功能材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Its main defect is that the production process is long and the cost is relatively high

Method used

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  • Prepn process of composite oxide based on cerium oxide and zirconium oxide
  • Prepn process of composite oxide based on cerium oxide and zirconium oxide
  • Prepn process of composite oxide based on cerium oxide and zirconium oxide

Examples

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Effect test

Embodiment 1

[0047] Using monazite and fluorocarbon-cerium-lanthanum mixed rare earth concentrate as raw materials, it is converted into mixed rare earth chloride solution by sulfuric acid roasting, water leaching, filtration, ammonium bicarbonate precipitation, and hydrochloric acid dissolution, or the water leaching solution is extracted and transformed, and hydrochloric acid reverse extraction is used to obtain the mixed The mixed rare earth chloride solution or high-grade monazite and fluorocarbon-cerium-lanthanum mixed rare earth concentrate is acid washed, sodium hydroxide decomposition, filtered, washed, dissolved in hydrochloric acid, and purified to obtain the mixed rare earth chloride solution. The obtained mixed rare earth chloride solution (a) is separated by praseodymium and neodymium to obtain lanthanum cerium praseodymium mixed rare earth chloride (b), and an outlet can also be opened at a certain stage of the extraction section to obtain lanthanum cerium praseodymium mixed rare...

Embodiment 2

[0056] Using fluorocarbon cerium lanthanum rare earth concentrate as raw material, it is converted into mixed rare earth chloride solution by sulfuric acid roasting, water leaching, filtration, ammonium bicarbonate precipitation, and hydrochloric acid dissolution, or water leaching solution is extracted and transformed into mixed rare earth chloride by hydrochloric acid back extraction. The solution or fluorocarbon cerium lanthanum rare earth concentrate is acid washed, sodium hydroxide decomposition, filtration, washing, hydrochloric acid dissolution, and purification to obtain a mixed rare earth chloride solution. The obtained mixed rare earth chloride solution (a) is separated by praseodymium and neodymium to obtain lanthanum cerium praseodymium mixed rare earth chloride (b), and an outlet can also be opened at a certain stage of the extraction section to obtain lanthanum cerium praseodymium mixed rare earth chloride (c). The mixed rare earth chloride (a) solution is separated ...

Embodiment 3

[0064] Using monazite rare earth concentrate as raw material, it is decomposed by sodium hydroxide, filtered, washed, dissolved in hydrochloric acid, and purified to obtain a mixed rare earth chloride solution. The obtained mixed rare earth chloride solution (a) is separated by praseodymium and neodymium to obtain lanthanum cerium praseodymium mixed rare earth chloride (b), and an outlet can also be opened at a certain stage of the extraction section to obtain lanthanum cerium praseodymium mixed rare earth chloride (c). The mixed rare earth chloride (a) solution is separated by cerium and praseodymium to obtain lanthanum-cerium mixed rare earth chloride (d), and can also be controlled during the separation of lanthanum-cerium mixed rare earth chloride to obtain lanthanum-cerium mixed rare earth chloride (e). Lanthanum-cerium-praseodymium mixed rare earth chloride (b) is subjected to cerium-praseodymium to obtain cerium-praseodymium mixed rare earth chloride (f). The typical rare e...

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Abstract

A preparation process for a composite oxide based on cerium oxide and zirconium oxide, characterized in that the composite oxide uses cerium-containing mixed rare earth salts obtained through decomposition, purification, extraction and separation of natural rare earth concentrates as raw materials, and the entire preparation process has obtained Simplified, greatly reducing the manufacturing cost of the cerium-zirconium composite. The obtained cerium-zirconium composite oxide itself has other rare earth elements as stabilizers to improve the thermal stability of the cerium-zirconium composite oxide and improve the product quality of the cerium-zirconium composite oxide.

Description

Technical field [0001] The invention relates to a preparation method of a composite oxide solid solution containing cerium and zirconium. Such composite oxide solid solutions can be used in automobile exhaust gas purification catalysts and other catalytic materials. Background technique [0002] With the increasingly stringent environmental protection regulations worldwide, the catalytic conversion technology used to treat and purify air pollutants is becoming more and more important. Such catalytic conversion often uses catalysts as the core material for pollutant conversion. With the gradual improvement of catalyst performance, it is very important to use rare earth element oxides and their composite oxides as catalytic materials to improve the activity, stability and selectivity of the catalyst. For example, automobile exhaust purification catalysts ("three-way catalysts") use cerium-zirconium composite oxides to increase the oxygen storage capacit...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/94B01J21/06B01J23/10B01J37/03
Inventor 俞小源马勇柯阳达建文陈璠王庆杰
Owner 淄博正轩稀土功能材料股份有限公司