Durable foam concrete and preparation method thereof
A foamed concrete, durable technology, applied in the field of foamed concrete, can solve the problems of decline and unsatisfactory durability, and achieve the effects of reducing water absorption, reducing liquid fluidity, and preventing thinning and cracking
Active Publication Date: 2021-09-03
北京慕湖新材料技术有限公司
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- Application Information
AI Technical Summary
Problems solved by technology
It can be seen that the mechanical strength of the foamed concrete prepared by using solid waste fly ash in the above-mentioned prior art has been improved to varying degrees, but their water absorption rate is also high, and the durability is still unsatisfactory or even declined.
Method used
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Examples
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Effect test
preparation example 1
[0035] Add 10 parts of alkali lignin to 50 parts of dioxane dissolved with 4.3 parts of triethylamine, keep the temperature of the mixture system constant, add 40 parts of perfluorooctanoyl chloride, keep the temperature at 15°C for 24 hours, and suction filter after the reaction. Wash with saturated sodium bicarbonate solution and water twice respectively, and finally dry for later use.
preparation example 2
[0037] The rest is the same as Preparation Example 1, except that the amount of perfluorooctanoyl chloride is 60 parts.
preparation example 3
[0039] The rest is the same as Preparation Example 1, except that perfluorooctanoyl chloride is replaced by 7H-dodecafluoroheptanoyl chloride of equal weight, and the amount of triethylamine is 40 parts.
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The invention relates to durable foam concrete and a preparation method thereof. The concrete comprises the following raw materials: cement, fly ash, a rosin type foaming agent, a surfactant, modified alkali lignin, water, a water reducing agent and an early strength agent, wherein the modified alkali lignin is obtained by modifying alkali lignin by fluorine-containing acyl chloride under the condition of alkali catalysis. According to the preparation method, alkali lignin and fluorine-containing acyl chloride are taken as raw materials, modified alkali lignin macromolecules with a three-dimensional network structure and hydrophobic side chains are prepared through an esterification reaction, on one hand, a large number of phenolic hydroxyl groups, ether bonds and the like contained in the three-dimensional network structure form hydrogen bonds with a foaming liquid film, the viscosity and compressive strength of the liquid film are improved, moisture in the liquid film is locked, the liquid mobility is reduced, and a bubble wall film is prevented from thinning and cracking; on the other hand, the hydrophobic side chains not only can prevent bubbles from intersecting to form communicating holes to reduce the compressive strength, but also can be adsorbed on the surfaces of foam concrete holes to form coating films, so that water is difficult to permeate into the holes, and the water absorption rate is reduced.
Description
technical field [0001] The invention belongs to the technical field of foam concrete, and in particular relates to a durable foam concrete and a preparation method thereof. Background technique [0002] Foam concrete refers to the use of physical or chemical foaming technology to make a porous material containing a large number of small and uniform independent pores on the basis of cementitious materials. It has the advantages of light weight, energy saving and environmental protection, and good thermal insulation performance. In the actual production process, industrial waste such as fly ash can be widely used in foamed concrete, which not only saves cement and reduces costs, but also greatly reduces the land occupation of fly ash and environmental pressure. Therefore, fly ash foamed concrete has received more and more attention. . As a building material, strength is still one of the main properties of foam concrete. However, as the foam becomes lighter, the strength will ...
Claims
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IPC IPC(8): C04B28/02C04B38/10C04B111/40
CPCC04B28/02C04B2201/50C04B2111/40C04B18/08C04B24/122C04B24/34C04B18/26C04B24/124C04B38/106C04B2103/302C04B24/005C04B24/121C04B24/10C04B22/10
Inventor 马清沛
Owner 北京慕湖新材料技术有限公司

