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Heat-resistant tellurium-copper alloy material and preparation method thereof

An alloy material, tellurium copper technology, applied in the direction of conductive materials, conductive materials, metal/alloy conductors, etc., can solve the problems of low content, high temperature resistance is not as good as element H, etc., to achieve simple extrusion process, good surface quality, solid good dissolving effect

Pending Publication Date: 2021-10-29
CHINA WEAPON SCI ACADEMY NINGBO BRANCH +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

After the process steps of solid solution, cold rolling, aging and drawing, the prepared product has excellent mechanical and electrical properties, the tensile strength exceeds 550MPa, the electrical conductivity is greater than 90% IACS, and the elongation is about 3%. The content of Cr, Co, and Y elements with high temperature stability is low (Cr: 0.07~0.10, Co: 0.07~0.10, Y: 0.005~0.01), and the recrystallization of Cu-(Cr / Sn) alloy under the limit solid solubility The temperature is about 400°C, the recrystallization temperature of Cu-Co alloy is lower than 250°C, and the recrystallization temperature of Cu-0.25Hf alloy is about 550°C. Obviously, the high temperature resistance of Cr / Sn element is not as good as that of element Hf, and the rare earth Y is 0.05%. The above is beneficial to the softening resistance of the alloy. In this patent, it plays the role of purification and impurity removal. Therefore, trace amounts of Cr: 0.07-0.10, Co: 0.07-0.10, Y: 0.005-0.01 have a very limited increase in the anti-softening temperature of tellurium-copper alloys.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] In terms of weight percent, the alloy composition of the heat-resistant tellurium-copper alloy material in this embodiment is: Te: 0.2%, Hf: 0.3%, Ag: 0.1%, and the balance is Cu.

[0026] The preparation method of the heat-resistant tellurium-copper alloy material of this embodiment includes the following steps in sequence:

[0027] (1) Upward continuous casting: batching is carried out according to the composition of the above-mentioned copper alloy materials, among which, first put pure Cu and dehydrated charcoal into an intermediate frequency induction furnace, the thickness of the dehydrated charcoal covering layer is 6cm, and smelt in an atmospheric environment After the pure copper is completely melted, Cu-8Hf wt.% master alloy and pure Ag are added, and the temperature is kept at 1180°C for 5 minutes, and the diameter of the cross-section of the drawn-cast copper alloy rod is 21mm;

[0028] (2) Drawing at room temperature: The alloy rod obtained in step (1) is d...

Embodiment 2

[0033] In terms of weight percent, the alloy composition of the heat-resistant tellurium-copper alloy material in this embodiment is Te: 0.2%, Hf: 0.7%, Ag: 0.15%, and the balance is Cu.

[0034] The preparation method of the heat-resistant tellurium-copper alloy material of this embodiment includes the following steps in sequence:

[0035] (1) Upward continuous casting: batching is carried out according to the composition of the above-mentioned copper alloy materials. First, pure Cu and dehydrated charcoal are put into an intermediate frequency induction furnace. The thickness of the dehydrated charcoal covering layer is 6 mm. After the pure copper is completely melted, Cu-8Hf wt.% master alloy and pure Ag are added, and the temperature is kept at 1180°C for 5 minutes. The diameter of the cross-section of the drawn-cast copper alloy rod is 21mm;

[0036] (2) Drawing at room temperature: The alloy rod obtained in step (1) is drawn through multiple passes (Φ=21mm→Φ=19mm→Φ=17mm→Φ=...

Embodiment 3

[0041] In terms of weight percentage, the alloy composition of the heat-resistant tellurium-copper alloy material in this embodiment is Te: 0.2%, Hf: 0.9%, Ag: 0.2%, and the balance is Cu.

[0042] The preparation method of the heat-resistant tellurium-copper alloy material of this embodiment includes the following steps in sequence:

[0043] (1) Upward continuous casting: mix ingredients according to the composition of the above-mentioned high-performance copper alloy materials, first put pure Cu and dehydrated charcoal into an intermediate frequency induction furnace, the thickness of the dehydrated charcoal covering layer is 6cm, and smelt in the atmospheric environment After the pure copper is completely melted, Cu-8Hf wt.% master alloy and pure Ag are added, and the temperature is kept at 1200°C for 5 minutes, and the diameter of the cross-section of the drawn-cast copper alloy rod is 21mm;

[0044] (2) Drawing at room temperature: The alloy rod obtained in step (1) is dr...

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Abstract

The invention relates to a heat-resistant tellurium-copper alloy material and a preparation method thereof. The heat-resistant tellurium-copper alloy material is characterized by comprising, by weight, 0.2-0.5 wt.% of Te, 0.3-0.9 wt.% of Hf, 0.1-0.2 wt.% of Ag and the balance Cu. The microalloying element Hf is added into the tellurium-copper alloy, the element Hf is separated out in copper in a nanophase mode, the solubility of the element Hf in the copper is larger than that of Zr (the trace Zr element is beneficial to the high-temperature stability of the copper alloy), the tensile strength and the high-temperature softening-resistant temperature of the tellurium-copper alloy are improved, and therefore the tellurium-copper alloy has good high-temperature stability.

Description

technical field [0001] The invention relates to the technical field of copper alloy materials, in particular to a heat-resistant tellurium copper alloy material and a preparation method thereof. Background technique [0002] The rapid development of new energy vehicles has greatly increased the demand for high-performance copper alloys. Copper and copper alloys are mainly used in battery systems, inverters, electric motors, high-voltage cables, low-voltage cables and other parts of new energy vehicles. New energy vehicles Bicycles use much more copper than traditional cars. Compared with ordinary copper alloys, the working environment of copper alloys used in new energy vehicles has four outstanding characteristics: high operating frequency, high operating power, complex and changeable working environment, and high safety requirements. Therefore, its mechanical properties, Good electrical conductivity, thermal conductivity, oxidation resistance, and softening resistance. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C9/00C22C1/03B22D11/00C21D1/26C22F1/08B21C1/00H01B1/02H01B13/00
CPCC22C9/00C22C1/03B22D11/004C21D1/26C22F1/08B21C1/003H01B1/026H01B13/00
Inventor 黄伟龚留奎张延松陈子明刘晓彬冯茜群韩震邓立勋黄实哈
Owner CHINA WEAPON SCI ACADEMY NINGBO BRANCH
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