Hybrid emulsion, water-based inorganic coating prepared from hybrid emulsion and preparation methods of hybrid emulsion and water-based inorganic coating

A water-based inorganic coating and emulsion technology, applied in the direction of coating, etc., can solve the problems of cracks, micropores, scrub resistance, and poor water resistance of the paint film, and achieve excellent scrub resistance, easy promotion, and simple operation Effect

Pending Publication Date: 2021-11-12
河北三棵树涂料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to overcome the shortcomings of the existing water-based interior wall inorganic coatings that are prone to cracks, micropores, etc., and have poor scrub resistance and water resistance, the invention provides a hybrid emulsion and a water-based inorganic paint prepared from the hybrid emulsion. The coating and its preparation method use organic-inorganic hybrid particles as the main film-forming substance, the organic part ensures that the film will not crack, and the introduction of inorganic silica endows the emulsion with scrub resistance, water resistance and storage stability Good advantages

Method used

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  • Hybrid emulsion, water-based inorganic coating prepared from hybrid emulsion and preparation methods of hybrid emulsion and water-based inorganic coating
  • Hybrid emulsion, water-based inorganic coating prepared from hybrid emulsion and preparation methods of hybrid emulsion and water-based inorganic coating
  • Hybrid emulsion, water-based inorganic coating prepared from hybrid emulsion and preparation methods of hybrid emulsion and water-based inorganic coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] A hybrid emulsion according to the present invention is mainly prepared from the following components according to the following ratios by weight and number:

[0048]

[0049]

[0050] Wherein, the mixed monomer is mainly prepared from the following components according to the following ratios by weight:

[0051]

[0052] The weight percent of potassium persulfate in the potassium persulfate aqueous solution is 0.8%.

[0053] A water-based inorganic coating prepared from the hybrid emulsion is mainly prepared from the following components according to the following ratios by weight and number:

[0054]

[0055] Described thickening agent is hydroxyethyl cellulose.

[0056] The water-based dispersant is polyacrylic acid sodium salt dispersant.

[0057] The water-based wetting agent is secondary alcohol ethoxylate.

[0058] Described water-based defoamer is nonionic mineral oil.

[0059] The film-forming aid is 2,2,4-trimethyl-1,3-pentanediol isobutyrate die...

Embodiment 2

[0070] A hybrid emulsion according to the present invention is mainly prepared from the following components according to the following ratios by weight and number:

[0071]

[0072] Wherein, the mixed monomer is mainly prepared from the following components according to the following ratios by weight:

[0073]

[0074] The weight percent of potassium persulfate in the potassium persulfate aqueous solution is 0.9%.

[0075] A water-based inorganic coating prepared from the hybrid emulsion is mainly prepared from the following components according to the following ratios by weight and number:

[0076]

[0077]

[0078] Described thickening agent is hydroxyethyl cellulose.

[0079] The water-based dispersant is polyacrylic acid sodium salt dispersant.

[0080] The water-based wetting agent is a block copolymer.

[0081] Described water-based defoamer is nonionic mineral oil.

[0082] The film-forming aid is 2,2,4-trimethyl-1,3-pentanediol isobutyrate diester.

...

Embodiment 3

[0093] A hybrid emulsion according to the present invention is mainly prepared from the following components according to the following ratios by weight and number:

[0094]

[0095]

[0096] Wherein, the mixed monomer is mainly prepared from the following components according to the following ratios by weight:

[0097]

[0098] The weight percent of potassium persulfate in the potassium persulfate aqueous solution is 0.7%.

[0099] A water-based inorganic coating prepared from the hybrid emulsion is mainly prepared from the following components according to the following ratios by weight and number:

[0100]

[0101] Described thickening agent is hydroxyethyl cellulose.

[0102] The water-based dispersant is polyacrylic acid sodium salt dispersant.

[0103] The water-based wetting agent is any combination of secondary alcohol ethoxylate, block copolymer and alkyl polyoxyethylene ether.

[0104] Described water-based defoamer is nonionic mineral oil.

[0105] T...

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Abstract

The invention relates to a hybrid emulsion, a water-based inorganic coating prepared from the hybrid emulsion and preparation methods of the hybrid emulsion and water-based inorganic coating. The water-based inorganic coating is mainly prepared from the following components in parts by weight: 40-70 parts of water, 0.4-20 parts of mixed monomers, 1-10 parts of potassium persulfate aqueous solution, 0.001-1 part of anionic emulsifier AS30, 0.001-1 part of tert-butyl hydroperoxide, 0.001-1 part of FF6M reducing agent, 1-10 parts of ethyl orthosilicate, 0.1-15 parts of gamma-glycidyl ether oxypropyltrimethoxysilane, and 0.1-5 parts of concentrated ammonia water. The defects that a paint film of an existing water-based inorganic coating for interior walls easily generates cracks, micropores and the like, and has the defects of poor scrubbing resistance, poor water resistance and the like. Organic-inorganic hybrid particles are used as main film forming substances, the organic matter part ensures that a formed film does not crack, and the introduction of the inorganic matter silicon dioxide endows the emulsion with the advantages of scrubbing resistance, water resistance, good storage stability and the like.

Description

technical field [0001] The invention relates to a hybrid emulsion, a water-based inorganic paint prepared from the hybrid emulsion and a preparation method thereof, which are applied in the field of paint production. Background technique [0002] Water-based interior wall inorganic paint refers to the preparation of alkali metal silicate and emulsion as the main binder, combined with inorganic mineral pigments and inorganic mineral fillers. It is formed on buildings by brushing, spraying or rolling. Thin decorative coating, and it does not contain harmful substances such as formaldehyde, volatile organic compounds, heavy metals, etc., and is widely applicable to the coating process of existing building walls. Although water-based inorganic coatings are environmentally friendly and safe, most of them use silicate or silica sol as the main film-forming substance, which makes the volume of water-based inorganic coatings shrink greatly during the film-forming process, and the fo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/18C08F220/14C08F220/20C08F220/32C09D133/08C09D133/12C09D7/61
CPCC08F220/1804C09D133/14C09D7/61C09D7/70C08K2003/2241C08K2003/3045C08F220/14C08F220/20C08F220/325C08K3/22C08K3/346C08K3/34C08K7/26C08K13/06C08K3/30
Inventor 林倩倩林昌庆付绍祥林朋郭全坚郭新明
Owner 河北三棵树涂料有限公司
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