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Biodegradable polymer packaging material

A technology for biodegradation and packaging materials, applied in the field of biodegradable polymer materials, can solve problems such as complex processes, and achieve excellent mechanical properties, good degradation rate, and the effect of inhibiting Escherichia coli and Staphylococcus aureus.

Inactive Publication Date: 2021-11-19
深圳市约玛新材制造有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The polymer degradation under this method will not completely disappear the polymer material, but will produce new substances under the action of microorganisms, the process is more complicated

Method used

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  • Biodegradable polymer packaging material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] A biodegradable polymer packaging material prepared from modified polyvinyl alcohol, stabilizer, plasticizer and auxiliary agent;

[0020] Wherein the preparation method of modified polyvinyl alcohol is as follows:

[0021] S1: After mixing 80 parts by weight of glutaraldehyde with 60 parts by weight of extractant tributylamine and 60 parts by weight of diluent n-butanol, add 6 parts by weight of catalyst Pd / SiO 2 , heated and stirred, the heating temperature was 55°C, and air was continuously introduced into it. During the reaction, 0.05mol / L NaOH solution was added dropwise to it, and the pH of the solution was tested with a pH meter, and the pH of the solution was adjusted to 7.5. After 4 hours of reaction, after the reaction was completed The aldehyde group at one end of glutaraldehyde is oxidized to a carboxyl group, that is, the product after the reaction has a carboxyl group at one end and an aldehyde group at the other end;

[0022] S2: Filter the mixed solutio...

Embodiment 2

[0030] A biodegradable polymer packaging material prepared from modified polyvinyl alcohol, stabilizer, plasticizer and auxiliary agent;

[0031] Wherein the preparation method of modified polyvinyl alcohol is as follows:

[0032] S1: After mixing 100 parts by weight of glutaraldehyde with 80 parts by weight of extractant tributylamine and 80 parts by weight of diluent n-butanol, add 10 parts by weight of catalyst Pd / SiO 2 , heated and stirred, the heating temperature was 65°C, and air was continuously introduced into it. During the reaction, 0.05mol / L NaOH solution was added dropwise to it, and the pH of the solution was tested with a pH meter, and the pH of the solution was adjusted to 7.5. After 6 hours of reaction, after the reaction was completed The aldehyde group at one end of glutaraldehyde is oxidized to a carboxyl group, that is, the product after the reaction has a carboxyl group at one end and an aldehyde group at the other end;

[0033] S2: Filter the mixed solut...

Embodiment 3

[0039] A biodegradable polymer packaging material prepared from modified polyvinyl alcohol, stabilizer, plasticizer and auxiliary agent;

[0040] Wherein the preparation method of modified polyvinyl alcohol is as follows:

[0041] S1: After mixing 80 parts by weight of glutaraldehyde with 60 parts by weight of extractant tributylamine and 60 parts by weight of diluent n-butanol, add 6 parts by weight of catalyst Pd / SiO 2 , heated and stirred, the heating temperature was 55°C, and air was continuously introduced into it. During the reaction, 0.05mol / L NaOH solution was added dropwise to it, and the pH of the solution was tested with a pH meter, and the pH of the solution was adjusted to 7.5. After 4 hours of reaction, after the reaction was completed The aldehyde group at one end of glutaraldehyde is oxidized to a carboxyl group, that is, the product after the reaction has a carboxyl group at one end and an aldehyde group at the other end.

[0042] S2: Filter the mixed solutio...

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Abstract

The invention belongs to the technical field of biodegradable polymer materials, and particularly relates to a biodegradable polymer packaging material. The biodegradable polymer packaging material is prepared from modified polyvinyl alcohol, a stabilizer, a plasticizer and an assistant, glutaraldehyde is used for modifying polyvinyl alcohol, an aldehyde group at one end of glutaraldehyde is oxidized into carboxyl, and the carboxyl and hydroxyl on a polyvinyl alcohol molecular chain are subjected to esterification reaction to obtain the modified polyvinyl alcohol, so that formation of a large number of intramolecular and intermolecular hydrogen bonds on the polyvinyl alcohol molecular chain is avoided; and meanwhile, an active aldehyde group is introduced to the modified polyvinyl alcohol molecular chain, so that the synthesized biodegradable polymer packaging material has excellent mechanical properties, can effectively inhibit escherichia coli and staphylococcus aureus, and has a good degradation rate.

Description

technical field [0001] The invention relates to the technical field of biodegradable polymer materials, in particular to a biodegradable polymer packaging material. Background technique [0002] With the development of society, various polymer materials are applied to daily production and life. However, these materials are difficult to degrade naturally and cause serious pollution to the environment. This situation is seriously inconsistent with the concept of "green development". In order to solve the pollution problem, the study of biodegradable polymer materials has become the focus of attention. Biodegradable polymers generally refer to polymer materials that have certain mechanical strength and can be decomposed into low-molecular compounds by microorganisms such as bacteria, mold (fungi) and algae in whole or in part in the natural environment without causing environmental pollution. It has the following characteristics: it can be made into compost and returned to na...

Claims

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Application Information

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IPC IPC(8): C08L29/04C08K5/00C08K5/098C08K5/12C08K5/11C08K5/134C08K5/13C08K5/1515C08F8/14C08F16/06B65D65/46A01N37/42A01P1/00
CPCC08K5/00C08K5/098C08K5/12C08K5/11C08K5/1345C08K5/13C08K5/1515C08F8/14B65D65/466A01N37/42C08L2201/06C08L29/04C08F16/06Y02W90/10
Inventor 牛宏伟
Owner 深圳市约玛新材制造有限公司