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A method for high-clean and non-destructive transfer of graphene nanoribbons

A graphene nanoribbon, clean technology, applied in the direction of graphene, single-layer graphene, nano carbon, etc., can solve the problem of unrealizable, complicated transfer of graphene nanoribbons, and obtain ultra-clean high-quality graphene nanoribbons Difficulties and other problems, to achieve the effect of avoiding stacking, avoiding agglomeration, and simple process

Active Publication Date: 2022-04-15
GUANGDONG MORION NANOTECHNOLOGY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This will make the transfer of graphene nanoribbons more complicated, and it will be more difficult to obtain ultra-clean high-quality graphene nanoribbons
Ultra-clean and non-destructive transfer of graphene nano-transfer process cannot be overcome. Before that, graphene nano-belts were difficult to apply to nano-electronic components, and it was impossible to break Moore's law that broke the physical limit of silicon materials and achieve ultra-integration of <5nm process. dream

Method used

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  • A method for high-clean and non-destructive transfer of graphene nanoribbons
  • A method for high-clean and non-destructive transfer of graphene nanoribbons

Examples

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Embodiment 1

[0024] A kind of method that the present invention proposes highly clean nondestructive transfer graphene nanoribbon, concrete steps are as follows:

[0025] (1) The Mica substrate is ultrasonically cleaned with acetone, absolute ethanol, and deionized water for 20 minutes in sequence, the purpose of which is to remove organic impurities and dust on the surface of the Mica;

[0026] (2) Transfer the cleaned Mica substrate to a plasma-assisted magnetron sputtering apparatus, replace the pure gold target, and grow a 30nm-thick Au(111) layer on the Mica substrate to obtain the Au(111) / Mica growth substrate.

[0027] (3) The Au(111) / Mica sample obtained in step (2) was washed with absolute ethanol to remove surface impurities, and transferred to a plasma-assisted CVD furnace, using ethylene as the growth source gas, on the Au(111) surface A single layer of N=7 GNR is grown, where N=7 means that the graphene nanoribbon width is 7 atoms wide, and N=7 GNR / Au(111) / Mica sample is obtai...

Embodiment 2

[0036] A method for highly clean and non-destructive transfer of graphene nanoribbons, the specific steps are as follows:

[0037] (1) The Mica substrate is ultrasonically cleaned with acetone, absolute ethanol, and deionized water for 20 minutes in sequence, the purpose of which is to remove organic impurities and dust on the surface of the Mica;

[0038] (2) Transfer the cleaned Mica substrate to a plasma-assisted magnetron sputtering apparatus, replace the pure gold target, and grow a 30nm-thick Au(111) layer on the Mica substrate to obtain the Au(111) / Mica growth substrate.

[0039] (3) The Au(111) / Mica sample obtained in step (2) was washed with absolute ethanol to remove surface impurities, and transferred to a plasma-assisted CVD furnace, using ethylene as the growth source gas, on the Au(111) surface A single layer of N=7 GNR is grown, where N=7 means that the graphene nanoribbon width is 7 atoms wide, and N=7 GNR / Au(111) / Mica sample is obtained.

[0040] (4) During t...

Embodiment 3

[0050] The difference between this example and Example 1 is that the iodine solution of potassium iodide in step (9) in Example 1 is replaced by nitrohydrochloric acid configured with concentrated hydrochloric acid and concentrated nitric acid in a volume ratio of 1:3, and the solution is dropped on the surface of the sample. On , the iodine solution of potassium iodide slowly etches the Au(111) layer. The Au(111) coating is completely etched, and the etching solution is blotted dry with dust-free paper, then washed repeatedly with deionized water and absolute ethanol, and then dried on a heating platform at 60°C to obtain graphene nanoribbons sample. The purpose of this example is to verify the effect of the etching speed of the Au(111) coating on the transfer quality of graphene nanoribbons. Raman multi-point test results show the I of the transferred graphene nanoribbons 2d / I G The value of is reduced, and some blanks appear at the same time. This indicates that the st...

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Abstract

The present invention proposes a method for high-clean and non-destructive transfer of graphene nanoribbons, by growing an Au(111) layer with a certain thickness on the Mica substrate to obtain the Au(111) / Mica growth substrate; using a CVD growth process on the Au(111) surface N=7GNR with a full monolayer was grown to obtain a N=7GNR / Au(111) / Mica sample, and a thin blade was used to coat the Au(111) layer of the N=7GNR / Au(111) / Mica sample grown with graphene nanoribbons Scratch lightly on the periphery of the surface to destroy the integrity of the amorphous carbon film on the surface, and then use a soft brush to stick a certain concentration of potassium iodide iodine solution with weak etching ability and brush it several times to make the amorphous carbon film on the surface fall off, and at the same time The N=7GNR / Au(111) layer is exposed to facilitate the subsequent separation of the Mica substrate from the Au(111) coating. During the transfer process, no new impurities and new defects are introduced, and the rapid transfer of graphene nanoribbons is achieved by purposefully removing the amorphous carbon layer.

Description

technical field [0001] The invention relates to the field of transfer of graphene nanobelts, in particular to a method for highly clean and non-destructive transfer of graphene nanobelts. Background technique [0002] Semiconductor devices are important basic electronic components for the manufacture of integrated circuits and chips. With the rapid development of high integration and microscale of electronic components, this will inevitably pose greater challenges to the nanoscale of electronic components. At present, the most advanced semiconductor photolithography process has reached 7nm and 5nm, and even 1nm process technology can be achieved in the laboratory. Although the gate length of the silicon material traditionally used to prepare semiconductor components is ≥5nm, it has quite ideal advantages, but when the gate length of the silicon material is less than 5nm, the more obvious "tunnel effect" will appear with the shortening of the gate length , preventing the sou...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B32/186C01B32/194
CPCC01B32/186C01B32/194C01B2204/02
Inventor 蔡金明陈其赞林泽斯
Owner GUANGDONG MORION NANOTECHNOLOGY CO LTD
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