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Cf/C-SiC composite material for engine piston and preparation method thereof

A composite material and engine technology, applied in engine components, machines/engines, pistons, etc., can solve the problems of reducing the reliability of the mechanical properties of materials at room temperature, increasing the sensitivity of materials to crack damage, and limiting applications, so as to improve service reliability. , reduce the sensitivity of crack damage, and promote the effect of application

Active Publication Date: 2021-11-26
湖北瑞宇空天高新技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But the C prepared by RMI method f The residual Si existing in the matrix of the / C-SiC composite material will expand in volume during the cooling process, and it is easy to generate cracks at the Si-SiC interface, which will reduce the mechanical properties of the material at room temperature and the reliability of long-term service. At the same time, the residual Si belongs to Brittle materials will increase the sensitivity of the material to crack damage, which greatly limits the further application of this material in the field of engine pistons

Method used

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  • Cf/C-SiC composite material for engine piston and preparation method thereof
  • Cf/C-SiC composite material for engine piston and preparation method thereof
  • Cf/C-SiC composite material for engine piston and preparation method thereof

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Effect test

Embodiment 1

[0036] (1) The density is 0.35g / cm prepared by the relay acupuncture method 3 carbon fiber prefabricated body;

[0037] (2) Pyrolytic carbon densification of carbon fiber prefabricated body by fast CVI method, and the obtained density is 1.35g / cm 3 C f / C porous body. Among them, the carbon source gas for chemical vapor deposition is propane and natural gas, the diluent gas is nitrogen, the volume ratio of propane:natural gas:nitrogen is 1:5:8, the infiltration time is 150h, the infiltration temperature is 980°C, and the pressure is 2000Pa , the residence time is 1.8s;

[0038] (3) The prepared C f The / C porous body is heat-treated at a high temperature of 2400 ° C for 2 hours, the argon gas protection atmosphere, and the pressure of 1500 Pa, the purpose is to improve the low-density C f / C The degree of graphitization of the porous body removes non-carbon impurities in the porous body;

[0039] (4) Add 6g of absolute ethanol and 1g of silane coupling agent A-1230 into ...

Embodiment 2

[0044] (1) The density is 0.40g / cm prepared by relay acupuncture method 3 carbon fiber prefabricated body;

[0045] (2) Pyrolytic carbon densification of carbon fiber prefabricated body by fast CVI method, and the obtained density is 1.25g / cm 3 C f / C porous body. Among them, the carbon source gas for chemical vapor infiltration is propane, the diluent gas is nitrogen, the volume ratio of source gas and diluent gas is 1:10, the infiltration time is 200h, the infiltration temperature is 1050°C, the pressure is 2500Pa; the residence time is 1.3 s.

[0046] (3) The prepared C f The / C porous body is heat-treated at a high temperature of 2200°C for 2h, under the protective atmosphere of argon gas, and the pressure is 1500Pa, the purpose is to improve the low-density C f / C The degree of graphitization of the porous body removes non-carbon impurities in the pores;

[0047] (4) Add 8g of absolute ethanol and 1.2g of silane coupling agent A-1230 into a beaker and mix them, then...

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Abstract

The invention relates to a preparation method of a Cf / C-SiC composite material for an engine piston. The Cf / C-SiC composite material is prepared by densifying a needle-punched carbon fiber preform to the density of 1.95-2.20 g / cm < 3 > through a chemical vapor infiltration (CVI) method, a slurry impregnation (SI) method and a fusion reaction siliconizing (RMI) method. The specific preparation method comprises the following steps: firstly, preparing a carbon fiber preform by adopting a relay type needling method, then preparing a low-density carbon / carbon (Cf / C) porous body by adopting a CVI (Chemical Vapor Infiltration) method, introducing a carbon nanofiller by adopting an SI (Scale Index) method after high-temperature heat treatment, adjusting the pore size and distribution of the Cf / C porous body, and then preparing the Cf / C-SiC composite material by adopting an RMI (Reactive Magnetic Index) method; finally, releasing residual thermal stress through a high-temperature heat treatment method, and preparing the high-reliability and low-damage-sensitivity Cf / C-SiC composite material for the engine piston. The prepared Cf / C-SiC composite material for the engine piston has the advantages of higher room-temperature and high-temperature mechanical strength, smaller thermal expansion coefficient, lower damage sensitivity and excellent self-lubricating property.

Description

technical field [0001] The invention belongs to the technical field of preparation of ceramic-based composite materials, and in particular relates to a preparation material of a composite material for engine pistons, a preparation method and application thereof. Background technique [0002] The piston is one of the most important parts in the engine, because it works under the conditions of high temperature, high pressure, corrosion, friction, high-speed movement, etc., it has high requirements on the performance of the material. The traditional engine piston materials generally have three types: cast iron, steel and aluminum alloy. The development direction of internal combustion engines with high speed and low energy consumption requires piston materials to have better high-temperature mechanical properties and lighter weight to meet performance requirements. Data show that the maximum explosion pressure of the cylinder internal combustion engine has exceeded 20MPa or ev...

Claims

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Application Information

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IPC IPC(8): C04B35/83C04B35/80C04B35/565C04B35/622F02F3/00
CPCC04B35/83C04B35/80C04B35/565C04B35/622F02F3/0084C04B2235/5454C04B2235/616C04B2235/5288C04B2235/422C04B2235/425C04B2235/96C04B2235/77
Inventor 罗瑞盈罗浩
Owner 湖北瑞宇空天高新技术有限公司
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