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Novel epoxy resin and application thereof

An epoxy resin, a new type of technology, applied in the direction of organic material conductors, non-metallic conductors, etc., can solve problems such as poor corrosion resistance, device performance degradation, limiting the service life of the engine or the environment in which tasks are performed, and achieve breakthroughs in technical bottlenecks, The effect of improving thermal stability

Pending Publication Date: 2021-12-31
NANO TOP ELECTRONICS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition to the above requirements, with the rapid increase in the integration level and operating frequency of electronic devices, more and more heat is generated, resulting in a significant decline in device performance, and electromagnetic interference shielding materials also require high thermal conductivity
[0003] High conductivity is the main factor determining the shielding effectiveness of materials, which is beneficial to the reflection and absorption of electromagnetic waves. Although traditional metal shields have excellent electromagnetic interference shielding performance, they are heavy and poor in corrosion resistance. In order to meet the growing lightweight, Ultrathin thickness and flexibility requirements, polymer matrix composites with conductive nanomaterials such as conductive carbon black, carbon nanotubes, carbon fibers, MXenes, and metal nanowires as fillers have been widely explored for electromagnetic shielding applications
However, in the prior art, the electromagnetic shielding coatings used on aircraft have poor temperature resistance, which will limit the service life of the engine or the environment in which tasks are performed, and most of the current military electromagnetic shielding coatings are silver-based coatings, which will bring huge the cost of

Method used

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  • Novel epoxy resin and application thereof
  • Novel epoxy resin and application thereof
  • Novel epoxy resin and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0035] The novel epoxy resin described in Example 1 includes the following raw materials in parts by weight: 0.15 parts by weight of carboxyl-containing imide curing agent, 0.04 parts by weight of diethylenetriamine, and 1.25 parts by weight of bisphenol-A epoxy resin.

[0036] The preparation method of described novel epoxy resin comprises the following steps:

[0037] (1) Preparation of carboxyl-containing imide curing agent: adding trimellitic anhydride to m-cresol, stirring until completely dissolved under heating conditions at a temperature of 150° C., adding diaminodiphenyl ether to the solution, the trimellitic anhydride and The molar ratio of diaminodiphenyl ether is 2:1, react at a temperature of 150°C for 6 hours, and after the reaction is completed, the reaction product is quenched with ice water, vacuum filtered and washed in sequence, and the detergent used is methane A mixture of cresol and water;

[0038] Then vacuum-dry the obtained washings at a temperature o...

Embodiment 2

[0041] The novel epoxy resin described in Example 2 includes the following raw materials in parts by weight: 0.2 parts by weight of carboxyl-containing imide curing agent, 0.04 parts by weight of diethylenetriamine, and 1.25 parts by weight of bisphenol-A epoxy resin.

[0042] The preparation method of novel epoxy resin described in embodiment 2 is identical with the preparation method of novel epoxy resin described in embodiment 1.

Embodiment 3

[0044] The novel epoxy resin described in Example 3 includes the following raw materials in parts by weight: 0.1 parts by weight of carboxyl-containing imide curing agent, 0.06 parts by weight of diethylenetriamine, and 1.25 parts by weight of bisphenol-a epoxy resin.

[0045] The preparation method of novel epoxy resin described in embodiment 3 is identical with the preparation method of novel epoxy resin described in embodiment 1.

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Abstract

The invention discloses novel epoxy resin which comprises the following raw materials: a carboxyl-containing imide curing agent, diethylenetriamine and epoxy resin. The novel epoxy resin has the beneficial effects that the number of rigid structures in the molecular structure of the epoxy resin is increased by introducing the carboxyl-containing imide curing agent into the epoxy resin, and higher energy is needed to break the structures, so that the decomposition temperature of the novel epoxy resin is increased, and the thermal stability of the novel epoxy resin is improved. According to the novel epoxy resin disclosed by the invention, by introducing the carboxyl-containing imide curing agent, epoxy resin with different properties and a composite conductive material thereof can be prepared, and the technical bottleneck that the epoxy resin and the composite conductive material thereof are difficult to use is broken through. The urgent requirements on the high-performance thermosetting epoxy resin and the composite conductive material thereof in the fields of aerospace, 5G electronic products and national defense and military are met.

Description

technical field [0001] The invention belongs to the technical field of manufacturing high-performance thermosetting materials, and in particular relates to a novel epoxy resin and its application. Background technique [0002] The rapid development of electronic equipment has led to a large increase in electromagnetic pollution, which has adverse effects not only on equipment performance, but also on the surrounding environment. Electromagnetic shielding materials have been widely developed to avoid harmful electromagnetic radiation. Especially in the fields of aircraft, spacecraft, drones, next-generation portable devices and wearable electronic devices, the application of ultra-thin, lightweight, high-strength and flexible EMI shielding materials with high shielding effectiveness is very urgent. In addition to the above requirements, with the rapid increase in the integration level and operating frequency of electronic devices, more and more heat is generated, resulting i...

Claims

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Application Information

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IPC IPC(8): C08G59/40C08L63/02C08K3/04H01B1/12
CPCC08G59/4042C08K3/04H01B1/12C08L63/00
Inventor 黄进杨仁裕甘霖符雪娇刘均刘元哲杨甜甜
Owner NANO TOP ELECTRONICS TECH
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