Coloured flame-retardant polypropylene fibre, preparation and use thereof

A flame retardant polypropylene and fiber technology, which is used in the manufacture of fire retardant filaments, melt spinning, and single-component polypropylene rayon. and other problems, to achieve the effects of improved spinning performance, no suffocation, and less smoke.

Inactive Publication Date: 2009-07-15
ZHEJIANG ELITE TEXTILE CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

If some pigments are too fine, such as when the proportion of particles below 0.2 μm is large, it will appear. First, it will be re-flocculated into large particles, which is difficult to maintain the micronized state; second, due to the diffraction of visible light, the light will bypass Pigment particles pass through, increasing the transparency of the coloring and making it difficult to stabilize the color, for example: red may become yellowish, blue may become greenish, etc.

Method used

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  • Coloured flame-retardant polypropylene fibre, preparation and use thereof
  • Coloured flame-retardant polypropylene fibre, preparation and use thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] The preparation of nano magnesium hydroxide:

[0045] In 10wt% magnesium chloride aqueous solution, add the mixture of polyethylene glycol octyl phenyl ether and sodium dodecylbenzenesulfonate whose total weight is 2wt% of the total weight of magnesium chloride aqueous solution, sodium dodecylbenzenesulfonate and polyethylene glycol The weight ratio of alcohol octyl phenyl ether is 1:3; add dropwise 5wt% NaOH aqueous solution under stirring, adjust the pH value to 8.5, and set the temperature at 30°C for precipitation reaction for 2 hours. Filter, wash, and dry to obtain nanometer Mg(OH) 2 powder. The average particle diameter of the nano-magnesium hydroxide is 30nm.

Embodiment 2

[0047] Preparation of nano aluminum hydroxide:

[0048] In 30wt% magnesium chloride aqueous solution, add the mixture of polyethylene glycol octyl phenyl ether and sodium dodecylbenzenesulfonate whose total weight is 1wt% of the total weight of magnesium chloride aqueous solution, sodium dodecylbenzenesulfonate and polyethylene glycol The mass ratio of alcohol octyl phenyl ether is 1:1; add 3wt% NaOH aqueous solution dropwise under stirring, adjust the pH value to 10, the temperature is 10°C, and precipitate for 1.5 hours. , washing, and drying to obtain nano-Al(OH) 3 powder. The average particle size of the nano aluminum hydroxide is 100nm.

Embodiment 3

[0050] Preparation of flame retardant masterbatch:

[0051] The following are parts by weight.

[0052] 10 parts of phosphorus flame retardant, 4 parts of aluminum hydroxide of embodiment 1, 1 part of magnesium hydroxide of embodiment 2, 85 parts of fiber grade polypropylene chips.

[0053] The SHL-35 type twin-screw extruder produced by Shanghai Chemical Machinery No. 4 Factory is used to add a static mixer known in the art, the feed screw is 50r / min, and the main screw is 150r / min. Using melt extrusion, cooled under water into strips, and pelletized. The size of the masterbatch is about 3×2×2mm, and the cutting speed is 400r / min. The temperature range of each zone of the blending screw is 200-230°C

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Abstract

The invention provides a colored flame retardant polypropylene fiber as well as a preparation method and application thereof. The fiber comprises the following components by weight: 1-10 parts of a color master batch, 1-20 parts of a flame retardant master batch and 98-70 parts of polypropylene fiber forming slices; the flame retardant master batch is a blend of a phosphorous flame retardant, modified magnesium hydroxide, modified nano aluminum hydroxide and the polypropylene fiber forming slices, and the parts of the phosphorous flame retardant, the magnesium hydroxide and the aluminum hydroxide by weight equal 10:3-5:0-1.5. The flame retardant has the advantages of excellent performance, improved pigment dispersivity and polypropylene fluidity, improved spinning performance, high decomposition temperature, good thermal stability, less smoke amount, no toxicity, no corrosiveness and no suffocation, and does not affect original performance of materials and production requirements basically; the performance indexes of obtained polypropylene filament yarn meet standard requirements; the fiber is soft and elastic, and has the advantages of good flame retardant performance and long flame retardant period.

Description

technical field [0001] The invention relates to a polypropylene fiber and its preparation method and application, in particular to a colored flame-retardant polypropylene fiber. Background technique [0002] In the past ten years, my country's polypropylene industry has developed rapidly. In 1995, the output was 1.073 million tons. In 2000, it exceeded 3 million tons. In 2004, the output soared to 4.749 million tons. To meet the rapidly growing demand of the domestic market, a large number of imports are made every year. In 2004, my country imported about 3 million tons of polypropylene, the highest record in history, and there is still a growing trend. Polypropylene is a variety of polypropylene with great development potential. In addition to being used as clothing fibers, industrial polypropylene is a hot spot for development in recent years. With the emphasis on engineering quality, the application of modified polypropylene fibers and geotextiles in roads, reservoirs, an...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F6/06D01F1/07D01D5/08
Inventor 江勇明
Owner ZHEJIANG ELITE TEXTILE CO LTD
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