32results about How to "Good reproducibility for multiple synthesis" patented technology

The invention belongs to the technical field of photoelectric materials, and particularly relates to luminescent materials based on thioxanthene-fluorene spiral structures and organic photoelectric devices adopting the materials as luminescent layers. The luminescent materials adopts the thioxanthene-fluorene spiral structures as skeleton units. Intermediates are prepared through Ullmann reactions, and then the target compounds are obtained through Ullmann reactions or Suzuki reactions. The materials are single in structure and definite in molecular weight. The spiral structures of the materials can adjust an intermolecular accumulation manner, thus effectively inhibiting exciplex luminescence. The materials have deep meaning for development of high-effect devices. The organic photoelectric devices adopting the materials as the luminescent layers have good luminescent properties and can be used for small organic molecule light emitting diodes.

The invention discloses a water-alcohol-soluble pyridinium salt based on small organic molecules, and a preparation method and an application thereof. According to the material, pyridinium is adopted as a frame; and through the changes upon connection units, molecular weight, pi-conjugacy and electrophilicity of the material can be adjusted. The chemical structure of the material is shown on the right. The preparation method comprises the steps that: p-xylene is adopted as an initial reaction raw material; a series of simple reactions are carried out; and under the effect of thionyl chloride, ring-closure salt-formation is carried out, such that a target compound is obtained. The material provided by the invention has a single structure, a definite molecular weight, good dissolubility, and good film forming property. The material can be used in modification layers of cathodes or anodes of organic photoelectric devices such as polymer electroluminescent diodes, organic solar cells, and the like.

The invention belongs to the technical field of intelligent materials, and discloses a multi-stimulus-response organic small-molecular luminescent material, and preparation and application thereof. By utilizing the dual-fluorescence characteristics of phenothiazine derivatives, a series of luminescent materials are designed and synthesized; and external stimulus effects are utilized to regulate the reciprocal transformation of two conformations, thereby providing a simple feasible effective design strategy for the stimulus-response luminescent material. According to the preparation method, phenothiazine, which is used as a main reaction raw material, is subjected to a series of simple reactions to obtain various target products. The obtained product has the advantages of definite molecular weight, single structure, lower glass transition temperature and greatly higher stimulus-response sensitivity. The stimulus-response principle of the material is conversion between two different conformations instead of the influence of the intermolecular acting force and accumulation mode, so that the material has the multi-stimulus-response characteristic, and is applicable to sensors of force, temperature, pH and the like.

The invention provides an organic small-molecule luminescent material and an organic electroluminescent device. The organic small-molecule luminescent material provided by the invention is obtained bycoupling a novel acridine donor unit 10H-spiro[acridine-9,2'-adamantane] with a receptor unit. The organic small-molecule luminescent material has a single structure and a determined molecular weight, is convenient for purification and high in multiple synthetic reproducibility, and has low sublimation temperature and high decomposition temperature and stable film morphology; since the non-aromatic rigid structure adamantine is used as a donor part structure, the organic small-molecule luminescent material has a high photoluminescent quantum yield in the film state; when the organic small-molecule luminescent material is applied to the organic electroluminescent device, the problem of low efficiency of the device caused by serious non-radiative attenuation due to configuration relaxationof an excited state molecule can be effectively solved.

The invention belongs to the technical field of photoelectric materials and particularly relates to an organic small molecular material based on spiro thioxanthene and an organic photoelectric device using the material as a light emitting layer. By using spiro thioxanthene as a framework unit, the organic small molecular material can be used for obtaining a target compound by virtue of friedel craft reaction and Ullmann reaction. The material is single in structure and certain in molecular weight and has good solubility and film forming property in common solvents. The spiro structure of the material can adjust the accumulation mode of molecules, so that an exciplex is effectively prevented from emitting light, therefore, the material is of profound significance in development of high-effect devices. The photoelectric device using the material as the light emitting layer has a good light emitting performance and can be applied to organic small molecular light emitting diodes.

The invention discloses a small-molecular luminescent material based on a trispirocyclic acridine donor unit and a preparation method and application thereof, and belongs to the technical field of organic photoelectric materials. The luminescent material disclosed by the invention comprises the trispirocyclic acridine donor unit; the material has a single material structure and definite amount, isconvenient to purify, has good reproducibility by multiple times of synthesis, and is extremely high in thermal stability and morphological stability. The small-molecular luminescent material based on the trispirocyclic acridine donor unit of the invention is applied to an organic photoelectric device; and compared with a small-molecular electroluminescent material composed of a bispirocyclic acridine donor, the material based on a trispirocyclic acridine donor can obtain darker blue light with higher horizontal dipole orientation and higher device efficiency, achieves higher device efficiency in a larger doping proportion, and thus has a wider application prospect; and for example, the small-molecular luminescent material can achieve higher efficiency in a non-doped device and can be applied to a pure delay fluorescent white light device and the like.

The invention discloses a 1, 2, 4-oxadiazole micromolecule main body material. The 1, 2, 4-oxadiazole micromolecule main body material contains one or multiple electrophilic 1, 2, 4-oxadiazoles which serve as electron acceptor units, wherein the tail ends of molecules are connected to electron donor units. The invention also discloses a preparation method of the micromolecule main body material. The preparation method is characterized in that a dibromo substituted intermediate, namely a 1, 2, 4-oxadiazole compound is prepared by using bromobenzonitrile as a reaction raw material, and then electron donor units are connected to the dibromo substituted intermediate, namely the 1, 2, 4-oxadiazole compound through Suzuki coupling reaction. The invention also discloses an application of the 1, 2, 4-oxadiazole micromolecule main body material. The 1, 2, 4-oxadiazole micromolecule main body material has relatively good solubility and film-forming property, relatively strong eletrophilicity, relatively low LUMO (Lowest Unoccupied Molecular Orbital) energy level and relatively high electronic mobility.

The invention discloses a biceptor organic luminescence small molecule material. Carbonyl is connected with sulfuryl by a benzene ring to form a novel receptor framework unit; one benzene ring is connected to each of two sides of the novel receptor framework unit so as to add reactive sites. The invention also discloses a preparation method and application of the biceptor organic luminescence small molecule material. The luminescence material connected with a receptor can realize a transfer effect of intramolecular charges; with a bipolar transmission characteristic of the luminescence material, the unbalance of a unipolar luminescent material charge carrier is reduced, and the structure of a device is simplified and the performance of the device is improved. The biceptor organic luminescence small molecule material disclosed by the invention is simple in preparation; various target products are obtained by a series of simple reactions. The material has the advantages of determined molecular weight, single structure, high decomposition temperature and lower sublimation temperature, and can be applied to an organic light-emitting diode.

The invention discloses a self-host organic light-emitting small molecule material connected with a sulfur-containing non-conjugated unit by a carbonyl group, and increasing reaction sites by connecting benzene rings on two sides separately. The invention further discloses a preparation method and application of the self-host organic light-emitting small molecule material. The self-host organic light-emitting small molecule material disclosed by the invention realizes the intramolecular charge transfer function, and the sulfur-containing non-conjugate unit owned by the self-host organic light-emitting small molecule material can act as a part of a host to show high device performances in a simplified device structure. The self-host organic light-emitting small molecule material disclosed by the invention is simple in preparation method, and various target products are obtained through a series of simple reactions. Furthermore, the material disclosed by the invention is determined in molecular weight, single in structure, very high in decomposition temperature and lower in sublimation temperature, thereby being easily sublimated into a high-purity light-emitting material.

The invention discloses a micromolecular host material based on D-R-A. According to the micromolecular host material, an electrophilic diphenylphosphine oxide group serves as an electron acceptor unit, carbazole or triphenylamine serves as an electron donor unit, and the electron acceptor unit and the electron donor unit are isolated from each other by an insulating alkyl chain. The invention also discloses a preparation method and applications of the micromolecular host material based on D-R-A. The micromolecular host material based on D-R-A has excellent bipolar transmission performance, very good solubility and film-forming performance, and has great potential when serving as a host material of a light emitting layer.