Force-induced color-changing material based on photonic crystal structure and preparation method thereof

A photonic crystal and color-changing technology, applied in the field of materials, can solve the problems of high product toxicity, complex synthesis process, application limitations, etc., and achieve the effect of simple steps and low preparation cost.

Active Publication Date: 2022-01-07
PHOMERA METAMATERIALS INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although these existing color-changing technologies can change the color of materials under the action of external force, there are still the following problems: 1) due to the fixed color-changing dyes and the small range of color changes, they can only realize the transformation between certain specific colors, and there is a problem The disadvantages of poor responsiveness and insensitivity to discoloration limit its application.
2) Color-changing dyes are usually imidazole derivatives, pyrrole derivatives, dianthrone derivatives, etc. The synthesis process is complicated, the preparation cycle is long, and the product is highly toxic

Method used

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  • Force-induced color-changing material based on photonic crystal structure and preparation method thereof
  • Force-induced color-changing material based on photonic crystal structure and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] This embodiment provides a mechanochromic material based on photonic crystals, the preparation method of which is as follows:

[0039] Step 1: 100 parts by weight of nanospheres (the particle diameter of nanospheres is 250nm, and the polydispersity index PDI of nanospheres is 0.10), 50 parts by weight of butyl acrylate, 10 parts by weight of hydroxyethyl methacrylate and 5 parts by weight Mix parts by weight of urethane acrylate, and add appropriate amount of additives as required, such as UV stabilizer, light curing agent, film-forming agent, leveling agent and viscosity regulator, to adjust the viscosity of the slurry to 50-80cps.

[0040] Step 2: Apply the slurry evenly on the TPU substrate by slit coating, then dry the TPU composite film through a 25m oven at 80°C, and cover it with a PET protective film.

[0041] Step 3: The composite film is flattened by micro-stress rolling, and the speed is controlled at 30m / min. A photonic crystal layer is formed between the T...

Embodiment 2

[0043] The preparation method of the photonic crystal-based mechanochromic material of the present embodiment is basically the same as that of Example 1, the difference is that in step one, according to 100 parts by weight of nanospheres (the particle size of nanospheres is 230nm, the polydispersity of nanospheres Index PDI is 0.10), 40 parts by weight of butyl acrylate, 10 parts by weight of glycidyl methacrylate, 10 parts by weight of tripropylene glycol diacrylate, 10 parts by weight of hydroxyethyl methacrylate and 5 parts by weight of polyurethane acrylate mix.

Embodiment 3

[0045] The preparation method of the photonic crystal-based mechanochromic material of the present embodiment is basically the same as that of Example 1, the difference is that in step one, according to 100 parts by weight of nanospheres (the particle size of nanospheres is 200nm, the polydispersity of nanospheres index PDI is 0.10), 40 parts by weight of butyl acrylate, 20 parts by weight of isooctyl acrylate, 5 parts by weight of trifluoroethyl methacrylate, 15 parts by weight of hydroxypropyl acrylate and 2.5 parts by weight of polyurethane acrylate were mixed.

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Abstract

The invention relates to a force-induced color-changing material based on photonic crystals and a preparation method thereof. The force-induced color-changing material comprises a photonic crystal functional layer and an elastic base material layer, and color changes rapidly when the material is stretched or contracted due to external force, so that stress applied to the material and generated strain are visible in real time. A polyacrylate elastomer continuous phase in the photonic crystal functional layer adopts a specific composition, so that the stripping force between the photonic crystal functional layer and the elastic base material layer is improved. The optical performance and the mechanical response color change characteristic of the film can be realized by changing the polymer microsphere structure, and the film has wide application prospects in the fields of product packaging, anti-counterfeiting, sport injury repair, pressure sensors and the like. The photonic crystal structure is obtained through coating and mechanical force regularization arrangement, the process is simple, green and environment-friendly, the preparation cost is low, and continuous and large-scale production can be achieved.

Description

technical field [0001] The invention relates to the field of materials, in particular to a mechanochromic material based on a photonic crystal structure and a preparation method thereof. Background technique [0002] Mechanochromic materials refer to a class of functional materials that change color under the action of external forces. The essence is to affect the microstructure by external forces, such as disturbing electronic energy levels by external forces, inducing phase transitions and defects by external forces, and inducing molecular structures by external forces. Isomerization, etc., change the position and shape of the electronic absorption spectrum of the compound, resulting in a color change. Mechanochromic materials have received more and more attention in recent years because of their application prospects in the fields of stress sensors, memory chips, and anti-counterfeiting. In the field of anti-counterfeiting, the traditional pressure-sensitive ink is a mat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J7/04C08J5/18C09D125/04C09D133/08C09D133/12C09D135/02C09D125/02C09D175/14C08L75/04
CPCC08J7/0427C08J5/18C09D125/04C09D133/08C09D133/12C09D135/02C09D125/02C08J2375/04C08L75/14
Inventor 田丰赵国伟董亚良
Owner PHOMERA METAMATERIALS INC
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