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Plasma-treated chitosan antibacterial fiber and preparation method thereof

A plasma and antibacterial fiber technology, applied in the field of textile fabrics, can solve the problems of damaging fiber evenness and mechanical properties, increasing impurities, and being easily oxidized, achieving low cost, short process, and strong antibacterial effect

Pending Publication Date: 2022-03-25
XIAMEN ANTA SPORTS GOODS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the production processes of antibacterial fibers on the market mainly include the following types: the first is to add antibacterial finishing agents (mainly chemical finishing agents containing silver, etc.) : Simple, relatively low cost, and the disadvantage is that it is not washable; the second is to implant antibacterial materials into the fiber through the method of masterbatch blending, but most of the antibacterial materials added by blending are irregular and random. The fiber neutralizes the surface, and the antibacterial agent must be on the surface of the fiber to exert the antibacterial effect. In order to improve the antibacterial performance, the addition of the antibacterial agent can only be increased. Compared with the fiber, it increases impurities and damages the evenness and mechanics of the fiber. performance, which has a great impact on the subsequent weaving; the third is to plate a layer of silver on the surface of the fiber by electroplating an antibacterial agent, such as the silver fiber launched by the American Noble Company, X-Static silver fiber is widely used in Lululemon's yoga pants have the advantages of better antibacterial effect, but the disadvantage is that the cost is relatively expensive, and the price of the yarn is more than 500 yuan / kg. In addition, elemental silver is easily oxidized and blackened in the air for a long time; The fourth type is natural antibacterial materials. Because the above three antibacterial technologies mostly use chemical antibacterial materials such as silver, copper and other metal materials, when they come into contact with human skin, they will have a certain impact on human health. Natural antibacterial materials have been introduced, such as tea, chitosan and other natural materials to achieve antibacterial, examples include the chitosan viscose fiber launched by Shandong Haismore, but these materials will fall off due to friction, washing, etc. during use , leading to a decrease in antibacterial performance

Method used

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  • Plasma-treated chitosan antibacterial fiber and preparation method thereof
  • Plasma-treated chitosan antibacterial fiber and preparation method thereof
  • Plasma-treated chitosan antibacterial fiber and preparation method thereof

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preparation example Construction

[0029] The invention provides a preparation method of plasma-treated chitosan antibacterial fiber, comprising the following steps: S1) performing plasma treatment on the fiber to obtain the treated fiber; S2) spraying the chitosan antibacterial solution by atomizing Cover the treated fiber, and obtain plasma treated chitosan antibacterial fiber after high temperature treatment; the chitosan antibacterial solution includes chitosan, amino silicone oil and water.

[0030] Wherein, the present invention has no special limitation on the sources of all raw materials, which can be commercially available or self-made.

[0031] The fiber is subjected to plasma treatment to obtain the treated fiber; the fiber is preferably a single-strand fiber; its type is preferably nylon, polyester or acrylic fiber, more preferably polyester; the plasma treatment is preferably low-temperature plasma treatment; The power of the plasma treatment is preferably 50-100W; the plasma treatment is preferabl...

Embodiment 1

[0045] The preparation method of 75D / 72F plasma treatment chitosan polyester antibacterial fiber mainly includes the following steps:

[0046] 1.1 Chitosan powder material preparation: mainly use crab shells and shrimp shells as raw materials to finally obtain chitosan with a particle size of 80 nanometers and a molecular weight of 10,000 through processes such as shell removal, protein removal, inorganic salt removal, and deacetylation. Sugar antibacterial liquid material.

[0047] 1.2 Plasma treatment: First, low-temperature plasma treatment is applied to the polyester single-strand fiber, so that free radicals such as -OH, -COOH, and -C=O are generated on the surface of the polyester fiber).

[0048] 1.3 Antibacterial treatment: Prepare the chitosan prepared in 1.1 as an antibacterial liquid material and apply it to a single yarn by atomization spraying, and then react with free radicals generated on the surface of polyester fibers through high temperature reaction and dryi...

Embodiment 2

[0064] The preparation method of 50D / 48F plasma treatment chitosan polyester antibacterial fiber mainly includes the following steps:

[0065] 2.1 Chitosan powder material preparation: mainly use crab shells and shrimp shells as raw materials to finally obtain chitosan with a particle size of 80 nanometers and a molecular weight of 11,000 through processes such as shell removal, protein removal, inorganic salt removal, and acetylation. Sugar antibacterial liquid material.

[0066] 2.2 Plasma treatment: first, low-temperature plasma treatment is applied to the polyester single-strand fiber, so that free radicals such as -OH, -COOH, and -C=O are generated on the surface of the polyester fiber).

[0067] 2.3 Antibacterial treatment: Prepare the chitosan prepared in 2.1 as an antibacterial liquid material and apply it to a single yarn by atomization spraying, and then react with free radicals generated on the surface of polyester fibers through high temperature reaction and drying...

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Abstract

The invention provides a method for preparing chitosan antibacterial fibers through plasma treatment. Compared with the prior art, the method has the advantages that the natural material chitosan is used as the antibacterial agent, so that the biocompatibility is better, active groups can be generated on the surface of the fiber subjected to plasma treatment, and the active groups can be subjected to grafting reaction with the chitosan so that the active groups can be uniformly attached to the outer surface layer of the fiber to form a whole, and the obtained antibacterial fiber has a stronger antibacterial effect; compared with the prior art, the chitosan antibacterial fiber has the advantages that the chitosan antibacterial fiber can inhibit growth of bacteria and has better washability, plasma treatment is adopted, the production process is high in efficiency, energy-saving, environment-friendly and low in cost, and the mechanical property of the fiber is not affected, so that the obtained chitosan antibacterial fiber treated by the plasma has the advantages of high strength, high washability, strong antibacterial property and low cost.

Description

technical field [0001] The invention belongs to the technical field of textile fabrics, in particular to a plasma-treated chitosan antibacterial fiber and a preparation method thereof. Background technique [0002] Antibacterial fibers can be used to fight against aureus bacteria, Escherichia coli, Candida albicans, etc., so they are widely used in sports T-shirts, underwear, and socks. [0003] At present, the production processes of antibacterial fibers on the market mainly include the following types: the first is to add antibacterial finishing agents (mainly chemical finishing agents containing silver, etc.) : Simple, relatively low cost, and the disadvantage is that it is not washable; the second is to implant antibacterial materials into the fiber through the method of masterbatch blending, but most of the antibacterial materials added by blending are irregular and random. The fiber neutralizes the surface, and the antibacterial agent must be on the surface of the fib...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M10/02D06M15/03D06M15/643D06M101/32
CPCD06M10/025D06M15/03D06M15/6436D06M16/00D06M2101/32
Inventor 赖宇坤蒙芳英
Owner XIAMEN ANTA SPORTS GOODS CO LTD