Powder coating composition and method for preparing thickness-controllable electrostatic spraying coating by powder coating composition
A technology of powder coating and electrostatic spraying, which is applied in coatings, conductive coatings, polyamide coatings, etc. It can solve problems such as the difficulty of thick coating, the decrease of the surface conductivity of the workpiece, and the inability to re-spray electrostatically, achieving mild conditions , good interaction and broad application prospects
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Embodiment 1
[0058] Preparation of insulating treated conductive filler:
[0059] The conductive filler for insulation treatment (hereinafter referred to as conductive filler), the specific preparation method is as follows: mix insulating thermoplastic resin and conductive material powder according to a certain mass ratio, and the thermoplastic resin can be polyolefin resin, polyamide resin, One or more mixtures of thermoplastic polyester resin, fluorocarbon resin, etc.; the conductive material powder can be metal (gold, platinum, silver, copper, iron, aluminum, zinc, magnesium and alloy powder, etc.), conductive One or more of conductive powders such as carbon materials (activated carbon, graphite, carbon nanotubes, and graphene, etc.), conductive polymers (polyacetylene, polyaniline, polythiophene, and polypyrrole, etc.) are mixed. Table 1 provides six representative composition formulas, obviously, the described formulas are only a part of the formulas of the present invention, not all ...
Embodiment 2
[0065] Preparation of polymer resins with ionizable groups:
[0066] The described polymer resin with ionizable groups (hereinafter referred to as ionizing resin) has sulfonic acid groups, or sulfonate groups, or carboxylic acid groups, or carboxylate groups, or amino groups, Or the polymer resin of one or more ionizable groups such as ammonium salt groups can be commercially available resin powder or designed and synthesized resin powder. Table 2 below shows four representative ionizing resins. Obviously, the described resin types are only a part of the applicable ionizing resins of the present invention, but not all applicable ionizing resins.
[0067] Table 2 Four representative ionization resins
[0068] sample name Resin type parameter Ionization resin 1# Sulfonated polyphenylene sulfide powder Self-made, sulfonation degree 3.5% Ionization resin 2# Sulfonated polyphenylene sulfide powder sodium salt Self-made, sulfonic acid sodium salt gra...
Embodiment 3
[0072] Preparation of base powder material:
[0073]The base layer powder material includes thermosetting resin, thermoplastic resin, insulating treated conductive filler, polymer resin with ionizable groups, thermosetting powder coating curing agent and additives. Table 3 provides four representative base powder composition formulas, obviously, the described formulas are only a part of the formulas applicable to the present invention, rather than all formulas.
[0074] Table 3 Composition formula of four representative base powder materials
[0075]
[0076] The PPS mentioned in the above table is the abbreviation of polyphenylene sulfide, PTFE is the abbreviation of polytetrafluoroethylene, and HDPE is the abbreviation of high-density polyethylene.
[0077] The components mentioned in the above table are all powders with a particle size of no more than 100 mesh, which are added to the powder mixer in proportion, mixed thoroughly, passed through a 100 mesh sieve, and clas...
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