Coating material and article coated with same
A coating and organic solvent technology, applied in the field of coatings and articles coated with the coating, can solve the problems of low coating safety and the like
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preparation example Construction
[0053] As a preparation method of the coating material of the present invention, for example, the above-mentioned visible light-responsive photocatalyst (A) and pigment can be added to the resin composition obtained by dissolving the above-mentioned resin (R) in the above-mentioned organic solvent (S), and sand milling can be used. Machine, disperser and other mixers for preparation. If necessary, by further mixing a curing agent, a two-component type paint can be prepared.
[0054] Examples of coating methods for the paint of the present invention include gravure coaters, roll coaters, comma coaters, knife coaters, air knife coaters, curtain coaters, and kiss coaters. Machine, spray coater, wheel coater, spin coater, dipping, screen printing, spraying, applicator, rod coater, brushing and other methods.
[0055] The coating material of the present invention can provide a cured coating film excellent in virus resistance to the surface of various articles.
[0056] The coatin...
preparation example 1
[0061] (Preparation Example 1: Preparation of Visible Light Responsive Photocatalyst (A-1))
[0063] a) Crystalline rutile titanium oxide
[0064] b) Preparation method: liquid phase method (sulfuric acid method)
[0065] c) Physical property value
[0066] · BET specific surface area: 9.0m 2 / g
[0067] · Rutile rate: 95.4%
[0068] ·Primary particle size: 0.18μm
[0069] (2) Manufacturing process
[0070] a) Mixing process (reaction process)
[0071] 600 parts by mass of the aforementioned titanium oxide, 8 parts by mass of copper chloride (ii) dihydrate, and 900 parts by mass of water were mixed in a stainless steel container. Next, the mixture was stirred with a stirrer ("ROBO MICS" manufactured by Tokuku Kikka Kogyo Co., Ltd.), and a 1 mol / L sodium hydroxide aqueous solution was added dropwise until the pH of the mixed solution became 10.
[0072] b) Dehydration process
[0073] Filtration under reduced pressure was carried out using ...
Embodiment 1
[0076] (Example 1: Manufacture of paint (1))
[0077] 11.2 parts by mass of the visible light-responsive photocatalyst (A-1) obtained above, titanium oxide pigment (manufactured by Chemours "Ti-Pure R-706") 35.2 parts by mass and 19.9 parts by mass of butyl acetate were kneaded with a sand mill for 30 minutes to obtain a pigment dispersion. 28.4 parts by mass of a polyisocyanate resin ("BURNOCKDN-980" manufactured by DIC Corporation) was added as a curing agent to the obtained pigment dispersion, and stirred for 5 minutes with a disperser to obtain a paint (1).
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