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High-wear-resistance beryllium oxide-zirconium oxide core-shell structure ceramic ball as well as preparation method and application thereof

A technology of core-shell structure and ceramic ball, which is applied in the field of high wear-resistant beryllium oxide-zirconia core-shell structure ceramic ball and its preparation, can solve the problems affecting the service life of the target ball and the stability of the target device, and achieve good coating effect , Improve wear resistance, high sphericity effect

Active Publication Date: 2022-05-13
INST OF MODERN PHYSICS CHINESE ACADEMY OF SCI +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Particle flow targets have complex and variable friction and wear during service, which affects the service life of the target ball and the stability of the target device, so improving the target Abrasion resistance is one of the key issues in particle flow target design

Method used

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  • High-wear-resistance beryllium oxide-zirconium oxide core-shell structure ceramic ball as well as preparation method and application thereof
  • High-wear-resistance beryllium oxide-zirconium oxide core-shell structure ceramic ball as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A high wear-resistant beryllium oxide-zirconia core-shell ceramic ball, the structure of which is BeO small ball inside the ceramic ball, ZrO wrapped outside 2 The core-shell structure, wherein the average diameter of the BeO spheres is 0.6mm, the outer ZrO 2 The average thickness of the layers was 0.4 mm.

[0033] The preparation method comprises the following steps:

[0034] The raw material 99.9% high-purity nano BeO ceramic powder and deionized water are weighed according to the formula of mass ratio = 1:0.6, and the materials are mixed by ball milling to obtain a BeO ceramic slurry with a solid content of 62%.

[0035] The uniformly mixed ceramic slurry is transported through the filter by a peristaltic pump to the centrifugal sprayer installed on the top of the drying chamber for spray drying. The inlet temperature of the dryer is controlled at 250°C, and the outlet temperature is controlled at 120°C. The BeO ceramic slurry is sprayed After drying, it is made in...

Embodiment 2

[0044] A high wear-resistant beryllium oxide-zirconia core-shell ceramic ball, the structure of which is a core-shell structure in which BeO balls are inside the ceramic ball and ZrO2 is wrapped on the outside, wherein the average diameter of the BeO balls is 0.7mm, External ZrO 2 The average thickness of the layers was 0.4 mm.

[0045] The preparation method comprises the following steps:

[0046] The raw material 99.9% high-purity nano BeO ceramic powder and deionized water are weighed according to the formula of mass ratio = 1:0.7, and the materials are mixed by ball milling to obtain a BeO ceramic slurry with a solid content of 59%;

[0047] The uniformly mixed ceramic slurry is transported through the filter by a peristaltic pump to the centrifugal sprayer installed on the top of the drying chamber for spray drying. The inlet temperature of the dryer is controlled at 270°C, and the outlet temperature is controlled at 130°C. The BeO ceramic slurry is sprayed After drying...

Embodiment 3

[0056] A high wear-resistant beryllium oxide-zirconia core-shell ceramic ball, the structure of which is BeO small ball inside the ceramic ball, ZrO wrapped outside 2 The core-shell structure, wherein the average diameter of the BeO spheres is 0.8mm, the outer ZrO 2 The average thickness of the layers was 0.3 mm.

[0057] The preparation method comprises the following steps:

[0058] The raw material 99.9% high-purity nano-BeO ceramic powder and deionized water are weighed according to the formula of mass ratio = 1:0.8, and the materials are mixed by ball milling to obtain a BeO ceramic slurry with a solid content of 56%;

[0059] The uniformly mixed ceramic slurry is transported through the filter by a peristaltic pump to the centrifugal sprayer installed on the top of the drying chamber for spray drying. The inlet temperature of the dryer is controlled at 290°C, and the outlet temperature is controlled at 140°C. The BeO ceramic slurry is sprayed After drying, it is made in...

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Abstract

The invention discloses a beryllium oxide-zirconium oxide core-shell structure ceramic ball and a preparation method thereof. The ceramic ball is of a core-shell structure, the core is a BeO small ball, and the shell layer is a ZrO2 layer; the average diameter of the BeO small balls is 0.6 to 0.8 mm, and the average thickness of the ZrO2 layer is 0.3 to 0.4 mm. The preparation method comprises the following steps: mixing nano BeO ceramic powder and deionized water to obtain BeO ceramic slurry; carrying out spray drying on the BeO ceramic slurry to obtain BeO ceramic particles; the method comprises the following steps: adding BeO ceramic particle seeds into a pelletizer, spraying nano BeO powder on the seeds, and spraying water at the same time; continuously rolling and forming until small balls with the diameter of 0.7-1.0 mm are formed; spraying nano ZrO2 powder on the BeO ceramic balls, spraying water at the same time, and continuously rolling to form small balls until a ZrO2 coated BeO core-shell structure ceramic ball blank with the diameter of 1.1-1.4 mm is formed; and drying and carrying out high-temperature vacuum sintering.

Description

technical field [0001] The invention belongs to the technical field of neutron source materials and neutron multiplication materials in the nuclear industry, and in particular relates to a high wear-resistant beryllium oxide-zirconia core-shell ceramic ball and its preparation method and application. Background technique [0002] Beryllium oxide (BeO) ceramics are widely used in special metallurgy, microelectronics, optoelectronics and other fields due to their high melting point (2530±10°C), high thermal conductivity, high strength, high chemical stability and high thermal stability. In addition, BeO has excellent nuclear properties such as high neutron scattering cross-section, higher reduction ratio than metal beryllium and graphite, and higher high-temperature radiation stability than metal beryllium, so it can be used as neutron source material, neutron multiplication material, especially As one of the candidate materials for particle flow targets in advanced nuclear en...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/08C04B35/622C04B41/87B01J13/04
CPCC04B35/08C04B35/622C04B41/87C04B41/5042B01J13/04B01J13/043C04B2235/6581C04B2235/6562C04B2235/6567C04B2235/94C04B2235/95C04B41/4578C04B41/0072
Inventor 杨磊王苍龙孟召仓刘懿文刘季韬赵皓詹文龙
Owner INST OF MODERN PHYSICS CHINESE ACADEMY OF SCI