Specific chromatogram construction method and detection method of salvia chinensis medicinal material or standard decoction thereof
A technology of feature map and construction method, which is applied in the field of feature map construction and detection of Ishigami medicinal materials or its standard decoction, can solve the problem of lack of specificity, unable to reflect the basic characteristics of clinical decoction materials, and unable to comprehensively evaluate Ishigami. Wear quality and other issues, to achieve the effect of simple operation, rapid quality evaluation method, good repeatability
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preparation example Construction
[0098] In one example, the preparation method of the reference substance solution includes the following steps:
[0099] Take caffeic acid reference substance, chlorogenic acid reference substance, rosmarinic acid reference substance, and salvianolic acid B reference substance, accurately weigh them, and add methanol aqueous solution with a volume fraction of 40% to 60% to prepare each 1 mL of caffeic acid. 50μg, chlorogenic acid 50μg, rosmarinic acid 100μg, salvianolic acid B 50μg reference solution;
[0100] Take the reference substance of Danshensu sodium, accurately weigh it, and add 40% to 60% methanol aqueous solution to make a reference substance solution containing 50 μg per 1 mL (equivalent to 45 μg of Danshensu per 1 mL).
[0101] In one example, the characteristic map includes 6 characteristic peaks.
[0102] In the present invention, by selecting a suitable reference substance and adopting certain ultra-high performance liquid chromatography (UPLC) conditions, the...
Embodiment 1
[0123] The present embodiment provides a method for constructing a characteristic atlas of Shijianchuan and its standard decoction, which is specifically as follows:
[0124] 1. Instruments, reagents and reagents
[0125] (1) Instruments
[0126] Waters HPLC (Waters H-Class, Waters Corporation), Thermo HPLC (Thermo Vanquish, Thermo Fisher Scientific), Agilent HPLC (Agilent 1290, Agilent); Thermo Scientific TM Q Exactive TM Focus combined quadrupole Orbitrap mass spectrometer (Thermo Fisher, USA); mzVault mass spectrometry database (Thermo Fisher, USA); Waters BEH C18 column (100mm×2.1mm, 1.7μm), YMC Triart C18 column (100mm ×2.1mm, 1.9μm), Agilent SB C18 column (100mm × 2.1mm, 1.8μm); one-thousandth balance (ME204E, METTLER TOLEDO), one-millionth balance (XP26, Mei Teller-Toledo Company); CNC ultrasonic cleaner (KQ500DE, Kunshan Ultrasonic Instrument Co., Ltd.), constant temperature water bath (HWS28, Shanghai Yiheng Technology Co., Ltd.), ultrapure water system (Milli-Q ...
Embodiment 2
[0238] The present embodiment provides a method for detecting the medicinal materials of Shi Jian Chuan
[0239] 1. Instruments, reagents and reagents
[0240] (1) Instruments
[0241] Waters high performance liquid chromatograph (Waters H-Class, Waters Corporation), Waters BEH C18 column (100mm×2.1mm, 1.7μm), 1 / 10,000 balance (ME204E, METTLER TOLEDO), One-millionth balance (XP26, METTLER TOLEDO); CNC ultrasonic cleaner (KQ500DE, Kunshan Ultrasonic Instrument Co., Ltd.), constant temperature water bath (HWS28, Shanghai Yiheng Technology Co., Ltd.), ultra-pure Water system (Milli-Q Direct, Merck & Co.).
[0242] (2) The reagents are the same as those in Example 1.
[0243] (3) The reagent is the same as in Example 1. Among them, the Imitsuba medicinal material numbered S16 in Table 1 was used as the Imitsubishi medicinal material to be tested.
[0244] 2. Preparation of the test solution
[0245] According to the method under "2.3(2)" in Example 1, the test solution of th...
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