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Sandwich-structure flexible piezoelectric composite film and preparation method and application thereof

A composite film, flexible piezoelectric technology, applied in the manufacture/assembly of piezoelectric/electrostrictive devices, piezoelectric/electrostrictive/magnetostrictive devices, material selection for piezoelectric devices or electrostrictive devices and other directions, it can solve problems such as fracture failure and limited flexibility applications, and achieve the effects of low cost, high repeatability, and easy control of the process

Pending Publication Date: 2022-07-29
ZHEJIANG UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

More importantly, most ferroelectric single crystal and ceramic materials will lead to the generation and development of internal defects when the strain is greater than 4%, and fracture failure occurs, which greatly limits their flexible applications.

Method used

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  • Sandwich-structure flexible piezoelectric composite film and preparation method and application thereof
  • Sandwich-structure flexible piezoelectric composite film and preparation method and application thereof
  • Sandwich-structure flexible piezoelectric composite film and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] (1) Dissolve 0.06g of polyvinylidene fluoride (PVDF) in 0.6mL of N,N-dimethylformamide (DMF) to obtain a 10wt% PVDF solution, and drop 0.6mL of the solution onto a glass substrate with a pipette , placed in a vacuum oven at 80°C for 12 hours and at 160°C for 6 hours to obtain PVDF films;

[0037] (2) Under the room temperature environment, take 3.0g of barium titanate nanoparticles into deionized water, ultrasonically vibrate for 1 hour to make it evenly dispersed; add 3.0g of dopamine hydrochloride powder to the system, and turn on magnetic stirring; Methane powder was slowly added to the obtained suspension, and the pH value was controlled to be ~8.5; then the above solution was magnetically stirred for 24 hours, allowed to stand for 1 night, the upper layer of yellow-brown solution was removed with a plastic tip dropper, and then washed with deionized water at least 3 times. The product was dried in an oven at 80 °C for 24 hours, and finally BTO@PDA nanoparticles wer...

Embodiment 2

[0045] (1) Dissolve 0.06g of polyvinylidene fluoride (PVDF) in 0.6mL of N,N-dimethylformamide (DMF) to obtain a 10wt% PVDF solution, and drop 0.6mL of the solution onto a glass substrate with a pipette , placed in a vacuum oven at 80°C for 12 hours and at 160°C for 6 hours to obtain PVDF films;

[0046](2) Under the room temperature environment, take 3.0g of barium titanate nanoparticles into deionized water, ultrasonically vibrate for 1 hour to make it evenly dispersed; add 3.0g of dopamine hydrochloride powder to the system, and turn on magnetic stirring; Methane powder was slowly added to the obtained suspension, and the pH value was controlled to be ~8.5; then the above solution was magnetically stirred for 24 hours, allowed to stand for 1 night, the upper layer of yellow-brown solution was removed with a plastic tip dropper, and then washed with deionized water at least 3 times. The product was dried in an oven at 80 °C for 24 hours, and finally BTO@PDA nanoparticles were...

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Abstract

The invention discloses a sandwich structure flexible piezoelectric composite film, which has a sandwich structure, an upper layer and a lower layer are formed by dopamine surface modified inorganic piezoelectric nanoparticles, and a middle layer is a polymer film layer. The invention also discloses a preparation method of the composite film. The preparation method comprises the following steps: dispersing dopamine modified inorganic piezoelectric nanoparticles in an ethanol solution to obtain a suspension; placing a polymer film at the bottom of a beaker, pouring the turbid liquid, and naturally settling the nano-particles to the surface of the polymer film; performing heat treatment to obtain an inorganic nanoparticle layer / polymer film layer with a double-layer structure; placing at the bottom of a beaker, placing the polymer film layer upwards, pouring the turbid liquid, and naturally settling the nano-particles to the other surface of the polymer film; and performing heat treatment to obtain the flexible piezoelectric composite film with the sandwich structure. The prepared composite film has good piezoelectric and ferroelectric properties and excellent flexibility, and can be applied to the field of wearable electronic equipment or flexible sensing.

Description

technical field [0001] The invention belongs to the field of organic-inorganic composite piezoelectric film preparation, and particularly relates to a sandwich-structure flexible piezoelectric composite film and a preparation method and application thereof. Background technique [0002] Under the background of the rapid development of the electronic information industry and the rapid maturity of the Internet of Things technology in the current intelligent era, the development of the flexible electronics industry and related technologies has become an inevitable trend. In recent years, the development of flexible electronic devices has also put forward new requirements for the flexibility of piezoelectric films. For example, ABO 3 The application of perovskite oxide piezoelectric materials is usually concentrated on ceramics and single crystal materials, and their thin films are mostly grown on rigid oxide substrates, which cannot achieve mechanical deformation in the form o...

Claims

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Application Information

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IPC IPC(8): H01L41/083H01L41/18H01L41/193H01L41/37H01L41/45
CPCH10N30/50H10N30/852H10N30/857H10N30/092H10N30/098
Inventor 乐静黄玉辉吴勇军洪子健施钧辉陈睿黾任丹阳
Owner ZHEJIANG UNIV