Method for preparing starch glue for lumber

A starch glue and starch technology, applied in the directions of starch-derived adhesives, adhesive types, etc., can solve the problems of insignificant performance of wood adhesives, poor water resistance and stability, slow drying speed, etc., and achieve low price and water resistance. Good, fast drying effect

Inactive Publication Date: 2005-10-26
JIANGNAN UNIV
View PDF1 Cites 59 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Starch has been used as an adhesive after gelatinization or oxidation modification for a long time, but its application range is greatly limited due to its poor moisture resistance, low initial adhesion, and slow drying speed, especially in wood adhesives. In the industry, few researchers use starch as the main raw material to develop wood adhesives. Most of the research is only adding a small amount of starch to wood adhesives such as white latex and urea-formaldehyde resins. The results are not significant for improving the performance of wood adhesives; there are also a small number of studies Those who directly compound starch or modified starch with polymers such as polyvinyl acetate emulsion, VAE emulsion, etc. in a certain proportion and add additives to make wood adhesives, although this method uses more starch than the previous method. There is a large increase, but because the compounding fails to change the starch properties too much, the water resistance and stability of the adhesive are still poor, and a large amount of additives such as formaldehyde must be added for improvement, which not only complicates the process, but also Increase costs, generate pollution

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Formula (weight percent):

[0040] Cornstarch 100

[0041] water 250

[0042] Hydrochloric acid 1

[0043] Ammonium persulfate 2.4

[0044]Vinyl acetate 80

[0045] Polyvinyl alcohol 10

[0046] Borax 0.6

[0047] Urea 20

[0048] Glycerin 10

[0049] Tributyl phosphate 4

[0050] Process: Mix cornstarch and hydrochloric acid solution into 30% (w / w) starch milk, add ammonium persulfate, acidolysis and oxidation at 60°C for 1.5h, adjust the pH to about 4.0, slowly add vinyl acetate dropwise, 1.5 After h, add the remaining ammonium persulfate, react at 70°C for 3h, neutralize to neutral, add polyvinyl alcohol solution to the solution, then add 5% borax solution dropwise, heat up to 80°C, and keep warm for reaction 1h, cool down to 50°C, add urea, glycerin and tributyl phosphate, stir for 0.5h, continue to cool down, discharge at room t...

Embodiment 2

[0052] Formula (percentage by weight):

[0053] Potato Starch 100

[0054] water 300

[0055] Sulfuric acid 1.5

[0056] Potassium persulfate 3.8

[0057] Butyl acrylate 50

[0058] Polyvinyl alcohol 15

[0059] Borax 1.8

[0060] Urea 40

[0061] Dibutyl phthalate 7

[0062] Octanol 2

[0063] Process: Make 35% (w / w) starch milk from potato starch and sulfuric acid solution, add potassium persulfate, acidolysis and oxidation at 70°C for 0.5h, adjust the pH to about 3.5, slowly add butyl acrylate dropwise, 1.5 After h, add the remaining potassium persulfate, react at 65°C for 4h, neutralize to neutral, add polyvinyl alcohol solution to the solution, then add 5% borax solution dropwise, heat up to 85°C, and keep warm for reaction After 30 minutes, cool down to 50°C, add urea, dibutyl phthalate and octanol, stir for 0.5h, then conti...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The present invention relates to a preparation method of starch glue for wood. Said invention uses starch as main raw material, and adopts the following steps: firstly, making starch undergo the processes of acidolysis, oxidation and graft copolymerization, etc., then adding modifying agent and complexing agent to make cross-linking modification, then heating and gelatinizing, cooling and successively adding the adjuvants of diluent, plasticizer and defoaming agent so as to obtain a starch glue with excellent performance for wood.

Description

technical field [0001] A preparation method of starch glue for wood belongs to the technical field of adhesive preparation methods. Background technique [0002] According to the different production materials and production methods of adhesives, wood adhesives can be divided into two categories: natural polymer glue and synthetic polymer glue. Natural polymer adhesives mainly include protein glue and starch glue. The history of using natural adhesives in my country is quite long. Since this kind of adhesive is made of natural materials, most of which are water-soluble. Generally speaking, the bonding strength, water resistance, heat resistance, chemical resistance and other properties are not high. Adhesive products cannot withstand harsh conditions and have a short service life. Therefore, the amount of natural polymer glue used in wood industry adhesives is becoming less and less. At present, synthetic polymer adhesives are mainly used. Among them, the most widely used a...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C09J103/04
Inventor 顾正彪李兆丰洪雁
Owner JIANGNAN UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products