Production method of pentafluoroethane
A production method and technology of pentafluoroethane, applied in the field of synthesis of pentafluoroethane, can solve the problem that the yield of pentafluoroethane cannot exceed 35%, and achieve low equipment requirements, mild reaction conditions, and simple process Effect
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Embodiment 1
[0020] In a 2-liter stainless steel autoclave, add 450 grams (2.4 mol) of tri-n-butylamine and 58 grams (1.0 mol) of acetone, cool to 0°C, and slowly introduce 160 grams of anhydrous hydrogen fluoride ( 8.0 mol), cooled to -10°C, and added 300 g (3.0 mol) of tetrafluoroethylene. Raise the temperature to 80°C, stir under a pressure of 1Mpa, and react for 4 hours. GC analysis shows that the conversion rate of tetrafluoroethylene is 99.9%. The gaseous product is collected to obtain 356.4 grams of product. GC and MS analysis show that it is pentafluoroethane with a purity of 99.0%. .
Embodiment 2
[0022] In a 2-liter stainless steel autoclave, add 400 grams (3.96 mol) of triethylamine and 250 grams (2.6 mol) of cyclohexanone, cool to 0°C, and slowly introduce 200 grams of anhydrous hydrogen fluoride under stirring and cooling conditions (10.0mol) and 500 grams (5.0mol) of tetrafluoroethylene. The temperature was raised to 130° C., stirred under a pressure of 1.5 MPa, and reacted for 9 hours to obtain 599.4 grams of product. GC and MS analysis showed that the conversion rate of tetrafluoroethylene was 99.9%, and the product was pentafluoroethane with a purity of 99.9%.
Embodiment 3
[0024] In a 2-liter carbon steel packed tower reactor, add 500 grams (3.5 mol) of tri-n-propylamine and 1200 grams (10 mol) of acetophenone, and slowly feed 560 grams (28.0 mol) of anhydrous hydrogen fluoride at a temperature of 70°C mol). This system is heated up to 145 DEG C, is stirred under pressure 1.8Mpa for 2 hours and slowly feeds 600 grams (6.0mol) of tetrafluoroethylene, separates and obtains 718.6 grams of product, and the GC analysis of gained product shows that tetrafluoroethylene conversion rate is 99.8%, The product is pentafluoroethane with a purity of 99.9%.
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