Optical directional material improving optical directional performance of liquid crystal and its preparing method
A technology for photo-alignment and photo-sensitive materials, applied in the field of photo-sensitive materials, can solve problems such as a single polymer material, and achieve the effect of improving the contrast ratio and improving the alignment effect of liquid crystal
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Embodiment 1
[0059] The preparation method of the photo-alignment material in this embodiment includes the following steps:
[0060] 1) Synthesis of photosensitive materials:
[0061] (a) Preparation of cinnamoyl chloride: Add 14.8g (0.100mol) cinnamic acid into a three-necked flask equipped with a reflux condenser and a gas absorber, and gradually add 7.5mL (12.3g, 0.105mol) with a dropping funnel under stirring Thionyl chloride was reacted for 4-10 hours under the condition that the temperature was controlled by a water bath at 40-70° C. to obtain white solid cinnamoyl chloride.
[0062] (b) Synthesis of bisphenol A dicinnamate: Add 1.140g (5mmol) bisphenol A, 2mL anhydrous pyridine and 10mL anhydrous tetrahydrofuran into a three-necked flask equipped with a reflux condenser, slowly drop in an ice-water bath Add 1.689g (10.2mmol) of cinnamoyl chloride in anhydrous tetrahydrofuran, and after all the addition is completed, the temperature is raised to 70°C for 4-10hr. The reaction produc...
Embodiment 2
[0070] In this embodiment, the photo-alignment material and its preparation method include the following steps:
[0071] 1) with embodiment 1
[0072] 2) with embodiment 1
[0073] 3) Mix bisphenol A dicinnamate and BP-AN-CA at a ratio of 10% to obtain the material for improving the photo-alignment effect of liquid crystals described in the present invention.
[0074] The liquid crystal alignment effect of this embodiment:
[0075] Step 3) The obtained material has a good liquid crystal alignment effect, and the contrast ratio of the liquid crystal cell is increased by 90% compared with that of a single polymer BP-AN-CA liquid crystal cell on the basis of ensuring the uniformity and stability of the aligned liquid crystal.
Embodiment 3
[0077] The preparation method of the photo-alignment material in this embodiment includes the following steps:
[0078] 1) with embodiment 1
[0079] 2) with embodiment 1
[0080] 3) Mix bisphenol A dicinnamate and BP-AN-CA at a ratio of 20% to obtain the material for improving the photo-alignment effect of liquid crystals described in the present invention.
[0081] The liquid crystal alignment effect of this embodiment:
[0082] Step 3) The obtained material has a good liquid crystal alignment effect, and the contrast ratio of the liquid crystal cell is increased by 30% compared with that of a single polymer BP-AN-CA liquid crystal cell on the basis of ensuring the uniformity and stability of the aligned liquid crystal.
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