Gas generating system

a technology of gas generating system and nitrocellulose, which is applied in the direction of pressure gas generation, explosives, weapons, etc., can solve the problems of high carbon monoxide content, inability to achieve ballistic tailoring with the use of nitrocellulose, and relative higher carbon monoxide content, etc., to achieve the effect of enhancing the ballistic properties, increasing the burning rate of propellant composition, and increasing the amount of carbon monoxid

Inactive Publication Date: 2006-10-05
AUTOMOTIVE SYST LAB
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0011] Typical micro gas generators use nitrocellulose or smokeless powder compositions for gas generation in a device. These compositions often result in relatively higher amounts of carbon monoxide. Furthermore, ballistic tailoring is not readily accomplished with the use of nitrocellulose. These are non-nitrocellulose compositions containing an oxidizer, a fuel, and a binder. Performance characteristics (i.e. ballistic output) related to burning rate can be varied based on the particle size distribution of the oxidizer component. In general, as the particle size distribution of the oxidizer is reduced, the burning rate of the propellant composition increases thereby enhancing the ballistic properties. As the particle size increases, the burning rate decreases and thus the ballistic output is reduced. Accordingly, the ballistic properties may be tailored in this manner. Average particle size ranges from 10 to 150 microns. Combinations of particle size distributions within said range can also be considered for the purpose of modifying performance. Ballistic tailoring can also be achieved by varying the shape, size and surface treatment, or any combination thereof of the propellant grains. Various propellant processes and techniques affecting propellant grain density, porosity, and surface finish (i.e. high or low exposed burning surface area) can also be employed to tailor ballistic output, for instance to achieve a regressive burn profile. A discreet propellant geometry such as a small cylinder, processed in a particular way such as extrusion, exhibits a porous center and also exhibits a regressive type burn profile. Limiting damage to equipment incorporating gas generants, seatbelt pretensioners for example, is thereby facilitated.
[0012] In sum, the present invention includes gas generant compositions that optimize the production of gas combustion products and minimize solid combustion products while retaining other design requirements such as reduced hygroscopicity and thermal stability. These and other advantages will be apparent upon a review of the detailed description.

Problems solved by technology

These compositions often result in relatively higher amounts of carbon monoxide.
Furthermore, ballistic tailoring is not readily accomplished with the use of nitrocellulose.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0017] A composition was homogeneously mixed in a known manner, the composition containing nitroguanidine, potassium perchlorate, and cellulose acetate butyrate. Upon applying heat from a hot plate, the composition did not autoignite at 320 C, and a black char resulted.

example 2

[0018] It has been shown that the addition of ammonium molybdate at about 1% by weight to the composition of Example 1 containing cellulose acetate butyrate, nitroguanidine, and potassium perchlorate resulted in an ignition temperature of 260 C, as measured by hot plate.

example 3 and example 4

[0019] It has been shown that the addition of molybdenum trioxide at about 1% or 2% by weight to the composition of Example 1 containing cellulose acetate butyrate, nitroguanidine, and potassium perchlorate resulted in an ignition temperature of 262 C., as measured by hot plate.

[0020] It can be seen from the examples presented that the use of a burn inhibitor or ignition catalyst, in accordance with the present invention, results in ignitable compositions that effectively mitigate the harm to associated equipment.

[0021] In yet another aspect of the invention, carbon monoxide scavengers may also be provided thereby maintaining the required effluent rates notwithstanding the use of a cellulosic binder. Metal oxides such as manganese oxide and cupric oxide, sulfates such as ammonium sulfate, and other scavengers are contemplated at about 0.1-20% by weight of the composition when optionally employed. By employing CO scavengers, the overall cost of the gas generant composition may be r...

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Abstract

The present invention generally relates to gas generant compositions for inflators of occupant restraint systems, for example. A gas generating composition 12 formed in accordance with the present invention includes an alkyl cellulosic fuel / binder, an oxidizer, and a burn inhibitor or ignition catalyst. A vehicle occupant protection system 180, and other gas generating systems, incorporate the compositions of the present invention.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS [0001] The present application claims the benefit of U.S. Provisional Application Ser. No. 60 / 666,964 having a filing date of Mar. 31, 2005.TECHNICAL FIELD [0002] The present invention relates generally to gas generating systems, and to gas generant compositions employed in gas generator devices for automotive restraint systems, for example. BACKGROUND OF THE INVENTION [0003] The present invention relates to nontoxic gas generating compositions that upon combustion rapidly generate gases that are useful for inflating occupant safety restraints in motor vehicles and specifically, the invention relates to thermally stable nonazide gas generants having not only acceptable burn rates, but that also, upon combustion, exhibit a relatively high gas volume to solid particulate ratio at acceptable flame temperatures. [0004] The evolution from azide-based gas generants to nonazide gas generants is well-documented in the prior art. The advantages of nona...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C06B45/10
CPCC06B23/007C06D5/06C06B45/10
Inventor DUNHAM, STEVEN M.G.STEVENS, BRUCE A.
Owner AUTOMOTIVE SYST LAB
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