Multilayered structure with water-impermeable substrate

Abstract

In accordance with the present invention, there is provided a multi-layered structure includes:

• • a) a water-impermeable substrate;
  • b) a first layer on at least one surface of the substrate comprising a water-based tie-layer composition;
  • c) a second layer formed over the first layer, wherein the second layer is a water-based ink-receptive composition includes:
    • i) a multivalent metal salt; and
    • ii) a hydrophilic binder polymer;
  • d) a third layer including at least one water-based ink composition deposited in a single pass by an inkjet printing process, wherein the water-based ink composition includes an anionically stabilized, water-dispersible pigment; and
  • e) additional layers deposited over the one or more ink layers and exposed second layer, the additional layers selected from one or more of the following compositions:
    • i) an opaque white layer;
    • ii) a protective layer; and
    • iii) an adhesive layer, further includes a continuous protective plastic or paper layer adhered thereto.

Description

CROSS REFERENCE TO RELATED APPLICATIONS[0001]Reference is made to commonly-assigned copending U.S. patent application Ser. No. ______ (Attorney Docket No. K001433US01RLO), filed herewith, entitled PRINTING ON WATER-IMPERMEABLE SUBSTRATES WITH WATER-BASED INKS, by Bugner et al.; the disclosure of which is incorporated herein.FIELD OF THE INVENTION[0002]The present invention relates to a method of depositing water-based inkjet inks on water-impermeable substrates and to multilayered structures and articles produced therefrom.BACKGROUND OF THE INVENTION[0003]High speed digital inkjet printing systems have recently found much success in competing with traditional analog printing presses in applications such as commercial printing and publishing. In particular inkjet printing systems which employ water-based pigment inks can rival the print quality and productivity of printing systems which are based on analog impact printing, such as lithography, gravure, and flexographic printing proce...

AI Technical Summary

Benefits of technology

[0018]It has been found after extensive investigations, that by the application of the appropriate surface treatments and water-based pre- and post-print coatings to a water-impermeable plastic substrate, a printed image and multi-layered article of high print qua

Problems solved by technology

However, decor and package printing, unlike commercial printing and publishing, commonly employ water-impermeable plastic substrates in addition to paper-based substrates.

Plastic substrates are particularly challenging for water-based inks due to the difficulty in getting the inks to wet and adhere to such substrates, which are typically designed and chosen to repel or otherwise present a barrier to water.

Although solvent-based and radiation curable (UV-curable) inkjet inks have been used with some success on plastic substrates, they are limited to certain types of inkjet printing systems, such as piezoelectric drop-on-demand systems, and come with health, safety, and environmental concerns compared to water-based inks.

When water-based inkjet inks useful for high speed digital inkjet printing, especially inks that comprise more than about 80 wt % water and less than about 10-15 wt % of organic co-solvents, are deposited on commonly available plastic substrates used for decor and packaging applications, the ink drops tend to either bead up or flow across the surface of the substrate, resulting in image quality artifacts known as mottle, coalescence, and intercolor bleeding.

In addition, water-based inks with levels of co-solvents greater than about 10-15 wt % are very difficult to completely dry, resulting in a sticky or tacky ink layer.

However, the water-containing inks disclosed in this publication are intended for flexographic or offset printing, and are not suitable for high speed inkjet printing due to their high viscosities.

There is no teaching as to how these types of inks can be modified for use in a high speed inkjet deposition system.

This imposes additional and expensive constraints on the overall printing system.

The temperatures required for the fusing step are problematic in that many water-impermeable plastic substrates useful for packaging and décor applications are prone to wrinkling or melting at temperatures as low as 50° C.

The inks further comprise “a silicone surfactant, an acetylene glycol surfactant, a pyrrolidone derivative, and a thermoplastic resin.” However, as the examples in this patent clearly demonstrate, when the inventive inks are deposited on a representative plastic film at ink coverages greater than about 60 to 70%, the “bleeding” between colors or the image non-uniformity of solid areas (“mottling”) is judged as “bad”.

This severely limits the applicability of this method for most packaging applications for which much higher ink coverages are desired.

With many water-impermeable plastic substrates, especially very thin flexible films used for packaging applications, the application of heat while printing can adversely affect the dimensional stability of the film, leading to poor color-to-color registration.

A key limitation of this me

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