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Bleaching and shive reduction process for non-wood fibers

a non-wood fiber and bleaching technology, applied in carpet cleaners, weaving, cleaning machines, etc., can solve the problems of undesirable particles, shives that continue to have deleterious effects on the appearance, surface smoothness, ink receptivity, and brightness of finished paper products, and achieve the effect of increasing the brightness of non-wood fibers

Pending Publication Date: 2021-02-04
GPCP IP HLDG LLC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The invention has various benefits and capabilities that can be easily understood by reading the description and examples provided.

Problems solved by technology

However, a common problem still occurring in non-wood fiber processes is the occurrence of shives, which are undesirable particles in finished paper products.
Shives are substantially resistant to defiberizing processes, rendering their presence problematic.
Even following oxidative bleaching, shives continue to have deleterious effects on the appearance, surface smoothness, ink receptivity, and brightness of a finished paper product.
Mechanical removal of shive to the level required for a high value product involves the application of significant mechanical energy, which results in fiber breakage and generation of fines, or small cellulose particles.
The fines are a yield loss, increasing the production cost.
Further, the broken fibers reduce the overall fiber strength so they either cannot be used in some manufacturing processes and / or result in weak textile or paper products.
Thus, conventional methods of non-wood fiber processing are not sufficiently robust to remove, decolorize, and break up the residual shive present in the fibers.
Thus, processed and finished fibers can still include dark particles of shive, which are both aesthetically unattractive and reduce the commercial value of the fiber product.
Furthermore, conventional bleaching processes are not sufficiently robust to increase paper brightness to sufficient levels required for commercial products.

Method used

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  • Bleaching and shive reduction process for non-wood fibers
  • Bleaching and shive reduction process for non-wood fibers
  • Bleaching and shive reduction process for non-wood fibers

Examples

Experimental program
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Effect test

examples

[0111]In the following examples, flax fibers (commercially available from Crailar Technologies, Inc., Greensboro, N.C.) were used to assess the impact of oxygen during the bleaching process on shive content and brightness.

[0112]All brightness measurements were conducted on thick pads of flax fiber. The pads were generated by diluting a sample of the flax fibers to approximately 2% consistency with water. The flax samples were gently hand mixed to separate the fibers as much as possible and then dewatered on a Buchner funnel with a piece of filter paper to form the fiber pad. During dewatering, the flax fiber was manually distributed to form as uniform a pad as possible. Then the pad was removed from the Buchner funnel and pressed between blotters in a laboratory press machine for about 10 minutes under a maximum pressure of 3,000 PSI. The fiber pads were then dried on a speed dryer until substantially dry. Care was taken to avoid overheating the samples because any potential excess ...

examples 1-9

[0113]The initial starting (control) flax was commercially available “finished flax” from Crailar Technologies, Inc. These fibers were treated by the Crailar process, which included mechanical treatment, chemical treatment to remove pectin, hydrogen peroxide bleaching, and drying. As shown in Table 1 below (ID 1), these flax fibers demonstrated a MacBeth UV-C brightness of 57.8. FIG. 12 shows a photomicrograph of flax fibers, which have substantial shive content.

TABLE 1Compositions and properties for Examples 1-9BrightnessChemicals % OPPhysicalMacBeth UV-CIDPeroxideCausticOxygenTAEDDTPASilicateMethod% TSSTemp F.MinutesBrightnessGain1Start Sample - “Bleached”57.8211000.10Bath1219012076.418.6322000.00Bath1219012077.419.6443000.10Bath1219012075.818.0522000.10.2Spinner819012076.819.0642000.10.2Spinner819012078.720.974200.50.10.2Spinner819012079.721.9831100.00.2Q Mixer1219018084.426.6931000.10.2Q Mixer1219018078.620.8DTPA = diethylene triamine pentaacetic acid, a chelant;Caustic = NaOH / s...

example 10-17

[0120]In Examples 10-17 shown in Table 2, bleaching was performed in the Quantum mixer to assess the impacts of oxygen and TAED on brightness, as well as the effect of reductive bleaching. All experiments were performed on a de-pectinified, unbleached flax sample (Example 10). This control sample had a lower brightness, 27.9 and a higher level of shive contamination (see also FIG. 12 of Example 24 below).

TABLE 2Compositions and properties for Examples 10-17Chemicals % OPBrightnessStartHydro-PhysicalMacBeth UV-CIDSamplePeroxideCausticOxygenTAEDDTPASilicatesulfateMethod% TSSTemp F.MinutesBrightnessGain10Unbleached27.9111041.510.10.5Mixer1519012064.036.1121131.5Mixer1518012082.654.7131041.510.50.1Mixer1519018064.136.214Unbleached31.510.10.50.5Mixer1519018083.655.715Unbleached31.510.10.51Mixer1519018081.853.916Unbleached31.510.10.51.5Mixer1519018082.254.317 12110.10.5Mixer1519018083.926.1

[0121]Example 11 utilized oxygen in the initial peroxide stage and demonstrated a 64.0 brightness af...

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Abstract

The present invention is directed to a method of increasing the brightness of non-wood fibers and nonwoven fabric fabrics produced by the method. In one aspect, the method includes forming a mixture of non-wood fibers and exposing the mixture to a brightening agent to produce brightened fibers. The brightening agent is oxygen gas, peracetic acid, a peroxide compound, or a combination thereof. The brightened fibers have a brightness greater than the fibers of the mixture before exposure as measured by MacBeth UV-C standard.

Description

CROSS REFERENCE TO RELATED APPLICATIONS[0001]This application is a continuation of U.S. patent application Ser. No. 14 / 716,153, filed May 19, 2015, which claims benefit of U.S. Provisional Patent Application Ser. No. 62 / 000,825, filed May 20, 2014, both of which are incorporated herein in their entirety by reference.TECHNICAL FIELD[0002]The instant invention generally is related to methods for fiber production. More specifically, the instant invention is related to methods for non-wood fiber bleaching and shive reduction.BACKGROUND OF THE INVENTION[0003]Plant fibers fall into three groups: seed fibers (e.g., cotton and kapok), stem fibers (bast fibers, e.g., flax and hemp), and leaf fibers (e.g., sisal and kenaf). Bast fibers occur as bundles of fibers, which extend through the length of the plant stems, located between the outer epidermal “skinlayers and the inner woody core (cortex) of the plant. Therefore, bast fiber straw includes three primary concentric layers: a bark-like s...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): D21C9/16D21H27/00D21H21/32D21H17/67D21H11/12D04H1/492D04H1/56D04H3/015D04H3/11D04H3/16A47L13/16A47L13/17D06B1/00D04H1/425D04H1/4266D06L4/30D21H21/30D21C9/147D21C5/00D06L4/13
CPCD21C9/163Y10T442/60D21H21/32D21H17/675D21H11/12D04H1/492D04H1/56D04H3/015D04H3/11D04H3/16A47L13/16A47L13/17D06B1/00D04H1/425D21H17/67D04H1/4266D21H27/00D06L4/30D21H21/30D21C9/166D21C9/147D21C5/00D06L4/13D21C9/16D10B2201/01D10B2201/08D10B2201/06D10B2201/02D10B2201/04D21H27/004D21H27/002D21C9/1026D21C9/1036D21C9/10D21C3/04D21C1/04D04H1/00
Inventor LEE, JEFFREY A.
Owner GPCP IP HLDG LLC