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93 results about "Dimethyl glutarate" patented technology

Method for purifying C4 to C6 dibasic acid monomers from adipic acid byproduct mixed dibasic acid

The invention discloses a method for purifying C4 to C6 dibasic acid monomers from an adipic acid byproduct mixed dibasic acid. The method disclosed by the invention comprises the following steps: firstly, carrying out esterification reaction on the adipic acid byproduct mixed dibasic acid and methanol at pre-set temperature in the presence of a catalyst; distilling and separating out mixed dibasic acid dimethyl ester; rectifying to obtain dimethyl succinate, dimethyl glutarate and dimethyl adipate; carrying out hydrolysis reaction on the dimethyl monomers in a rectifying reactor in the presence of a hydrolysis catalyst by two sections; at the first section of the reaction, controlling the conversion ratio of a hydrolysis ester group to be 80 percent to 95 percent and directly utilizing tower top methanol to esterify; at the second section of the reaction, controlling the conversion ratio of the hydrolysis ester group to 99.9 percent or more and directly utilizing a mixture of the tower top methanol and water to hydrolyze raw materials. According to the method disclosed by the invention, the conversion ratio of the ester group and the reaction efficiency are improved; no waste liquid is generated in a hydrolysis process so that the method is a green and environment-friendly production process.
Owner:SHANGHAI HUAFON NEW MATERIAL R&D TECH CO LTD +1

Method for preparing glutaric acid from dimethyl glutarate

The invention discloses a method for preparing glutaric acid from dimethyl glutarate. The glutaric acid is prepared by taking a strongly acidic styrene type cation exchange resin as a catalyst and taking dimethyl glutarate and water as raw materials through a hydrolytic-catalytic reaction. Each liter of reaction solution contains 100 to 330g of resin, the volume ratio of the water to the dimethylglutarate is 6:1-20:1, the heating temperature of a reaction system is between 90 and 140 DEG C, and the reaction time is between 1 and 8h. The hydrolytic-catalytic reaction system is also provided with a fractionating device used for fractionating methanol generated by the reaction. The method has the advantages that: other organic solvents are unnecessarily added, the preparation system is circular and closed, and a preparation process is environment-friendly; the catalyst is high in activity, low in consumption and high in catalytic efficiency, and the conversion ratio of the dimethyl glutarate is can reach over 85 percent; the catalyst can recycled by a simple filtering step, and keeps the stable catalytic performance; and the raw materials and the catalyst are all sold on the market,so that the method has low cost and broad application prospect.
Owner:SOUTH CHINA UNIV OF TECH +1

Emulsus anti-rust oil

The invention discloses emulsus anti-rust oil. The emulsus anti-rust oil is prepared from the following raw materials in parts by weight: 0.6-1 part of alpha-bromocinnamaldehyde, 0.1-0.2 part of stannous octoate, 0.6-1 part of ricinoleic acid, 1-2 parts of sodium potassium silicate, 1-2 parts of triglycidyl Isocyanurate, 1-2 parts of sea buckthron oil, 1-2 parts of propenol, 2-3 parts of dimethyl glutarate, 1-2 parts of 8-hydroxyquinoline, 0.4-1 part of Span-80, 5-7 parts of an antirust agent, 70-80 parts of No.30 mechanical oil, 1-2 parts of polyvinyl alcohol, 1-2 parts of triethanolamine oleate, 0.8-1 part of emulsifier OP-10 and 5-6 parts of anti-stripping mechanical oil. According to the emulsus anti-rust oil, film forming mechanical oil namely pentaerythritol oleate which has excellent lubricating performance and excellent surface film forming performance, is added and modified with 2,2,4-trimethyl-1,3-pentanediolmono(2-methylpropanoate) through blending, so that the film forming effect of a finished product can be remarkably improved, and the film forming temperature can be reduced; and the added rare-earth lanthanum ions can generate an insoluble complex with OH<-> which is generated on the surface of a metal substrate in an oxygen absorption corrosion process, so that the electrode reaction of corrosion can be retarded, and a good sustained release effect can be achieved.
Owner:WUHU HONGKUN AUTO PARTS

Method for purifying diacid dimethyl esters by plate distillation separation

The invention discloses a method for purifying diacid dimethyl esters by plate distillation separation. The distillation separation is successively finished in three series-wound distillation towers. The bottom of a second distillation tower is vertically provided with a separator plate, which divides the bottom cavity into a first tower chamber and a second tower chamber. A material inlet of the second distillation tower is positioned below the top of the separator plate. The method provided by the invention comprises the following steps of: mixing a raw material with diacid dimethyl esters, allowing the mixture to enter into the first distillation tower, separating a light component out from the top of first distillation tower, allowing the material at the tower bottom to enter into the second distillation tower, separating 1,4-succinic acid dimethyl ester out from the top of the distillation tower, separating 1,5-dimethyl glutarate out from the bottom of the second tower chamber of the second distillation tower, allowing the material at the tower bottom of the first tower chamber of the second distillation tower to enter into the third distillation tower, separating 1,6-adipic acid dimethyl ester out from the top of the third distillation tower, and discharging a heavier component in the raw material from the tower bottom. Starting with the first distillation tower, the temperature of the distillation towers successively rises and the pressure successively reduces.
Owner:WEIFANG YUANLI CHEM

Method for separating mixed diacid dimethyl ester

The invention discloses a method for separating mixed diacid dimethyl ester. Mixed diacid dimethyl ester successively passes through a rectification tower 1, a rectification tower 2 and a rectification tower 3; dimethyl succinate is separated from the top of the rectification tower 1, dimethyl glutarate is separated from the top of the rectification tower 2, and dimethyl adipate is separated from the top of the rectification tower 3; the reflux ratio of the rectification tower 1, the rectification tower 2 or the rectification tower 3 is 0.5 to 3.0; the mixed diacid dimethyl ester is a product of esterification of methanol and mixed diacid by-produced in production of adipic acid, and comprises 10 to 30 wt% of dimethyl succinate, 40 to 60 wt% of dimethyl glutarate and 20 to 40 wt% of dimethyl adipate. With the method, the recovery rate and purity of dimethyl succinate, dimethyl glutarate and dimethyl adipate are more than 95 wt% and no less than 98%, respectively. According to the invention, a rectification apparatus is divided into the three rectification towers, each rectification tower is provided with 5 to 30 tower plates, the reflux ratio is controlled to be 0.5 to 3, energy consumption is low, the utilization rate of resources is high, and the advantages of easy realization of industrialization and low energy consumption are obtained.
Owner:CHINA PETROLEUM & CHEM CORP
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