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Making method for core component of water-reservation proton exchange film fuel battery

A proton exchange membrane and core component technology, applied in fuel cell parts, solid electrolyte fuel cells, fuel cells, etc., can solve the problems of CCM's lack of water retention capacity, lack of regulation, and PTFE's inability to continuously and uniformly disperse. The effect of improving electrochemical reactivity, increasing net output power, and good water retention capacity

Inactive Publication Date: 2009-01-21
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although this method can improve the hydrophobicity of the catalytic layer, PTFE cannot be continuously and uniformly dispersed in the catalytic layer, so it lacks the regulation of water management in fuel cell applications
[0013] However, the core component CCM prepared by these methods has no water retention capacity and is not suitable for working at high temperature or low humidity.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] (1) Take 100 grams of perfluorosulfonic acid resin solution (Nafion DE 520) with a weight concentration of 5%, adjust the pH value to 7.5 with NaOH, then transfer to 100 grams of N-methylpyrrolidone, and stir it electromagnetically for 30 minutes to make The perfluorosulfonic acid resin was fully dissolved in N-methylpyrrolidone; the solution was distilled for 5 hours to remove moisture in the solution until the solution temperature reached 203°C, and at the end, the perfluorosulfonic acid resin (Nafion DE 520 solution) / N- Methylpyrrolidone solution.

[0033] (2) Weigh 1.7 grams of tetraethoxysilane (about 0.5 grams of silicon dioxide in total), dissolve in the perfluorosulfonic acid resin (Nafion DE 520 solution) / N-methylpyrrolidone solution prepared in step (1), Electromagnetic stirring was performed for 30 minutes to obtain an inorganic oxide precursor solution.

[0034] (3) Add an excessive amount of HCl solution (37wt% HCl and 63wt% water) to the solution of the p...

Embodiment 2

[0039] (1) Take 80 grams of sulfonated polyether ether ketone resin solution with a weight concentration of 10%, adjust the pH value to 7 with NaOH, then transfer to 150 grams of ethylene glycol-methyl ether, and electromagnetically stir for 30 minutes to make the sulfonated polyether ether ketone resin solution Polyetheretherketone resin is fully soluble in ethylene glycol-methyl ether. The solution was distilled for 6 hours to remove water in the solution until the temperature of the solution reached 125° C., and ended; a sulfonated polyether ether ketone resin / ethylene glycol-methyl ether solution was obtained.

[0040] (2) Weigh 1.2 g of ethyl titanate, dissolve it in the sulfonated polyether ether ketone resin / ethylene glycol-methyl ether solution prepared in step (1), and stir it electromagnetically for 30 minutes to obtain an inorganic oxide precursor solution.

[0041] (3) Add an excess of HCl solution (the HCl content is 37wt% and the water content is 63wt%) to the so...

Embodiment 3

[0044] (1) Take 500 grams of weight concentration and be 3% sulfonated trifluorostyrene resin, adjust the pH value to 6.5 with NaOH, then transfer to 900 grams of ethylene glycol-ether, and stir electromagnetically for 30 minutes to make the sulfonated trifluorostyrene resin Styrene resin is well soluble in ethylene glycol-ether. Distill to remove water in the solution until the temperature of the solution reaches 136°C, and end; a sulfonated trifluorostyrene resin / ethylene glycol-ether solution is obtained.

[0045] (2) Measure 0.1 g of isopropyl titanate, dissolve it in the sulfonated trifluorostyrene resin / ethylene glycol-ether solution prepared in step (1), and stir it electromagnetically for 30 minutes to obtain an inorganic oxide precursor solution.

[0046] (3) In the inorganic oxide precursor solution, add an excess of HCl solution 10 times larger than the hydrolysis reaction (HCl content is 37wt%, water content is 63wt%), and electromagnetically stirs for 6 hours to obt...

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PUM

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Abstract

The invention relates to a proton exchange membrane fuel cell core module preparation method. The preparation method, its characteristic lies in that it includes the following steps: 1)prepares the proton conduction polymer for decorating an inorganic oxide compound nanometer granule: a) first the weight concentration 1.2% -10% of the proton conductionpolymer solution adjusts with NaOH to the pHvalue 6.5-7.5, then changes over to the anhydrous organic solventin, obtains the solution A, then distills this solution to obtain solution B; b) according to inorganic oxide compound and proton conduction polymerload ratio 0.01: 1-0.1: 1, joins this inorganic oxide compound inorganic oxide compound forerunner body in solution B which prepares in step a) to stir 20-30 minutes, makes the inorganic oxide compound forerunner body solution; c) prepares the proton conduction polymer for decorating an inorganic oxide compound nanometer granule; 2) prepares the fuel cell core module. The guarantee water proton exchange membrane fuel cell core module of the invention preparation has good guarantee water ability.

Description

technical field [0001] The invention relates to a preparation method of a core component of a proton exchange membrane fuel cell. Background technique [0002] Hydrogen is an element ubiquitous in nature and is a renewable and clean energy. Scientists believe that hydrogen energy will make up for and gradually replace the increasingly depleted fossil energy sources such as coal and oil in the 21st century, and become an important part of the world's energy structure. Proton Exchange Membrane Fuel Cell (PEMFC) is an important way to convert hydrogen energy into electrical energy. Its energy conversion efficiency is as high as 50%, and its working temperature is low and its noise is low. The only emission is pure water. , can be widely used in vehicle power source and fixed power station power supply. Therefore, it is generally believed that fuel cells are the preferred clean and efficient power generation technology in the 21st century (Yi Baolian, Fuel Cells—Principles, Te...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M8/02H01M8/10H01M2/14H01M4/88H01M8/0245H01M8/1004H01M8/1051H01M8/1069
CPCY02E60/12Y02E60/521Y02P70/50Y02E60/50
Inventor 唐浩林潘牧李跃卿宛朝辉
Owner WUHAN UNIV OF TECH
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