Making method for core component of water-reservation proton exchange film fuel battery
A proton exchange membrane and core component technology, applied in fuel cell parts, solid electrolyte fuel cells, fuel cells, etc., can solve the problems of CCM's lack of water retention capacity, lack of regulation, and PTFE's inability to continuously and uniformly disperse. The effect of improving electrochemical reactivity, increasing net output power, and good water retention capacity
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Embodiment 1
[0032] (1) Take 100 grams of perfluorosulfonic acid resin solution (Nafion DE 520) with a weight concentration of 5%, adjust the pH value to 7.5 with NaOH, then transfer to 100 grams of N-methylpyrrolidone, and stir it electromagnetically for 30 minutes to make The perfluorosulfonic acid resin was fully dissolved in N-methylpyrrolidone; the solution was distilled for 5 hours to remove moisture in the solution until the solution temperature reached 203°C, and at the end, the perfluorosulfonic acid resin (Nafion DE 520 solution) / N- Methylpyrrolidone solution.
[0033] (2) Weigh 1.7 grams of tetraethoxysilane (about 0.5 grams of silicon dioxide in total), dissolve in the perfluorosulfonic acid resin (Nafion DE 520 solution) / N-methylpyrrolidone solution prepared in step (1), Electromagnetic stirring was performed for 30 minutes to obtain an inorganic oxide precursor solution.
[0034] (3) Add an excessive amount of HCl solution (37wt% HCl and 63wt% water) to the solution of the p...
Embodiment 2
[0039] (1) Take 80 grams of sulfonated polyether ether ketone resin solution with a weight concentration of 10%, adjust the pH value to 7 with NaOH, then transfer to 150 grams of ethylene glycol-methyl ether, and electromagnetically stir for 30 minutes to make the sulfonated polyether ether ketone resin solution Polyetheretherketone resin is fully soluble in ethylene glycol-methyl ether. The solution was distilled for 6 hours to remove water in the solution until the temperature of the solution reached 125° C., and ended; a sulfonated polyether ether ketone resin / ethylene glycol-methyl ether solution was obtained.
[0040] (2) Weigh 1.2 g of ethyl titanate, dissolve it in the sulfonated polyether ether ketone resin / ethylene glycol-methyl ether solution prepared in step (1), and stir it electromagnetically for 30 minutes to obtain an inorganic oxide precursor solution.
[0041] (3) Add an excess of HCl solution (the HCl content is 37wt% and the water content is 63wt%) to the so...
Embodiment 3
[0044] (1) Take 500 grams of weight concentration and be 3% sulfonated trifluorostyrene resin, adjust the pH value to 6.5 with NaOH, then transfer to 900 grams of ethylene glycol-ether, and stir electromagnetically for 30 minutes to make the sulfonated trifluorostyrene resin Styrene resin is well soluble in ethylene glycol-ether. Distill to remove water in the solution until the temperature of the solution reaches 136°C, and end; a sulfonated trifluorostyrene resin / ethylene glycol-ether solution is obtained.
[0045] (2) Measure 0.1 g of isopropyl titanate, dissolve it in the sulfonated trifluorostyrene resin / ethylene glycol-ether solution prepared in step (1), and stir it electromagnetically for 30 minutes to obtain an inorganic oxide precursor solution.
[0046] (3) In the inorganic oxide precursor solution, add an excess of HCl solution 10 times larger than the hydrolysis reaction (HCl content is 37wt%, water content is 63wt%), and electromagnetically stirs for 6 hours to obt...
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