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Making method of organic-inorganic combined part for the ultraviolet detection

An inorganic composite and organic technology, applied in the field of preparation of organic-inorganic composite devices, can solve the problems of inability to realize large-scale production and complicated preparation process, and achieve the effect of easy structure adjustment, simple process and low price

Inactive Publication Date: 2009-07-29
ZHEJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chinese patent CN1587996A describes a method for preparing an indium gallium oxide photoconductive ultraviolet detector; U.S. patent US6326654 describes an inorganic-inorganic composite ultraviolet detector, but none of them can realize large-scale production
Based on triphenylamine derivatives, LinHao-Wu et al prepared a purely organic UV detector by vacuum evaporation, but the preparation process is too complicated

Method used

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  • Making method of organic-inorganic combined part for the ultraviolet detection
  • Making method of organic-inorganic combined part for the ultraviolet detection
  • Making method of organic-inorganic combined part for the ultraviolet detection

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Polymethyl methacrylate was dissolved in acetone solution and coated on the aluminum substrate, and dried at 60°C.

[0018] 20ml of tetrabutyl titanate was mixed with 20ml of absolute ethanol, and magnetically stirred at room temperature for 2 hours. A mixture of 4ml of deionized water, 2ml of glacial acetic acid and 14ml of absolute ethanol was slowly added dropwise under magnetic stirring, and kept stirring for 2 hours to prepare a titanium dioxide sol. The sol was dip-coated on a substrate with a polymethyl methacrylate film, and dried at 60°C.

[0019] 0.4 g of triphenylamine and 2 g of film-forming agent polycarbonate were dissolved in 39.6 g of dichloromethane, coated on the titanium dioxide layer, and dried at 70° C. to obtain a prototype ultraviolet detector device.

Embodiment 2

[0021] The polyimide is dissolved in anhydrous ethanol solution, dip-coated on the copper substrate, and dried at 80°C.

[0022] 1ml of tetrabutyl titanate was mixed with 99ml of absolute ethanol, and magnetically stirred at room temperature for 10 hours. A mixed solution of 4 ml of deionized water, 20 ml of glacial acetic acid and 4 ml of absolute ethanol was added and kept stirring for 6 hours to obtain a titanium dioxide sol. The sol was spin-coated on the substrate with polyimide film, and dried at 100°C.

[0023] 1 gram of polyvinylcarbazole and 0.2 gram of polystyrene as a film-forming agent were dissolved in 1 gram of dioxane, coated on the titanium dioxide layer, and dried at 90°C to obtain a prototype ultraviolet detector device.

Embodiment 3

[0025] Polycarbonate is dissolved in acetone solution, coated on the magnesium substrate, and dried at 70°C.

[0026] 15ml of tetrabutyl titanate was mixed with 100ml of absolute ethanol, and magnetically stirred at room temperature for 0.5 hours. A mixed solution consisting of 16 ml of deionized water, 10 ml of glacial acetic acid, and 20 ml of absolute ethanol was slowly added, and kept stirring for 4 hours to prepare a titanium dioxide sol. This sol was coated on a substrate with polycarbonate film and dried at 70°C.

[0027] 0.8 g of phenylhydrazone and 0.4 g of film-forming agent polyester were dissolved in 0.8 g of methylene chloride, coated on the titanium dioxide layer, and dried at 60° C. to obtain a prototype ultraviolet detector device.

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Abstract

The invention discloses an organic-inorganic compound ultraviolet detector and its preparation method. Its preparation step is: 1) coating a obstruct material in the basis, drying, obtains the obstruct layer; 2) the 1-50% volume ratio of tetrabutyl titanate dissolves into the absolute ethyl alcohol, joins intermixture which is composed by the deionized water, the glacial aceticacid, the absolute ethyl alcohol, stirs, obtains the titanium dioxide sol; 3) spincoating or dip coating the titanium dioxide sol on the obstruct layer, drying, obtains the titanium dioxide layer; 4) put the organic matter by 1-50% load ratio density dissolves into the methylene chloride or dioxane, after joins film former, dip coating or spincoating on the titanium dioxide layer, drying, obtains the organic layer, makes the ultraviolet surveythe organic - inorganic compound component. This invention fully synthesized the organic material price inexpensive, structure easy adjust, can big area manufacture, and inorganic material good stability merit, its craft simple, was easy to realize, and effectively reduce the cost.

Description

technical field [0001] The invention relates to a method for preparing an organic-inorganic composite device for ultraviolet detection. Background technique [0002] As early as the 1950s, people began to study ultraviolet detection technology. Ultraviolet detection technology is another dual-use photoelectric detection technology developed after infrared and laser detection technology. In the late 1980s, following the maturity of infrared countermeasure and anti-countermeasure technology, ultraviolet countermeasure and anti-countermeasure technology also received more and more attention from the military. Foreign countries have made some progress in the military research of ultraviolet technology. The U.S. Navy’s C-130S helicopter and P-3S transport aircraft have the world’s first ultraviolet warning device AAR-47. Soon there were thousands of sets of aircraft equipped in the United States, Britain, Canada, Australia and other countries, which were put into actual combat...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L51/48
CPCY02E10/549Y02P70/50
Inventor 吴刚韩延刚汪茫陈红征
Owner ZHEJIANG UNIV