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Polyalcohol microporous barrier for high ratio polyalcohol lithium ion power cell

A technology of power battery and microporous membrane, applied in secondary batteries, circuits, electrical components, etc., can solve the problems of poor liquid absorption capacity, unsuitable for charging and discharging of high current, and high rate performance cannot meet the requirements of electric vehicles, etc. The effect of high rate discharge performance and good liquid absorption ability

Active Publication Date: 2008-04-02
WANXIANG 123 CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The polymer lithium-ion battery assembled with this polymer electrolyte membrane has excellent charge-discharge performance and cycle life, but it is not suitable for high-current charge-discharge, and cannot be used as a microporous membrane for high-rate lithium-ion power batteries.
[0004] The diaphragm is an important part of the lithium-ion battery. The PP / PE / PP film used in the liquid lithium-ion battery has high mechanical strength, but its own liquid absorption capacity is too poor to form a gel polymer electrolyte. It is easy to Leakage, poor safety
The PVDF-based gel polymer electrolyte has a good liquid absorption ability, which can prevent liquid leakage and other phenomena, and has better safety. However, its high rate performance cannot meet the needs of electric vehicles and needs to be further improved.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] 1200g of copolymer of vinylidene fluoride and hexafluoropropylene, 1800g of dibutyl phthalate, 650g of silicon dioxide and 8500g of acetone were stirred and dissolved to obtain a viscous colorless and transparent polymer solution, which was cast on PET film, dried and extracted in methanol, vacuum dried to obtain a microporous film, soaked in the electrolyte to obtain a gel polymer electrolyte film. The copolymer of vinylidene fluoride and hexafluoropropylene is abbreviated as PVDF-HFP, and the content of each monomer in the copolymerization is arbitrary.

Embodiment 2

[0019] 1200g PVDF-HFP, 1800g dibutyl phthalate, 650g aluminum oxide and 8500g acetone were stirred and dissolved to obtain a viscous colorless and transparent polymer solution, which was cast on a PET film and dried Extracting in ether, drying in vacuum to finally obtain a polymer electrolyte membrane, drying in vacuum to finally obtain a microporous membrane, soaking in an electrolyte solution to obtain a gel polymer electrolyte membrane.

Embodiment 3

[0021] 1200g PVDF-HFP, 1800g propylene carbonate, 650g silicon dioxide and 8500g acetone were stirred and dissolved to obtain a viscous colorless transparent polymer solution, which was cast on a PET film, dried and extracted in methanol. A microporous membrane is finally obtained after vacuum drying, and a gel polymer electrolyte membrane is obtained by soaking in an electrolyte solution.

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PUM

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Abstract

The present invention relates to a polymer microporous membrane for high-rate polymer lithium-ion power battery. The polymer microporous membrane is mainly used in gel polymer lithium-ion power battery. The power battery can provide powered power supply for equipment of high energy consumption and large current discharge, such as an electric vehicle, an electric motorcycle, uninterruptible power supply and so on. The microporous membrane is made of polymer material, inorganic filler, plasticizer and organic solvent. The porosity rate is between 20 percent and 70 percent. After treatment, the microporous membrane can be transformed into electrolyte membrane; the high-rate gel polymer lithium-ion power battery can be made with a square-layered battery structure. The power battery has excellent high-rate charge and discharge performances and security performances.

Description

technical field [0001] The invention relates to a polymer microporous membrane for high-rate polymer lithium-ion power batteries, which is mainly used in gel polymer lithium-ion power batteries. The power batteries can be used for high energy consumption such as electric vehicles, electric motorcycles and uninterruptible power supplies , Provide power supply for equipment that requires high current discharge. Background technique [0002] As the world is facing increasingly serious environmental problems and future oil and other energy sources will be exhausted, seeking renewable energy has become an urgent task for mankind. Power battery, as one of the new green power sources that developed countries in the world focus on developing, has a good market application prospect in electric vehicles, electric motorcycles, electric tools, mobile electronic equipment, etc. The current power batteries mainly include lead-acid batteries, nickel-cadmium batteries and lithium-ion batte...

Claims

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Application Information

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IPC IPC(8): C08J5/18C08L27/16C08L33/20C08L33/06C08L23/00C08L31/04C08K5/3415H01M10/40C08K3/36C08K3/22C08K5/109
CPCY02E60/122
Inventor 邓龙征郑利峰张兴国唐伟张克俭何峰俞琴
Owner WANXIANG 123 CO LTD
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