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Flue gas cleaning treatment method during producing carbon product

A production process and technology of carbon products, applied in the field of flue gas purification and treatment, can solve the problems of high cost, consumption of a large amount of fuel, complicated process, etc., and achieve the effects of convenient operation, low treatment cost and simple process flow

Active Publication Date: 2008-11-19
河南华慧有色工程设计有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

First of all, the flue gas generated during the raw material calcination process has not been dealt with by corresponding measures
Secondly, the flue gas generated during the production of raw electrodes is generally treated by adsorption method, and the exhaust gas still contains some carbon dust and asphalt fume. Moreover, the adsorption method is complicated in process, high in cost, and difficult to handle with adsorbents.
In addition to the adsorption method (including carbon powder adsorption method and alumina adsorption method), the roasting flue gas treatment methods include wet washing, electrostatic capture method and simple incineration method. The adsorption method used here also faces complex processes, high costs, and adsorption It is difficult to deal with the solvent; the electrostatic capture method is difficult to clean up, and there is a danger of explosion and combustion in the equipment; the secondary pollution of water by wet treatment is difficult to deal with, and these methods cannot effectively treat various components in the flue gas at the same time. The most important thing is that the carcinogen 3,4-benzopyrene in the asphalt smoke cannot be processed; and the simple incineration method needs to consume a large amount of fuel, and the process cost is very high
Moreover, the existing methods only deal with a certain process link separately, lack effective comprehensive consideration, and cannot realize the comprehensive utilization of combustible substances in the flue gas

Method used

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  • Flue gas cleaning treatment method during producing carbon product

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] The flue gas is treated in the anode production plant with an annual output of 100kt. The specific method is as follows: first, the flue gas generated during the raw anode production 3 The flow rate per hour enters the calciner. During the transmission process, it is heated by the hot gas discharged from the boiler and kept at 120°C. The flue gas and air sent to the calciner are burned at a high temperature of 1350°C, and then discharged from the calciner at 1000°C High temperature gas at 75000Nm 3 The flow rate of / h is 100000Nm with the flow rate discharged from the roasting furnace 3 / h of 155°C low-temperature flue gas mixed, the temperature of the mixed flue gas is 500°C, and at this temperature continues to be incinerated by the combustion aid coal powder, and the 600°C high-temperature gas discharged after incineration is sent to the waste heat boiler as a heat source, from The high-temperature gas discharged from the waste heat boiler is partially returned to t...

Embodiment 2

[0025] The flue gas is treated in the anode production plant with an annual output of 60kt. The specific method is as follows: first, the flue gas generated during the raw anode production 3 The flow rate per hour enters the calciner. During the transmission process, it is heated by the hot gas discharged from the boiler and kept at 150°C. The flue gas and air sent to the calciner are combusted at a high temperature of 1050°C, and then discharged from the calciner at 850°C High temperature gas at 46000Nm 3 The flow rate of / h is 50000Nm with the flow rate discharged from the roasting furnace 3 / h of 150°C low-temperature flue gas mixed, the temperature of the mixed flue gas is 530°C, and at this temperature, it is continuously incinerated by the combustion aid heavy oil, and the 660°C high-temperature gas discharged after incineration is sent to the waste heat boiler as a heat source, from the waste heat The high-temperature gas discharged from the boiler is partially returne...

Embodiment 3

[0027] The flue gas is treated in the anode production plant with an annual output of 25kt. The specific method is as follows: firstly, the flue gas generated in the raw anode production process 3 The flow rate per hour enters the calciner. During the transmission process, it is heated by the hot gas discharged from the boiler and kept at 160°C. The flue gas and air sent to the calciner are combusted at a high temperature of 1000°C, and then discharged from the calciner at 800°C High temperature gas at 18000Nm 3 The flow rate of / h is 19000Nm with the flow rate discharged from the roaster 3 / h of 155°C low-temperature flue gas mixed, the mixed flue gas temperature is 650°C, at this temperature through self-heating incineration, the 720°C high-temperature gas discharged after incineration is sent to the waste heat boiler as a heat source, and discharged from the waste heat boiler Part of the high-temperature gas is returned to the raw anode production process after desulfuriza...

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Abstract

The invention relates to a flue gas purifying treatment method during the production process of carbon products. The flue gas purifying treatment method is characterized in that the treatment process directly sends flue gas produced in the production process of a green electrode into a calcining furnace for high-temperature calcination, high-temperature gas after the calcination is mixed with low-temperature gas emitted from a roasting furnace, the mixed calcination is carried out under the high temperature via sufficient calorific value thereof or with the help of a combustion adjuvant, the high-temperature gas emitted after the calcination is taken as a heat source to be directly sent to a boiler, the gas emitted from the boiler is finally subjected to desulphurization and defluorination treatment, then a part of the purified gas is returned to the production process of the green electrode, a pipeline is heated and subjected to the temperature keeping during the process of sending the dust collecting flue gas produced during the process to the calcining furnace, and the residual purified gas is subjected to the high-altitude emission. The method of the invention can thoroughly treat the harmful substances in the flue gas and comprehensively take into account the actual production conditions and the heat of the emitted flue gas of various work segments, the process flow is simple, the operation is convenient and the treatment cost is low.

Description

technical field [0001] The invention relates to a flue gas purification treatment method in the production process of carbon products. Background technique [0002] Primary aluminum is produced using the Hall-Heroult electrolysis process. The carbon electrodes (including cathode and anode) used in this process are made of calcined petroleum coke, anthracite and other carbonaceous aggregates and coal tar pitch through kneading, molding and high-temperature roasting. During the production process, a large amount of flue gas will be produced, including carbon dust, asphalt smoke, tar, SO 2 , fluorine-containing gases, etc. These substances not only pollute the environment, but also cause great harm to the health of humans, animals and plants, especially the 3,4-benzopyrene contained in asphalt smoke has carcinogenic effect, so the purification of flue gas Governance is essential. [0003] In the production process of carbon electrodes, there are three main process steps to p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/75F23G7/06
Inventor 罗英涛赵淋苏自伟
Owner 河南华慧有色工程设计有限公司
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