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Multifunctional degradable liquid mulch film, production method and uses thereof

A liquid mulch, multi-functional technology, applied in applications, chemical instruments and methods, organic fertilizers, etc., can solve problems such as delaying crop emergence time, and achieve the effects of enhanced water resistance, high film-forming performance, and strong resistance to hard water.

Inactive Publication Date: 2009-04-08
INST OF GENETICS & DEVELOPMENTAL BIOLOGY CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to provide a multifunctional degradable liquid mulch, its preparation method and application direction. The technical problem to be solved is to make the liquid mulch have excellent film-forming performance, not delay the emergence time of crops, keep warm, and reduce soil moisture evaporation. The efficacy is stable and does not produce environmental ecological pollution

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] (1) Preparation of polyether polyol-polyvinyl alcohol-polyaspartate polymer

[0034] Add 300 kg of water to the reactor, followed by 240.0 kg of polyether polyol polymerization mother liquor (hydroxyl value 100±5mg KOH / g, viscosity 3000±500mPa·s / 25°C, polyether polyol content 50%, Qingdao Ruinuo Chemical Co., Ltd.), 150.0 kg of sodium polyaspartate solution (produced by Shijiazhuang Desai Chemical Co., Ltd., molecular weight 3000-5000, content 40%). Raise the temperature to 80-90°C, add 15.0 kg of polyvinyl alcohol (polymerization degree 1000, content 98%), stir at high speed for 20-30 minutes, and cool down to below 45°C. A polymer emulsion containing 160-180 kg of polyether polyol-polyvinyl alcohol-polyaspartic acid polymer is obtained.

[0035] (2) Preparation of liquid mulch

[0036] In the above polymer emulsion, add 15.0 kg of sodium lauryl sulfate, 25.0 kg of nonylphenol polyoxyethylene (10) ether, 20.0 kg of sodium methylene dinaphthalene sulfonate, 0.5 kg of ...

Embodiment 2

[0039] (1) Preparation of polyether polyol-polyvinyl alcohol-polyaspartate polymer

[0040]Add 300 kg of water to the reactor, followed by 200.0 kg of polyether polyol polymerization mother liquor (hydroxyl value 60±5mg KOH / g, viscosity 2000±500mPa·s / 25°C, polyether polyol content 80%, Qingdao Ruinuo Chemical Co., Ltd.), 250.0 kilograms of sodium polyaspartate solution (manufactured by Shijiazhuang Desai Chemical Co., Ltd., molecular weight 3000-5000, content 40%). Raise the temperature to 80-90°C, add 20.0 kg of polyvinyl alcohol (polymerization degree 1000, content 98%), high-speed shear and stir for 20-30 minutes, cool down to below 45°C, and obtain 240-250 kg of polyether polyol-polyethylene Polymeric Emulsions of Alcohol-Polyaspartic Acid Polymers.

[0041] (2) Preparation of liquid mulch

[0042] In the above polymer emulsion, add 25.0 kg of sodium lauryl sulfate, 20.0 kg of nonylphenol polyoxyethylene (10) ether, 25.0 kg of sodium methylene dinaphthalene sulfonate, 1....

Embodiment 3

[0045] (1) Preparation of polyether polyol-polyvinyl alcohol-polyaspartate polymer

[0046] Add 200 kilograms of water into the reactor, and then add 250.0 kilograms of polyether polyol polymerization mother liquor (hydroxyl value 150 ± 5 mg KOH / g, viscosity 1000 ± 200 mPa s / 25 ° C, molecular weight 4000, polyether polyol content 80%, Tianjin Petrochemical Company No. 3 Petrochemical Plant), 300.0 kilograms of sodium polyaspartate solution (manufactured by Shijiazhuang Desay Chemical Co., Ltd., molecular weight 3000-5000, content 40%). Raise the temperature to 80-90°C, add 25.0 kg of polyvinyl alcohol (polymerization degree 1000, content 98%), high-speed shear and stir for 20-30 minutes, cool down to below 45°C, and obtain 280-300 kg of polyether polyol-polyethylene Polymeric Emulsions of Alcohol-Polyaspartic Acid Polymers.

[0047] (2) Preparation of liquid mulch

[0048] In the above polymer emulsion, add 25.0 kg of sodium lauryl sulfate, 25.0 kg of nonylphenol polyoxyethy...

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PUM

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Abstract

The invention provides a multi-functional degradable liquid mulching film which comprises the materials with the following weight percentage: a polymer of polyether glycol-polyvinyl alcohol-polyaspartate: 15.0 percent to 40.0 percent, an emulsifier: 1.0 percent to 5.0 percent, a disperse speader: 0.5 percent to 5.0 percent, a pH value regulator: 0.1 percent to 5.0 percent, an antifreeze: 1.0 percent to 5.0 percent, and water as the rest; after the mulching film being watered and sprayed on soil surface, the macromolecules thereof are combined with soil particles and a layer of black curing film can be formed on the soil surface rapidly which can restrain the soil water from vaporizing and prompt the soil to absorb more solar energy, thereby improving the earth temperature. The liquid mulching film completely degrades into a humic acid organic fertilizer, water and carbon dioxide which can be absorbed by crops; the degradation products effectively accelerate the formation of soil grain clusters; and the number of grain clusters with water stability is increased by 10 percent to 15 percent and the volume weight of soil can be decreased by 5 percent to 10 percent. If sprayed on the surface of sandy soil, the liquid mulching film can effectively slow down the infiltration of the water to reserve water, thereby saving the water consumption of irrigation. The liquid mulching film can replace plastic mulching films in a certain range and has a certain social meaning and market prospect.

Description

technical field [0001] The invention relates to a multifunctional degradable liquid mulch film, a preparation method and an application thereof, in particular to a multifunctional degradable liquid mulch film whose main component is a high molecular polymer, and belongs to the technical field of facility agriculture. Background technique [0002] In the past 30 years, the promotion of plastic mulching technology has made important contributions to the increase of my country's grain production and the abundance of people's food baskets. But with the extensive use of plastic mulch, its negative impact is becoming more and more obvious. It is difficult to recycle plastic mulch, and a large amount remains in the farmland, destroying the soil structure and reducing crop production. According to estimates, as long as 4kg of plastic waste remains in each mu of land, the yield of corn will be reduced by about 15%, that of wheat by about 13%, and that of vegetables by 15% to 60%. T...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L79/08C08L71/00C08L29/04C08K5/42C08K5/541C08K5/053C09K17/18C09K17/52A01G13/02
Inventor 孙宏勇张喜英王学虎陈素英王艳梅裴冬
Owner INST OF GENETICS & DEVELOPMENTAL BIOLOGY CHINESE ACAD OF SCI
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