Multifunctional degradable liquid mulch film, production method and uses thereof
A liquid mulch, multi-functional technology, applied in applications, chemical instruments and methods, organic fertilizers, etc., can solve problems such as delaying crop emergence time, and achieve the effects of enhanced water resistance, high film-forming performance, and strong resistance to hard water.
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Embodiment 1
[0033] (1) Preparation of polyether polyol-polyvinyl alcohol-polyaspartate polymer
[0034] Add 300 kg of water to the reactor, followed by 240.0 kg of polyether polyol polymerization mother liquor (hydroxyl value 100±5mg KOH / g, viscosity 3000±500mPa·s / 25°C, polyether polyol content 50%, Qingdao Ruinuo Chemical Co., Ltd.), 150.0 kg of sodium polyaspartate solution (produced by Shijiazhuang Desai Chemical Co., Ltd., molecular weight 3000-5000, content 40%). Raise the temperature to 80-90°C, add 15.0 kg of polyvinyl alcohol (polymerization degree 1000, content 98%), stir at high speed for 20-30 minutes, and cool down to below 45°C. A polymer emulsion containing 160-180 kg of polyether polyol-polyvinyl alcohol-polyaspartic acid polymer is obtained.
[0035] (2) Preparation of liquid mulch
[0036] In the above polymer emulsion, add 15.0 kg of sodium lauryl sulfate, 25.0 kg of nonylphenol polyoxyethylene (10) ether, 20.0 kg of sodium methylene dinaphthalene sulfonate, 0.5 kg of ...
Embodiment 2
[0039] (1) Preparation of polyether polyol-polyvinyl alcohol-polyaspartate polymer
[0040]Add 300 kg of water to the reactor, followed by 200.0 kg of polyether polyol polymerization mother liquor (hydroxyl value 60±5mg KOH / g, viscosity 2000±500mPa·s / 25°C, polyether polyol content 80%, Qingdao Ruinuo Chemical Co., Ltd.), 250.0 kilograms of sodium polyaspartate solution (manufactured by Shijiazhuang Desai Chemical Co., Ltd., molecular weight 3000-5000, content 40%). Raise the temperature to 80-90°C, add 20.0 kg of polyvinyl alcohol (polymerization degree 1000, content 98%), high-speed shear and stir for 20-30 minutes, cool down to below 45°C, and obtain 240-250 kg of polyether polyol-polyethylene Polymeric Emulsions of Alcohol-Polyaspartic Acid Polymers.
[0041] (2) Preparation of liquid mulch
[0042] In the above polymer emulsion, add 25.0 kg of sodium lauryl sulfate, 20.0 kg of nonylphenol polyoxyethylene (10) ether, 25.0 kg of sodium methylene dinaphthalene sulfonate, 1....
Embodiment 3
[0045] (1) Preparation of polyether polyol-polyvinyl alcohol-polyaspartate polymer
[0046] Add 200 kilograms of water into the reactor, and then add 250.0 kilograms of polyether polyol polymerization mother liquor (hydroxyl value 150 ± 5 mg KOH / g, viscosity 1000 ± 200 mPa s / 25 ° C, molecular weight 4000, polyether polyol content 80%, Tianjin Petrochemical Company No. 3 Petrochemical Plant), 300.0 kilograms of sodium polyaspartate solution (manufactured by Shijiazhuang Desay Chemical Co., Ltd., molecular weight 3000-5000, content 40%). Raise the temperature to 80-90°C, add 25.0 kg of polyvinyl alcohol (polymerization degree 1000, content 98%), high-speed shear and stir for 20-30 minutes, cool down to below 45°C, and obtain 280-300 kg of polyether polyol-polyethylene Polymeric Emulsions of Alcohol-Polyaspartic Acid Polymers.
[0047] (2) Preparation of liquid mulch
[0048] In the above polymer emulsion, add 25.0 kg of sodium lauryl sulfate, 25.0 kg of nonylphenol polyoxyethy...
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