Manufacturing method for positive pole of lithium ionic cell
A lithium-ion battery and a manufacturing method technology are applied in the field of manufacturing a positive electrode of a lithium-ion battery, which can solve problems such as capacity and cycle performance of a battery that is easy to curl, and achieve the effects of reducing curling, reducing curling, and reducing surface tension.
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[0019] The water-based positive electrode slurry can be prepared by conventional preparation methods, for example, uniformly mixing positive electrode active materials, conductive agents, water-soluble binders, thickeners and water.
[0020] The positive electrode active material can be a conventional positive electrode active material for lithium-ion batteries, for example, it can be LiCoO 2 、LiFePO 4 , LiNiCoAlO 2 and LiNiMnCoO 2 one or more of them.
[0021] The conductive agent can be a conventional conductive agent used in lithium-ion batteries, for example, it can be one or more of carbon black, acetylene black, carbon fiber, graphite and artificial graphite.
[0022] The water-soluble binder can be a conventional water-soluble binder for lithium ion batteries, for example, it can be styrene-butadiene rubber (SBR), polytetrafluoroethylene (PTFE), silane coupling agent and titanate One or more of the coupling agents.
[0023] The thickener can be a conventional thick...
Embodiment 1
[0030] This example illustrates the preparation method of the positive electrode of the lithium ion battery provided by the present invention.
[0031] (1) Preparation of slurry.
[0032] Make the tackifier CMC into a 4% by weight aqueous solution, stir and mix with the conductive agent acetylene black for 1 hour, then add the positive electrode active material LiFePO 4 Fully mixed, stirred for 3 hours, then added 40% by weight of SBR aqueous solution, fully stirred for 1 hour, and finally added 20% by weight of ethylene glycol ether aqueous solution and stirred for 30 minutes to obtain a water-based positive electrode slurry. Its composition is LiFePO 4 : Acetylene black: CMC: SBR: Ethylene glycol ether: water = 100:5:1:2:20:127 (weight ratio).
[0034] The prepared slurry was uniformly coated on an aluminum foil with a thickness of 12 microns.
[0035] (3) The pole piece is dried and rolled.
[0036] Enter the oven, set the temperature in th...
Embodiment 2
[0038] This example illustrates the preparation method of the positive electrode of the lithium ion battery provided by the present invention.
[0039] The positive electrode sheet A2 was prepared according to the same method as in Example 1, except that the water-based positive electrode slurry did not contain ethylene glycol ether, and the composition of the water-based positive electrode slurry was LiFePO 4 : Acetylene black: CMC: SBR: water = 100:5:1:2:60 (weight ratio).
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