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Fatty acid salt lubricant, preparation and application thereof

A technology of fatty acid salt and high-grade fatty acid salt, which is applied in lubricating compositions, textiles, papermaking, base materials, etc. It can solve the problems of coated paper sticking, high viscosity, and easy yellowing, and achieve uniform dispersion and high viscosity. Low, no odor effect

Active Publication Date: 2012-07-18
SHANGHAI DONGSHENG NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] U.S. Patent No. 4,676,836 uses anionic emulsifier as a lubricant component to prepare an anionic lubricant for coated paper with a solid content of 50-75%, but its viscosity is relatively high, with a maximum viscosity of 1700cps; and due to the use of a large amount of urea Solid content makes the product easy to turn yellow during storage, which brings problems such as sticking and cracking in the production of high-speed coated paper

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Add 74 grams of calcium hydroxide and 507 grams of water to a four-necked flask with a thermometer and heat up to 50°C, then add 298 grams of stearic acid that has been melted in advance, react for 1 minute, and then add 0.3 grams of lauric acid polyoxygen Vinyl ester (Shanghai Rufa Chemical Technology Co., Ltd.) and 3 grams of sodium polyacrylate dispersant (product of Shanghai Dongsheng New Material Co., Ltd. brand DS-FS 126), continued to react for 240 minutes, cooled to below 35°C, and obtained the product;

[0020] The average particle diameter of the obtained product is 0.08 micron. The viscosity is 114cps, and the weight solid content is 42.5%.

Embodiment 2

[0022] Add 74 grams of calcium hydroxide and 2373 grams of water to a four-necked flask with a thermometer and heat up to 60°C, then add 596 grams of stearic acid that has been melted in advance, react for 10 minutes, add 3 grams of sorbitan mono Stearate (Zhejiang Wumart Chemicals Co., Ltd.) and 0.3 g of sodium polyphosphate (Henan Xinxiang Huaxing Chemical Co., Ltd.) continued to react for 180 minutes, and the temperature was lowered to below 35° C. The average particle size of the obtained product was 0.098 microns. The viscosity is 98cps, and the weight solid content is 22.1%.

Embodiment 3

[0024] Add 58 grams of magnesium hydroxide and 6192 grams of water to a four-necked flask with a thermometer and heat up to 70°C, then add 600 grams of lauric acid that has been melted in advance, react for 20 minutes, add 18 grams of polyethylene glycol monohard Fatty acid ester (Jiangsu Haian Petrochemical Factory) and 12 grams of sodium polyacrylate (product of Shanghai Dongsheng New Material Co., Ltd. brand DS-FS 531) continued to react for 120 minutes, cooled to below 35°C, and the average particle size of the product obtained was 0.01 micron . The viscosity is 398cps, and the weight solid content is 10.15%.

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Abstract

The invention provides a fatty acid salt lubricant, preparation and application thereof. The preparation method comprises the following steps: adding higher fatty acid to an aqueous solution of an alkali compound to react; and then, adding a dispersing agent and an emulsifying agent into the solution to react so as to obtain an advanced fatty acid salt lubricant. The dispersing agent is selected from polyphosphate, polysilicate, polycarboxylate, polyacrylate or polyoxythylene fatty alcohol ether silicane; and the emulsifying agent is selected from polyoxyethylene fatty acid, polyethylene glycol fatty acid monoester, sorbitan fatty acid ester or polyoxyethylene-polyoxypropylene segmented copolymer. The fatty acid salt lubricant can be used for a lubricant of matt enamelled paper primary coat paint. Compared with the prior art, the fatty acid salt lubricant has the advantages of good stability, high solid content, low viscosity coefficient, small dosage, and the like. As the product is evenly dispersed in high-speed coating process of the paint, and has good fluidity and levelability.

Description

technical field [0001] The invention relates to a superfine high-grade fatty acid salt lubricant with high-grade fatty acid salt as raw material, its preparation method and application. technical background [0002] Advanced fatty acid salt lubricant is a water-insoluble metal soap surfactant, commonly known as SCD dispersion. Generally, it is made into a water-suspended dispersion with a weight concentration of about 50%, and is added to the paint at 0.5-5% of the absolute dry weight of the pigment, and its lubricating effect is also very obvious. [0003] High-grade fatty acid salt dispersions have been used as coating lubricants for coated paper in my country's paper industry as early as the early 1980s. At present, stearate lubricants are produced all over the country, but the solid content is basically 40~ Between 45%, the solid content is low. If the storage time is a little longer, the product will easily turn yellow, have peculiar smell, and be easy to delaminate. ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10M105/42D21H19/00
Inventor 施晓旦李丽王养臣
Owner SHANGHAI DONGSHENG NEW MATERIALS
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