Ferroelectric material organically templated metal boron phosphate and preparation method and application thereof
A technology of borophosphate and organic templates, applied in organic chemistry, cobalt organic compounds, etc., can solve the problems of low ferroelectric coupling coefficient, application limitations, and small relative dielectric constant, and achieve good repeatability, high yield, The effect of simple preparation process
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[0014] 1. Preparation of compounds
[0015] 1. Weigh cobalt acetate (Co(CH 3 COO) 2 )0.088 to 0.880g, boric acid (H 3 BO 3 )0.062 to 0.186g, piperazine (C 4 h 10 N 2 )0.048 to 0.258, measure 0.18 to 0.72ml phosphoric acid aqueous solution (H 3 PO 4 Mass concentration 85%), water (H 2 O) 3.0 to 9.0ml as a solvent, the above Co:H 3 BO 3 : C 4 h 10 N 2 :H 3 PO 4 :H 2 The molar ratio of O is 0.5~5:1~3:0.5~3:1.5~6:16~50, stir for 20 minutes, put it into a closed 28mL reaction kettle, heat up to 140~220°C, and keep the temperature for 1 to 7 days After taking it out, it can be cooled naturally at room temperature to obtain crystals. After X-ray single crystal diffraction analysis, it was determined that the crystal was C 4 h 13 N 2 B 2 P 3 CoO 13 . Cobalt acetate is replaced by cobalt nitrate hexahydrate, cobalt nitrate, cobalt sulfate or cobalt chloride in the same amount to obtain the same C 4 h 13 N 2 B 2 P 3 CoO 13 compound.
[0016] Concrete react...
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