The invention belongs to the technical field of preparation of high-performance positive
electrode materials for
sodium-
ion batteries, and particularly relates to a porous spherical
ferric pyrophosphate sodium-based positive
electrode material synthesized on the basis of a
sol-
gel method. The invention provides a new strategy for coordinated regulation and control of high-entropy induced lattice
distortion and a porous
microsphere structure, and the micron-sized spherical rich-hole high-entropy positive
electrode material Na4Fe2.75 (MgCrMnVCo) 0.05 (PO4) 2P2O7 (HE0.05-NFPP) is successfully prepared. High-entropy doped five-membered
transition metal ions are introduced through a solution-
gel method, on one hand, lattice
distortion is induced through the high-entropy effect, the unit
cell volume is enlarged, and a three-dimensional
transmission channel of Na < + > is effectively widened; and on the other hand, the
energy density is greatly improved through the porous
microsphere structure, internal gaps of the porous
microsphere structure serve as a buffer layer and an
electrolyte storage area, and the problem of interface infiltration at the low temperature and
volume expansion at the high temperature are effectively solved. The material shows excellent all-weather
sodium storage performance, and the capacity
retention rate reaches 87.1% after 10000 cycles at the ultrahigh rate of 50 DEG C at the normal temperature; at a high temperature of 60 DEG C, 82.9 mAh g <-1 > (50 C); more importantly, at the low temperature of-20 DEG C, the reversible capacity of 73.9 mAh g <-1 > can still be released at the multiplying power of 10 C. According to the invention, a solution with great industrial prospect is provided for developing a wide-temperature-range and fast-charging sodium-
ion battery.