The invention relates to a lead
barium borate compound and a lead
barium borate
nonlinear optical crystal and a preparation method and application, and belongs to the technical field of
nonlinear optical crystals. According to the technical scheme, the
chemical formula of the
crystal is Pb0.81Ba8.19B18O36, the molecular weight is 2063.14, the
crystal belongs to a hexagonal
system, the
space group is R32,
cell parameters are that a=7.2116(7) angstroms, c=19.226(4) angstroms, Z=1, V=865.9(2) cubic angstroms, the
powder frequency-doubling effect reaches one third time that of KDP, the transparency range is wider, and the transparency
wave band ranges from 310 nm to 2600 nm. The lead
barium borate compound and the lead
barium borate nonlinear optical crystal and the preparation method and application have the
advantage that the compound is synthesized through a
solid phase reaction method, the crystal is grown through a co-
solvent method, the crystal is easy to operate, low in cost, large in size, short in
growth cycle, few in inclusion, large in mechanical
hardness and easy to
cut, polish and preserve, and the lead
barium borate nonlinear optical crystal can be widely applied in nonlinear optical devices such as frequency-doubling conversion and optical parametric oscillators.