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Water-based primer-topcoat braking paint and preparation method thereof

A bottom surface, water-based technology, applied in the direction of anti-corrosion coatings, coatings, etc., can solve the problems of poor anti-corrosion performance, easy pulverization, high production cost, etc., achieve excellent weather resistance and gloss retention, excellent anti-rust performance, and improve compactness Effect

Active Publication Date: 2010-04-28
CNOOC CHANGZHOU PAINT & COATINGS IND RES INST +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Cathodic electrophoretic coatings and water-based epoxy-amine curing systems with epoxy resin (mostly bisphenol A epoxy resin) as the main film-forming material have high adhesion and excellent corrosion resistance, but epoxy resin The outdoor weather resistance is relatively poor, easy to pulverize, lose gloss, and the fullness of the coating film is not high, so it is not suitable for high-quality outdoor paint and high decorative paint, and is often used as a primer; And gloss and color retention, it has good decorative properties in various coatings, but its anti-corrosion performance is slightly poor, and it is often used as a top coat
Therefore, in order to achieve corrosion resistance, aging resistance and better decorative performance, current metal parts such as lamps, toys, motorcycle frames, compressors, and automobile chassis generally require two-step spraying, namely spraying primer and spraying Topcoat, its construction is cumbersome and the production cost is relatively high

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Embodiment 1 prepares water-based acrylic resin A1

[0035] (1) Formula

[0036] Water-based acrylic resin is composed of 10-30% of hydroxyl-containing acrylic monomers, 5-20% of carboxyl-containing acrylic monomers, 2-8% of internal crosslinking monomers, 20-40% of other acrylic monomers, styrene 15-30% of the monomer, 1-5% of the initiator, and 40-50% of the alcohol-ether co-solvent are the free radical polymerization reaction products of the raw materials, and the above percentages are percentages by weight;

[0037] The specific formula is shown in Table 1.

[0038] Table 1

[0039] components

raw material name

Dosage, parts by weight

weight

share%

Hydroxy-containing acrylic monomer

Hydroxypropyl Acrylate

115.8

12.73

Carboxyl-containing acrylic monomer

acrylic acid

32

3.52

Other acrylic monomers

Butyl acrylate

180

19.79

Styrenic monomer

Styrene

137.5

...

Embodiment 2

[0042] Embodiment 2 prepares water-based acrylic resin A2

[0043] Basically the same as Example 1, the obtained water-based acrylic resin A2 has a solid content of 55% by weight, the difference is that the crosslinking agent glycidyl acrylate is used in an amount of 5 parts by weight, and the amount of acrylamide is 20 parts by weight.

[0044] The raw material of synthesizing waterborne acrylic resin is not limited to the raw material used in embodiment 1 and embodiment 2, can be selected from the raw material listed below:

[0045] The hydroxyl-containing acrylic monomer is one or more of hydroxypropyl acrylate, hydroxyethyl acrylate, and caprolactone;

[0046] The carboxyl-containing acrylic monomer is one or both of acrylic acid or methacrylic acid;

[0047] Other acrylic monomers are one or more of methyl methacrylate, butyl methacrylate, methyl acrylate, and butyl acrylate;

[0048] Styrenic monomers are one or more of styrene, m-methylstyrene and p-methylstyrene;

...

Embodiment 3

[0052] Embodiment 3 prepares water-based bottom surface all-in-one baking paint 1#

[0053] (1) Formula: 30-40 parts by weight of water-based acrylic resin, 2-10 parts by weight of amino resin, 1-3 parts by weight of neutralizing agent, 2-5 parts by weight of composite antirust pigment, 1-3 parts by weight of coloring pigment, filler 10-20 parts by weight, 0.1-0.5 parts by weight of defoamer, 0.1-0.5 parts by weight of leveling agent, and 25-40 parts by weight of deionized water. See Table 2 for the specific formula.

[0054] Table 2

[0055] components

raw material name

Dosage, parts by weight

% by weight

Waterborne Acrylic Resin

A1, made in Example 1

450

45

Neutralizer

Dimethylethanolamine

18

1.8

amino resin

R717

36

3.6

Defoamer

BYK022

1.5

0.15

leveling agent

BYK331

1.5

0.15

coloring pigment

PU carbon black

20

2.0

Composit...

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PUM

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Abstract

The invention relates to a water-based primer-topcoat braking paint and a preparation method thereof. The braking paint comprises the following materials by weight percentage: 30-40 of water-based acrylic resin, 2-10 of amino resin, 1-3 of neutralizing agent, 2-5 of compound rustproofing pigment, 1-3 of tinting pigment, 10-20 of filling agent, 0.1-0.5 of defoaming agent, 0.1-0.5 of flatting agent and 25-40 of deionized water, wherein the water-based acrylic resin is a free radical polymerization resultant which comprises the following materials by weight percentage: 10-30 of monomer containing hydroxy acrylic acid, 5-20 of monomer containing carboxyl acrylic acid, 2-8 of internal crosslinking monomer, 20-40 of other acrylic acid monomer, 15-30 of phenyl ethylene monomer, 1-5 of evocating agent and 40-50 of alcohol ether latent solvent. When the paint is prepared, the dispersion and the abrading condition of the pigments and the filling agents are reasonably controlled to ensure that each component of the paint fully plays the respective function. The paint ensures the corrosion prevention effect and the decoration of a coating and realizes the combination of a primer and a topcoat.

Description

technical field [0001] The invention relates to a water-based bottom-surface-in-one baking coating and a preparation method thereof, which is especially suitable for rust prevention and decoration of steel structures such as metal machinery. Background technique [0002] Water-based coatings use water instead of organic solvents, which can greatly reduce the use of organic solvents in the coatings industry, and have the advantages of low energy consumption and low emissions. It has become the development direction of coatings in the world. Cathodic electrophoretic coatings and water-based epoxy-amine curing systems with epoxy resin (mostly bisphenol A epoxy resin) as the main film-forming material have high adhesion and excellent corrosion resistance, but epoxy resin The outdoor weather resistance is relatively poor, easy to pulverize, lose gloss, and the fullness of the coating film is not high, so it is not suitable for high-quality outdoor paint and high decorative paint,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D133/14C09D133/12C09D133/06C09D125/14C09D125/16C09D161/32C09D7/12C09D5/08
Inventor 胡中张汉青庄振宇祝宝英朱柯
Owner CNOOC CHANGZHOU PAINT & COATINGS IND RES INST
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