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Preparation method of coal dust suppressant with nuclear membrane structure

A technology of dust suppressant and coal, applied in the direction of chemical instruments and methods, other chemical processes, etc., can solve problems such as short circuit of power supply insulators, deterioration of the environment of employees and passengers, and high cost

Active Publication Date: 2010-07-28
BEIJING UNIV OF CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

And it also produces serious pollution to the body of other vehicles passing by.
Secondly, it has a great impact on the equipment
Coal dust has seriously polluted the track bed of railway lines, aggravating the degree of compaction. In heavily polluted sections, coal dust has buried fasteners, sleeper plates and other parts, which has brought considerable difficulties to the daily maintenance of the engineering department. Serious corrosion on rails and fasteners, causing safety hazards
Due to the pollution of coal dust, the daily maintenance of signal communication equipment is very difficult
It often causes short circuit and discharge of power supply insulators, which shortens the service life and brings great inconvenience to daily maintenance operations
Third, it poses a threat to driving safety
The thickness of coal particles increases at a rate of about 20cm per month at the entrance of the tunnel. The concentration of coal dust in the tunnel is suffocating, and the visibility is less than 10m. The temperature of the working environment of the electrical equipment in the locomotive will rise, which will often cause equipment failure, reduce the integrity rate and safety degree, and seriously threaten the operation safety of the train
Fourth, it seriously deteriorates the environment for employees and passengers
A large amount of coal dust in the tunnel invaded the locomotive crew room, deteriorating the working environment of the crew, and the raised coal dust caused dust pollution to the roadside stations, crossings and other environments, especially for the public works, electricity and power supply workers who often work in the tunnel serious harm to the health of
For some ordinary vehicles that are not well sealed, coal dust flies into the vehicle, which poses a serious threat to the health of passengers
Fifth, there are potential serious security risks
However, in an environment with extremely dry natural conditions, due to rapid evaporation, frequent spraying, time-consuming and labor-consuming, and a large amount of water, not only the cost is high, but it is also difficult to continuously meet the requirements of environmental quality

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Take 1.5g of tetrabutyl titanate (analytical pure) and dissolve it in 6g of ethanol (analytical pure, the same below), fully dissolve; take 1.5 g of sodium carboxymethyl cellulose and dissolve it in 88ml of distilled water; then dissolve tetrabutyl titanate The solution of the ester is dripped into the sodium carboxymethyl cellulose solution at a rate of 20-30 drops / min. After the addition is completed and fully mixed, oxalic acid (20%) is added dropwise according to the acidity at this time to make The pH value of the mixed solution is 7, and after 7 hours of reaction, an environment-friendly dust suppressant with nuclear membrane structure composed of sodium carboxymethyl cellulose, titanium oxide, dibutyl oxalate, ethanol and water can be obtained.

Embodiment 2

[0027] Take 0.3g of tetrabutyl titanate (analytical pure) and dissolve it in 4g of ethanol, fully dissolve; take 1.0g of hydroxypropyl methylcellulose and dissolve it in 90ml of distilled water; then drop the solution of tetrabutyl titanate into hydroxyl In the propyl methylcellulose solution, the dropping speed is 20-30 drops / minute. After the dropping is completed and fully mixed, oxalic acid (20%) is added dropwise according to the acidity at this time, so that the pH value of the mixed solution is 6.8 After 5 hours of reaction, an environment-friendly dust suppressant with nuclear membrane structure composed of hydroxypropyl methylcellulose, titanium oxide, dibutyl oxalate, ethanol and water can be obtained.

Embodiment 3

[0029] Take 3.0g of tetrabutyl titanate (analytical pure) dissolved in 6g of ethanol, fully dissolved; take 2.0 grams of sodium carboxymethyl starch and dissolve in 87ml of distilled water; then drop the solution of tetrabutyl titanate into carboxy In the sodium methyl starch solution, after the dropwise addition is completed and fully mixed, oxalic acid (20%) is added dropwise according to the acidity at this time, so that the pH value of the mixed solution is 7.2, and after 8 hours of reaction; Sodium starch, titanium oxide, dibutyl oxalate, ethanol and water is an environment-friendly dust suppressant with nuclear membrane structure.

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Abstract

The invention relates to a preparation method of a coal dust suppressant with a nuclear membrane structure, comprising the following ingredients in parts by weight: 1.0-2.0 parts of modified cellulose or modified starch, 0.3-3.0 parts of nano particle matrix, 4.0-8.0 parts of alcohol and 87-94.7 parts of water. The nano particle matrix is dissolved in the alcohol; the modified starch or the modified cellulose is dissolved in the water; the two mixtures are evenly mixed to ensure that the pH value of mixed liquid is 6.5-7.5; and then, the mixed liquid is stirred for 5-8 hours. The dust suppressant of the invention capable of preventing coal dust emission can be proportioned and prepared at normal temperature without adding other warming-up devices. After being proportioned at normal temperature, the coal dust suppressant is sprayed or coated on the surface of compartment coal to ensure that a solidified layer is formed on the surface of the coal so as to avoid dust raising pollution and coal dust raising loss along the line in the railway transportation process and can not cause environment pollution. In addition, the invention not only has great economic benefit for railway transportation and coal clients but also has social benefits for environment protection.

Description

technical field [0001] The invention relates to a preparation method of a coal dust suppressant with a nuclear film structure. The dust suppressant is mainly used to prevent coal loss and environmental pollution during coal transportation on railways and roads and coal stacking. Background technique [0002] At this stage, China's coal is generally transported by open car in railway transportation. During the transportation process, due to the bumps caused by the roadbed, turnouts and rail facilities, coupled with the wind force, especially when the train enters the tunnel, due to the "piston wind" effect, it will form an instant strong disturbance air flow, and the fine coal powder on the surface will The particles are blown away from the vehicle body, fall onto the road surface, and then be rolled by subsequent vehicles to form secondary dust with smaller particle size and higher concentration. As a result, the coal dust on the surface of the coal seam in the vehicle is s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K3/22C08L1/26C08L1/08C08L3/04C08L3/08C08K5/5415C08K5/057C08K5/10
Inventor 朱红王芳辉申闫春
Owner BEIJING UNIV OF CHEM TECH
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